A Cd-Coordination Polymer Based on a Bis-pyridyl-bis-amide Ligand: Synthesis, Structure and Its Application in Removal Organic Dyes

  • Xiuli Wang
  • Jing Zhao
  • Mao Le
  • Hongyan Lin
  • Juan Luan
  • Guocheng Liu
  • Xiang Wang
Article
  • 51 Downloads

Abstract

A cadmium(II) coordination polymer, namely, [Cd2(3-bpcb)(1,2-pda)2(H2O)2] (1), was prepared by hydrothermal reaction of cadmium(II) chloride with 1,2-H2pda (H2pda = 1,2-phenylenediacetic acid) and a bis-pyridyl-bis-amide ligand (3-bpcb = N,N′-bis(3-pyridinecarboxamide)-1,4-benzene). Complex 1 was structurally characterized by single crystal X-ray diffraction, which shows a 2D layer structure with (42·6)(42·63·8) topology. Complex 1 was further characterized by elemental analysis, infrared spectroscopy (IR) and thermogravimetric analysis (TGA). The application in removal organic dyes of complex 1 has been investigated.

Keywords

Metal–organic coordination polymer Bis-pyridyl-bis-amide ligand Removal dye 

Notes

Acknowledgements

Financial supports of the National Natural Science Foundation of China (21671025, 21471021, 21501013 and 21401010) and Program for Distinguished Professor of Liaoning Province (No. 2015399) are gratefully acknowledged.

Supplementary material

10904_2017_754_MOESM1_ESM.doc (34.2 mb)
Supplementary material 1 (DOC 34975 KB)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2017

Authors and Affiliations

  • Xiuli Wang
    • 1
  • Jing Zhao
    • 1
  • Mao Le
    • 1
  • Hongyan Lin
    • 1
  • Juan Luan
    • 1
  • Guocheng Liu
    • 1
  • Xiang Wang
    • 1
  1. 1.Department of ChemistryBohai UniversityJinzhouPeople’s Republic of China

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