Skip to main content
Log in

Impact of Zn2+ Doping on the Structural, Morphological and Photodiode Properties of V2O5 Nanorods

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

In the present study, the effects of Zn2+ doping on the microstructural, morphological and photodiode response of the V2O5 nanorods have been studied. Pure and Zn2+ doped V2O5 nanorods were prepared by a simple and cost effective wet chemical solution process. The XRD studies confirmed that the pure and Zn2+ doped samples exhibit crystalline nature with mixed phases for Zn doping. From the morphology analysis, it is observed that substitution of Zn2+ into the V2O5 matrix is found to gradually transform the morphology from hexagonal face rods to short rods mixed with the plate like structures. The luminescence features of nanostructures are analyzed using photoluminescence studies. Moreover, the V2O5/p-Si and ZnV2O5/p-Si photodiodes parameters were studied under dark and light environments.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Y. Wang, Y. Zhou, C. Meng, Z. Gao, X. Cao, X. Li, X. Liang, W. Zhu, X. Peng, B. Zhang, Y. Lin, L. Liu, A high-response ethanol gas sensor based on one-dimensional TiO2/V2O5 branched nanoheterostructures. Nanotechnology 27, 425503 (2016)

    Article  Google Scholar 

  2. X. Haitao, H. Zhang, L. Liu, L. Fang, Yu. Wang, Substrate-free fabrication of self-supported V2O5 nanobelt arrays by a low-temperature solvothermal method with high electrochemical performance. Nanotechnology 27, 315402 (2016)

    Article  Google Scholar 

  3. G.T. Kim, J. Muster, V. Krstic, Y.W. Park, S. Roth, M. Burghard, Field-effect transistor made of individual V2O5 nanofibers. Appl. Phys. Lett. 76, 1875 (2000)

    Article  CAS  Google Scholar 

  4. C.-Y. Chen, T.-C. Wei, P.-H. Hsiao, C.-H. Hung, Vanadium oxide as transparent carrier-selective layer in silicon hybrid solar cells promoting photovoltaic performances. ACS Appl. Energy Mater. 7, 4873–4881 (2019)

    Article  Google Scholar 

  5. Y. Zhang, J. Zheng, Y. Zhao, H. Tao, Z. Gao, C. Meng, Fabrication of V2O5 with various morphologies for high-performance electrochemical capacitor. Appl. Surf. Sci. 377, 385–393 (2016)

    Article  CAS  Google Scholar 

  6. Y. Dong, H. Wei, W. Liu, Q. Liu, W. Zhang, Y. Yang, Template-free synthesis of V2O5 hierarchical nanosheet-assembled microspheres with excellent cycling stability. J. Power Sources 285, 538–542 (2015)

    Article  CAS  Google Scholar 

  7. Y. Chen, C. Chen, W. Chen, H. Liu, J. Zhu, Influence of thermal-decomposition temperatures on structures and properties of V2O5 as cathode materials for lithium ion battery. Prog. Nat. Sci.: Mater. Int. 25, 42–46 (2015)

    Article  Google Scholar 

  8. B.P. Yalagala, P. Sahatiya, C.S.R. Kolli, S. Khandelwal, V. Mattela, S. Badhulika, V2O5 nanosheets for flexible memristors and broadband photodetectors. ACS Appl. Nano Mater. 2, 937–947 (2019)

    Article  CAS  Google Scholar 

  9. S. Islam, M.H. Alfarugi, D.Y. Putro, V. Soundharrajan, B. Sambandam, J. Jo, S. Park, S. Lee, V. Mathew, J. Kim, K+ intercalated V2O5 nanorods with exposed facets as advanced cathodes for high energy and high rate zinc-ion batteries. J. Mater. Chem. A 7, 20335–20347 (2019)

    Article  CAS  Google Scholar 

  10. J. Dai, Z. Wu, X. Wu, C. Ji, Z. Xiang, Y. Shi, Z. Huang, D. Wang, X. Dong, Y. Jiang, Design and preparation of a VO2-based high-performance metamaterial for smart windows. Appl. Phys. A (2020). https://doi.org/10.1007/s00339-020-03469-7

    Article  Google Scholar 

  11. S. Liang, Q. Shi, H. Zhu, B. Peng, W. Huang, One-step hydrothermal synthesis of W-doped VO2 (M) nanorods with a tunable phase-transition temperature for infrared smart windows. ACS Omega 1, 1139–1148 (2016)

    Article  CAS  Google Scholar 

  12. Z. Mao, W. Huang, L. Wenhao Zhou, Q.S. Tang, In-situ stirring assisted hydrothermal synthesis of W-doped VO2 (M) nanorods with improved doping efficiency and mid-infrared switching property. J. Alloys Compd. 821, 153556 (2020)

    Article  CAS  Google Scholar 

  13. M. Li, S. Magdassi, Y. Gao, Y. Long, Hydrothermal Synthesis of VO2 Polymorphs: advantages, challenges and prospects for the Application of Energy Efficient Smart Windows. Small 13, 1701147 (2017)

    Article  Google Scholar 

  14. C. Sun, L. Yan, B. Yue, H. Liu, Y. Gao, The modulation of metal–insulator transition temperature of vanadium dioxide: a density functional theory study. J. Mater. Chem. C 2, 9283–9293 (2014)

    Article  CAS  Google Scholar 

  15. L. Whittaker, C. Jaye, F. Zugen, D.A. Fischer, S. Banerjee, Depressed phase transition in solution-grown VO2 nanostructures. J. Am. Chem. Soc. 131, 8884–8894 (2009)

    Article  CAS  Google Scholar 

  16. X. Li, R.E. Schaak, ZnO-templated synthesis and metal-insulator transition of VO2 nanostructures. Chem. Mater. 31, 2088–2096 (2019)

    Article  CAS  Google Scholar 

  17. J. Yoon, H. Kim, X. Chen, N. Tamura, B.S. Mun, C. Park, H. Ju, Controlling the temperature and speed of the phase transition of VO2 microcrystals. ACS Appl. Mater. Interfaces. 8, 2280–2286 (2016)

    Article  CAS  Google Scholar 

  18. W. Changzheng, F. Feng, J. Feng, J. Dai, J. Yang, Y. Xie, Ultrafast solid-state transformation pathway from new-phased goethite VOOH to paramontroseite VO2 to rutile VO2(R). J. Phys. Chem. C 115, 791–799 (2011)

    Article  Google Scholar 

  19. Y. Chen, H. Liu, W.-L. Ye, Preparation and electrochemical properties of submicron spherical V2O5 as cathode material for lithium ion batteries. Scr. Mater. 59, 372–375 (2008)

    Article  CAS  Google Scholar 

  20. R. Suresh, K. Giribabu, R. Manigandan, S. Praveen Kumar, S. Munusamy, S. Muthmizh, A. Stephen, V. Narayanan, New electrochemical sensor based on Ni-doped V2O5 nanoplates modified glassy carbon electrode for selective determination of dopamine at nanomolar level. Sens. Actuators B: Chem. 202, 440–447 (2014)

    Article  CAS  Google Scholar 

  21. R. Suresh, K. Giribabu, R. Manigandan, S. Munusamy, S. Praveen Kumar, S. Muthamizh, A. Stephen, V. Narayanan, Doping of Co into V2O5 nanoparticles enhances photodegradation of methylene blue. J. Alloys Compd. 598, 151–160 (2014)

    Article  CAS  Google Scholar 

  22. G.N. Kryukova, G.A. Zenkovets, N. Pfander, D.-S. Su, R. Schlogl, Structural study of titanium doped vanadia and vanadium doped titania catalysts. React. Kinet. Catal. Lett. 80, 161–169 (2003)

    Article  CAS  Google Scholar 

  23. J. Qi, B. Zhao, Yu. Naisen, C. Niu, G. Sun, Preparation of tungsten-doped VO2 (M) nanoparticles through sol-gel method and hydrothermal synthesis. Adv. Mater. Res. 881, 960–963 (2014)

    Article  Google Scholar 

  24. S.Y. Zhan, C.Z. Wang, K. Nikolowski, H. Ehrenberg, G. Chen, Y.J. Wei, Electrochemical properties of Cr doped V2O5 between 3.8 V and 2.0 V. Solid State Ion. 180, 1198–1203 (2009)

