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A hydrostable Cadmium–Organic Framework for Highly Selective and Sensitive Luminescence Sensing of Al3+ Ion

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Abstract

A hydrostable and methyl-functionalized MOF with a qtz topology constructed from dinuclear clusters, {[Cd(1,4-NDC)(3,3′-dmbpy)]·(H2O)}n (1) (1,4-H2NDC = 1,4-naphthalenedicarboxylic, 3,3′-dmbpy = 3,3′-dimethyl-4,4′-bipyridine) was synthesized and structurally characterized. TGA, PXRD, and water vapor sorption results show high thermal and water stability for the framework. 1 displays a 3D framework with the channel of 5.1 × 7.0 Å2 along the b axis. The framework exhibits a reversible and highly selective luminescent sensing function with respect to Al3+ cation.

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Acknowledgements

This work was supported by the Special Funds of Guangdong College Students’ Scientific and Technological Innovation Cultivation (pdjhb0543), the Training Plan of Guangdong Province Outstanding Young Teachers in Higher Education Institutions (YQ2015168), and the Natural Science Foundation of Zhaoqing University (201532).

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Authors and Affiliations

  1. School of Food and Pharmaceutical Engineering, Zhaoqing University, Zhaoqing, 526061, People’s Republic of China

    Deyun Ma, Chanchan Chen, Minchun Chen, Shanshan Zhu, Yetao Wu, Zhanhong Li & Yan Li

  2. College of Life Science, Zhaoqing University, Zhaoqing, 526061, People’s Republic of China

    Liping Zhou

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  1. Deyun Ma
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  2. Chanchan Chen
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  3. Minchun Chen
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  7. Yan Li
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Correspondence to Yan Li or Liping Zhou.

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Ma, D., Chen, C., Chen, M. et al. A hydrostable Cadmium–Organic Framework for Highly Selective and Sensitive Luminescence Sensing of Al3+ Ion. J Inorg Organomet Polym 29, 1829–1837 (2019). https://doi.org/10.1007/s10904-018-1023-4

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  • DOI: https://doi.org/10.1007/s10904-018-1023-4

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