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Hydrogenation of p-Nitrobenzoic Acid by Gold and Palladium Nanoparticles Immobilized Within Macroporous Amphoteric Cryogels in Aqueous Solution

Journal of Inorganic and Organometallic Polymers and Materials volume 28, pages 2427–2438 (2018)Cite this article

Abstract

Aqueous solutions of sodium salt of p-nitrobenzoic acid (p-NBA) were hydrogenated in mild conditions in the presence of palladium (PdNPs) and gold nanoparticles (AuNPs) immobilized within macroporous amphoteric cryogel based on N,N-dimethylaminoethylmethacrylate (DMAEM) and methacrylic acid (MAA). The morphology of the macroporous catalyst DMAEM-co-MAA/AuNPs was characterized using SEM. The pore sizes of sponge-like porous structure of cryogels are in the range of 5–40 µm, while the average sizes of AuNPs immobilized within the macroporous amphoteric cryogel are 80 ± 20 nm. The reduction of p-NBA to p-aminobenzoic acid (p-ABA) and further to by-products p,p′-azodibenzoate and sodium 4-(4-aminobenzamido)benzoate was confirmed by Raman and 1H NMR spectroscopy. The conversion degree, kinetic parameters, and activation energies of hydrogenation of p-NBA were found.

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Acknowledgements

Financial support from the Ministry of Education and Science of the Republic of Kazakhstan (IRN AP05131003, 2018–2020) is greatly acknowledged.

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Authors and Affiliations

  1. Laboratory of Engineering Profile, K.I. Satpayev Kazakh National Research Technical University, Almaty, Kazakhstan

    Sarkyt Kudaibergenov, Moldir Dauletbekova, Gaukhar Toleutay & Sana Kabdrakhmanova

  2. Institute of Polymer Materials and Technology, Almaty, Kazakhstan

    Sarkyt Kudaibergenov, Moldir Dauletbekova & Sana Kabdrakhmanova

  3. Sh. Ualikhanov Kokshetau State University, Abay Str. 76, 020000, Kokshetau, Kazakhstan

    Tulegen Seilkhanov

  4. National Nanotechnological Laboratory, Al-Farabi Kazakh National University, Almaty, Kazakhstan

    Khabib Abdullin

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  1. Sarkyt Kudaibergenov
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  2. Moldir Dauletbekova
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  3. Gaukhar Toleutay
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  4. Sana Kabdrakhmanova
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Correspondence to Sarkyt Kudaibergenov.

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Kudaibergenov, S., Dauletbekova, M., Toleutay, G. et al. Hydrogenation of p-Nitrobenzoic Acid by Gold and Palladium Nanoparticles Immobilized Within Macroporous Amphoteric Cryogels in Aqueous Solution. J Inorg Organomet Polym 28, 2427–2438 (2018). https://doi.org/10.1007/s10904-018-0930-8

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  • DOI: https://doi.org/10.1007/s10904-018-0930-8

Keywords

  • Macroporous amphoteric cryogel
  • Palladium and gold nanoparticles
  • Hydrogenation
  • p-Nitrobenzoic acid
  • Macroporous flow-through catalytic reactor