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Structural Elucidation and Supercapacitive Performance in a 1D Cadmium(II) Polymer Based on Pyrazole Carboxylic Acid

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Abstract

One pyrazole carboxylic complex, namely, {[Cd(Hpzca)2(H2O)3]·H2O}n (1), where H2pzca is 1H-pyrazole-4-carboxylic acid, has been synthesized under solvothermal condition, and the crystal structure was determined by single crystal X-ray diffraction. The X-ray study reveals that complex 1 is a 1D polymer. While it was used as the electrode material for a supercapacitor, exhibited large specific capacitance, high rate capability and good cycling stability. Capacitances of 106 F g−1 could be achieved at a rate of 0.5 mVs−1 and the retention was maintained at about 93% even after 1000 cycles.

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Acknowledgements

We thank the support of this work by the Key Research Project of Natural Science from Provincial Bureau of Education, Anhui, China (Grant Nos. KJ2017A572, KJ2018A0567), the National Science Foundation for Cultivation of Bengbu University (Grant No. 2018GJPY03) and Starting Research Fund of Bengbu University (Grant No. BBXY2018KYQD15).

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Author notes

  1. Chao Feng, Guo-Ning Zhang and Chang-Peng Lv contribute to this work equally.

Authors and Affiliations

  1. School of Materials and Chemical Engineering, Bengbu University, Bengbu, 233030, People’s Republic of China

    Chao Feng, Chang-Peng Lv & Xiao-Qi Jin

  2. Institute of Medicinal Biotechnology, Chinese Academy of Medical Science and Peking Union Medical College, Beijing, 100050, People’s Republic of China

    Guo-Ning Zhang

  3. Shangqiu Second Senior High School, Shangqiu, 476000, People’s Republic of China

    Li-Na Sun

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  1. Chao Feng
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  2. Guo-Ning Zhang
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  3. Chang-Peng Lv
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Correspondence to Chao Feng.

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Feng, C., Zhang, GN., Lv, CP. et al. Structural Elucidation and Supercapacitive Performance in a 1D Cadmium(II) Polymer Based on Pyrazole Carboxylic Acid. J Inorg Organomet Polym 29, 1559–1564 (2019). https://doi.org/10.1007/s10904-019-01119-x

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