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Dye Adsorption and Fluorescence Sensing Behaviour About Rare Earth-Indole Carboxylic Acid Complexes

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Abstract

Five rare earth-indole carboxylic acid complexes: [Eu(IAA)2(phen)2]·NO3 (1) (IAA = indole acetic acid, phen = o-phenanthroline); [Nd(IAA)2(phen)2]·NO3 (2); [Er(IBA)3(phen)](phen)·HNO3·H2O (3) (IBA = indole butyric acid); [Ce(IBA)3(phen)](phen)·HNO3·H2O (4); [Dy(IBA)3(phen)](phen)·HNO3·H2O (5) were synthesized and characterized. Then, we reported their properties as dye adsorption and fluorescence sensing for the first time. The fluorescence explorations demonstrated that complex 1 exhibits highly selective and sensitive sensing for nitro aromatic compounds with high sensitivity (1.49 × 107 M−1) and low detection limit (11.40 µM). Meanwhile, these complexes also exhibit stronger selective adsorption of dye molecules (MB and MG) in aqueous solution. This study provides new physical insights into the rational design of lanthanide complexes based on multifunctional materials.

Graphical Abstract

We firstly reported five lanthanide complexes and displayed fluorescence sensing and selective adsorption dye properties.

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Acknowledgements

This work was supported by the Grants of the National Natural Science Foundation of China (Nos. 21571091, 21371086) and Commonweal Research Foundation of Liaoning province in China (No. 20170055).

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Authors and Affiliations

  1. College of Chemistry and Chemical engineering, Liaoning Normal University, Huanghe Road 850#, Dalian, 116029, People’s Republic of China

    Chun Hong Liu, Li Jing Zhang, Feng Ying Bai, Yu Wang & Yong Heng Xing

  2. School of Physics and Electronic Technology, Liaoning Normal University, Dalian, 116029, People’s Republic of China

    Yuan Zhi Hong & Cheng Ren Li

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  1. Chun Hong Liu
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Correspondence to Feng Ying Bai or Yong Heng Xing.

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Liu, C.H., Zhang, L.J., Bai, F.Y. et al. Dye Adsorption and Fluorescence Sensing Behaviour About Rare Earth-Indole Carboxylic Acid Complexes. J Inorg Organomet Polym 28, 1839–1849 (2018). https://doi.org/10.1007/s10904-018-0869-9

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