Single Crystal of New Nanostructure Self-Assembled Copper–Cyanide and Hexamethylenetetramine as an Efficient Supramolecular Coordination Polymer Catalyst

  • Safaa Eldin H. Etaiw
  • Dina M. Abd El-Aziz
  • Safaa N. Abdou
Article
  • 52 Downloads

Abstract

Yellow prismatic nanoparticles of the supramolecular coordination polymer (SCP) [Cu6(CN)7(C6H12N4)2(OH3)], 1 were obtained by the reaction of K3[Cu(CN)4] and hexamethylenetetramine (hmt) in presence of Me3SnCl at ambient conditions. The X-ray structure of 1 consists of many rhombic [(Cu)2µ3–(CN)2] motifs which construct eight fused cyclic rings accommodating two hmt ligands. The copper atoms exhibit pseudo-tetrahedral configuration. The cyanide ligands create the bifurcated µ3-CN bridges. The [(Cu)2µ3–(CN)2] motifs causes expansion of the structure of 1 to three dimensions while extensive H-bonds play an essential role in packing structure. SCP 1 was used as an efficient heterogeneous catalyst for oxidative mineralization of acid blue-92 (AB-92), textile dye, with H2O2. The study aimed to investigate the efficiency of recycled the catalyst 1 and the mechanism of degradation of AB-92. The morphological feature of the SCP 1 as a catalyst before and after catalysis was examined by high resolution transmission electron microscope (TEM).

Keywords

Cu(I)CN Nanoparticles Supramolecular coordination polymer Hexamethylenetetramine Acid blue-92 Catalytic activity 

Supplementary material

10904_2017_749_MOESM1_ESM.docx (496 kb)
Supplementary material 1 (DOCX 496 KB)

References

  1. 1.
    R.H. Wang, L. Han, L.J. Xu, Y.Q. Gong, Y.F. Zhou, M.C. Hong, A.S.C. Chan, Eur. J. Inorg. Chem. 18, 3751 (2004)Google Scholar
  2. 2.
    T.A. Tronic, K.E. deKrafft, M.J. Lim, A.N. Ley, R.D. Pike, Inorg. Chem. 46(21), 8897 (2007)CrossRefGoogle Scholar
  3. 3.
    S. Pagola, R.D. Pike, K.E. deKrafft, T.A. Tronic, Acta Cryst. Sect. C 64, 134 (2008)CrossRefGoogle Scholar
  4. 4.
    I. Jess, C. Näther, Acta Crystallogr. Sect. E 62(4), 721 (2006)CrossRefGoogle Scholar
  5. 5.
    S.E.H. Etaiw, A.S. Sultan, M.M. El-bendary, J. Organomet. Chem. 696, 1668 (2011)CrossRefGoogle Scholar
  6. 6.
    S.E.H. Etaiw, A.S. Sultan, A.S. Badr El-din. Eur. J. Med. Chem. 46, 5370 (2011)CrossRefGoogle Scholar
  7. 7.
    S.E.H. Etaiw, S.A. Amer, M.M. El-bendary, J. Inorg. Organomet. Polym. 21, 662 (2011)CrossRefGoogle Scholar
  8. 8.
    S.E.H. Etaiw, A.S. Fouda, S.N. Abdou, M.M. El-bendary, Corros. Sci. 53, 3657 (2011)CrossRefGoogle Scholar
  9. 9.
    S.E.H. Etaiw, M.E. El-Zaria, T.A. Fayed, S.N. Abdou, J. Inorg. Organomet. Polym. 21, 465 (2011)CrossRefGoogle Scholar
  10. 10.
    R.D. Pike, K.E. deKrafft, A.N. Ley, T.A. Tronic, Chem. Comm. 36, 3732 (2007)CrossRefGoogle Scholar
  11. 11.
    C.B. Aakeröy, N.R. Champness, C. Janiak, Cryst. Eng. Comm. 12, 22 (2010)CrossRefGoogle Scholar
  12. 12.
    C. Janiak, Dalton Trans. 14, 2781 (2003)CrossRefGoogle Scholar
  13. 13.
    A.Y. