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Electrochemical Synthesis of an Organometallic Material Based on Polypyrrole/MnO2 as High-Performance Cathode

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Abstract

We report herein the design of promising composite material as a cathode in a rechargeable battery by combining the properties of polypyrrole (PPy) and MnO2 particles. The composites were prepared by electropolymerization of the pyrrole monomer followed by electrodeposition of a manganese salt suspension by two methods. The first method involved the formation of MnO2 in situ in the PPy/ITO electrode, while the second method involved first a preliminary adsorption of Mn2+ ions in the polymer, followed by an electrochemical of the electrode. The morphology of the resulting composite materials (PPy/MnO2) was studied by energy-dispersive X-ray spectroscopy (EDS), X-ray diffractometry (XRD), scanning electron microscopy (SEM), Fourier-transform infrared (FTIR). The investigations of the electrochemical properties of the composite electrodes show that the presence of MnO2 play an important role in improving the surface of polymer films, which leads to lower charge transfer resistance and higher electrode activity. For the optimal synthesis method, the electrode generates a maximum current of up to − 7.9 mA cm−2 for the oxygen reduction reaction, which is eight times the current density delivered by the electrode without PPy.

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Acknowledgements

The authors gratefully acknowledge the laboratory of Institut Européen des Membranes, Montpellier for their SEM and XRD characterizations. The authors gratefully acknowledge the financial support from the General Directorate of Scientific Research and Technological Development of Algeria (DGRSDT/MESRS).

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Authors and Affiliations

  1. Lab. Dynamic Interactions and Reactivity of Systems, Kasdi Merbah University, 30000, Ouargla, Algeria

    Waffa Rakhrour, Djamel Selloum & Abdellah Henni

  2. Faculty of Applied Sciences, Department of Mechanical Engineering, University Kasdi Merbah of Ouargla, Ouargla, Algeria

    Noureddine Cherrad

  3. Laboratoire Croissance et Caractérisation de Nouveaux Semi-Conducteurs, Université Ferhat Abbas, Sétif-1, Algeria

    Imene Chikouche

  4. Laboratory of Process Engineering, Laghouat University, Laghouat, Algeria

    Mokhtar Benalia, Mabrouk Djedid & Nacira Bouzar

  5. Centre de Recherche Scientifique et Technique en Analyses Physico-Chimiques (CRAPC), 30000, Ouargla, Algeria

    Sarra Mouffok

  6. Institut Européen des Membranes, IEM UMR 5635, Univ Montpellier, ENSCM, CNRS, 34090, Montpellier, France

    Sophie Tingry

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  1. Waffa Rakhrour
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  2. Djamel Selloum
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Correspondence to Djamel Selloum.

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Rakhrour, W., Selloum, D., Henni, A. et al. Electrochemical Synthesis of an Organometallic Material Based on Polypyrrole/MnO2 as High-Performance Cathode. J Inorg Organomet Polym 31, 62–69 (2021). https://doi.org/10.1007/s10904-020-01664-w

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  • DOI: https://doi.org/10.1007/s10904-020-01664-w

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