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Polyaniline/Cu(II) Metal-organic Frameworks Composite for High Performance Supercapacitor Electrode

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Abstract

The specific capacitance of supercapacitors can be benefited by the porosity of the metal-organic frameworks (MOFs). In this study, a nanocomposite of polyaniline-Cu(II) MOFs (PANI/Cu-MOF) was fabricated by a two-step process including chemical polymerization of aniline and room temperature synthesis of Cu–MOFs in the presence of the as-prepared polyaniline. The obtained compounds were characterized by FT-IR, PXRD, SEM, EDAX mapping, and XPS techniques. PXRD patterns revealed the amorphous character of the nanocomposite. FT-IR and EDS-mapping demonstrate the formation of PANI/Cu–MOF nanocomposite. SEM was applied for studying the PANI/Cu-MOF morphology. As demonstrated by CV (cyclic voltammetry), GCD (galvanostatic charge/discharge), and EIS (electrochemical impedance spectroscopy), PANI/Cu-MOF composite shows better capacitive properties compared to the pure Cu-MOF. Furthermore, the results of CVs indicate that the PANI/Cu-MOF composite has a higher capacitance (734 F g−1 at 5 mV s−1) with good electrochemical cycling stability.

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Acknowledgements

This study was financially supported by Shahid Chamran University of Ahvaz (Grant No. 1396).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Shahid Chamran University of Ahvaz, Ahvaz, Iran

    Zeinab Neisi & Zeinab Ansari-Asl

  2. Medical Physics Department, School of Medicine, Iran University of Medical Sciences (IUMS), Tehran, Iran

    Amin Shiralizadeh Dezfuli

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  1. Zeinab Neisi
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  2. Zeinab Ansari-Asl
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  3. Amin Shiralizadeh Dezfuli
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Correspondence to Zeinab Ansari-Asl.

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Neisi, Z., Ansari-Asl, Z. & Dezfuli, A.S. Polyaniline/Cu(II) Metal-organic Frameworks Composite for High Performance Supercapacitor Electrode. J Inorg Organomet Polym 29, 1838–1847 (2019). https://doi.org/10.1007/s10904-019-01145-9

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