Pure Sb2S3 and Fe (2.5%): Sb2S3 thin films were synthesized on Zn2SnO4 coated with FTO conductive glasses using chemical bath deposition (CBD) technique. The X-ray diffraction (XRD) patterns obtained show that both thin films have an orthorhombic structure. Although the crystal structure of the two thin films was the same, the crystalline size of Fe (2.5%): Sb2S3 thin film (51.15 nm) was found to be smaller than that of pure Sb2S3 (52.89 nm). The effect of Fe-doped metal on crystal size of Sb2S3 was observed with this result. Another important observation is that the energy band gap of Fe (2.5%): Sb2S3 thin film (2.00 eV) is larger than that of pure Sb2S3 (1.89 eV). The photovoltaic properties of the synthesized thin films were examined by applying both incident photon-to-current efficiency (IPCE) and current density (J)–voltage (V) measurements. The obtained IPCE(%) values at 600 nm for pure Sb2S3 and Fe (2.5%): Sb2S3 thin films are 30.29 and 49.06, respectively. Using the J–V curves, the calculated η (%) values for pure Sb2S3 and Fe (2.5%): Sb2S3 thin films are 3.95 and 5.44, respectively. Based on the data obtained from both measurements, it was observed that the Fe dopant significantly enhance the performance of the Sb2S3-based solar cell devices.
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S. Seghaier et al., Structural and optical properties of PbS thin films deposited by chemical bath deposition. Mater. Chem. Phys. 97(1), 71–80 (2006)
S. Horoz, H. KoÇ, Ö ŞAhİN, Investigation of structural, optical and photovoltaic properties of Sb2S3 thin films. J. Phys. D Appl. Phys. 38, 588–593 (2017)
J. Kavinchan et al., Synthesis of coral-like, straw-tied-like, and flower-like antimony sulfides by a facile wet-chemical method. J. Nanomater. 2013, 5 (2013)
H. Yang, S. Xiaohui, A. Tang, Microwave synthesis of nanocrystalline Sb2S3 and its electrochemical properties. Mater. Res. Bull. 42(7), 1357–1363 (2007)
M.I. Medina-Montes et al., Structural, morphological and spectroscopic ellipsometry studies on sputter deposited Sb2S3 thin films. J. Mater. Sci. Mater. Electron. 27(9), 9710–9719 (2016)
K. Surya Subrahmanyam et al., High-surface-area antimony sulfide chalcogels. Chem. Mater. 28, 7744–7749 (2016)
A. Deangelis et al., Antimony(III) sulfide thin films as a photoanode material in photocatalytic water splitting. ACS Appl. Mater. Interfaces. 8(13), 8445–8451 (2016)
S. Shaji et al., Antimony sulfide thin films prepared by laser assisted chemical bath deposition. Appl. Surf. Sci. 393, 369–376 (2017)
R.G. Avilez Garcia et al., Antimony sulfide (Sb2S3) thin films by pulse electrodeposition: Effect of thermal treatment on structural, optical and electrical properties. Mater. Sci. Semicond. Process. 44, 91–100 (2016)
E. Kärber et al., Sb(2)S(3) grown by ultrasonic spray pyrolysis and its application in a hybrid solar cell. Beilstein J. Nanotechnol. 7, 1662–1673 (2016)
F. Ezema et al., Optical properties and structural characterizations of Sb2S3 thin films deposited by chemical bath deposition technique. Turk. J. Phys. 31(4), 205–210 (2007)
F.E. Loranca-Ramos et al., Structural, optical and electrical properties of copper antimony sulfide thin films grown by a citrate-assisted single chemical bath deposition. Appl. Surf. Sci. 427, 1099–1106 (2018)
S. Messina, M.T.S. Nair, P.K. Nair, Antimony sulfide thin films in chemically deposited thin film photovoltaic cells. Thin Solid Films 515, 5777–5782 (2007)
I. Validzic et al., Structural analysis, electronic and optical properties of the synthesized Sb2S3 nanowires with small band gap. Semicond. Sci. Technol. 29, 035007 (2014)
S. Srikanth et al., Effect of annealing temperature and deposition time on Sb 2S s3 thin films. J. Optoelectron. Adv. Mater. 12, 2075–2081 (2010)
N. Habubi, S. Chiad, A.M.E. Ibrahim, Annealing effect on the optical properties of Sb2S3 thin films. J. Univ. Anbar Pure Sci. 5, 18–22 (2011)
H. Lee, J.-K. Kim, H.-B. Chung, On Ag-doping in amorphous Sb2S3 thin film by HeNe and HeCd laser exposures and its optical characteristics. J. Non-Cryst. Solids 279, 209–214 (2001)
S. Horoz, O. Sahin, Synthesis, characterization and photovoltaic properties of Mn-doped Sb2S3 thin film. Mater. Sci. Pol. 35, 861–867 (2017)
K. Tsujimoto et al., TiO2 surface treatment effects by Mg2+, Ba2+, and Al3+ on Sb2S3 extremely thin absorber solar cells. J. Phys. Chem. C 116, 13465–13471 (2012)
S. Nar, O. Sahin, S. Horoz, Determination of the optimum Co concentration in Co:Sb2S3 thin films. J. Mater. Sci. Mater. Electron. 29, 17853–17858 (2018)
S. Mushtaq et al., Nickel antimony sulphide thin films for solar cell application: study of optical constants. Nat. Sci. 8, 33–40 (2016)
B. Frumarová et al., Thin films of Sb2S3 doped by Sm3+ ions. J. Non-Cryst. Solids 326, 348–352 (2003)
F. Aousgi, M. Kanzari, Study of the optical properties of Sn-doped Sb2S3 thin films. Energy Procedia 10, 313–322 (2011)
S. Mushtaq et al., Low-temperature synthesis and characterization of Sn-doped Sb2S3 thin film for solar cell applications. J. Alloy. Compd. 632, 723–728 (2015)
S. Nar, O. Sahin, S. Horoz, Determination optimum ni concentration in Zn2SnO4/Ni-Doped Sb2S3 thin films with different ni concentrations using incident photons to current efficiency (IPCE) and current density (J)-voltage (V) measurements. Chalcogenide Lett. 15, 491–497 (2018)
This study supported by the Scientific and Technological Research Council of Turkey. (TUBITAK) (Project Number: 117F193).
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Nar, S., Şahin, Ö. & Horoz, S. Fabrication of Pure Sb2S3 and Fe (2.5%): Sb2S3 Thin Films and Investigation Their Properties. J Inorg Organomet Polym 29, 1331–1336 (2019). https://doi.org/10.1007/s10904-019-01097-0
- Energy band gap
- Particle size
- Thin film