    Article  CAS  Google Scholar 

  25. R. Suresh, K. Giribabu, L. Vijayalakshmi, A. Stephen, V. Narayanan, Visible light photocatalytic property of Zn doped V2O5 nanoparticles. AIP Conf. Proc. 1447, 351–352 (2012)

    Article  CAS  Google Scholar 

  26. T. Akkila, I. Mansur Basha, Study of structural, morphological and optical properties of nano-structured zinc doped V2O5 thin films. J. Pure Appl. Sci. Technol. 8, 18–33 (2018)

    Google Scholar 

  27. M. Zeng, H. Yin, K. Yu, Synthesis of V2O5 nanostructures with various morphologies and their electrochemical and field-emission properties. Chem. Eng. J. 188, 64–70 (2012)

    Article  CAS  Google Scholar 

  28. S. Pavasupree, Y. Suzuki, A. Kitiyanan, S.P. Art, S. Yoshikawa, Synthesis and characterization of vanadium oxides nanorods. J. Solid State Chem. 178, 2152–2158 (2005)

    Article  CAS  Google Scholar 

  29. M. Wang, Y. Xue, Z. Cui, R. Zhang, Size-dependent crystal transition thermodynamics of nano-VO2 (M). J. Phys. Chem. C 122, 8621–8627 (2018)

    Article  CAS  Google Scholar 

  30. S.H. Ng, T.J. Patey, R. Buchel, F. Krumeich, J.Z. Wanq, H.K. Liu, S.E. Pratsinis, P. Novak, Flame spray-pyrolyzed vanadium oxidenanoparticles for lithium battery cathodes. Phys. Chem. Chem. Phys. 11, 3748–3755 (2009)

    Article  CAS  Google Scholar 

  31. G. Kortum, Reflectance Spectroscopy (Springer, New York, 1969)

    Book  Google Scholar 

  32. A.L. Pergament, E.L. Kazakova, G.B. Stefanovich, Optical and electrical properties of vanadium pentoxidexerogel films: modification in electric field and the role of iron transport. J. Phys. D Appl. Phys. 35, 2187–2195 (2002)

    Article  CAS  Google Scholar 

  33. K. Karthika, K. Ravichandran, Tuning the microstructural and magnetic properties of ZnO nanopowders through the simultaneous doping of Mn and Ni for biomedical applications. J. Mater. Sci. Technol. 31, 1111–1117 (2015)

    Article  CAS  Google Scholar 

  34. B.X. Lin, Z.X. Fu, Y.B. Jia, Green luminescent center in undoped zinc oxide films deposited on silicon substrates. Appl. Phys. Lett. 79, 943 (2001)

    Article  CAS  Google Scholar 

  35. N.K. Dutta, R.J. Nelson, The case for Auger recombination in In1−xGaxAsyP1−y. J. Appl. Phys. 53, 74 (1982)

    Article  CAS  Google Scholar 

  36. X.B. Wang, C. Song, K.W. Geng, F. Zeng, F. Pan, Photoluminescence and Raman scattering of Cu-doped ZnO films prepared by magnetron sputtering. Appl. Surf. Sci. 253, 6905–6909 (2007)

    Article  CAS  Google Scholar 

  37. S. Muthukumaran, R. Gopalakrishnan, Structural, optical and photoluminescence studies of heavily Mn-doped ZnO nanoparticles annealed under Ar atmosphere. J. Mater. Sci.: Mater. Electron. 23, 1393–1401 (2012)

    CAS  Google Scholar 

  38. E.H. Rhoderick, R.H. Williams, Metal-semiconductor contacts, 2nd edn. (Clarendon, Oxford, 1988), p. 252

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to N. Senthil Kumar, B. Mohanbabu or K. Mohanraj.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kumar, N.S., Chang, J.H., Ho, MS. et al. Impact of Zn2+ Doping on the Structural, Morphological and Photodiode Properties of V2O5 Nanorods. J Inorg Organomet Polym 31, 1066–1078 (2021). https://doi.org/10.1007/s10904-020-01751-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-020-01751-y

Keywords

Navigation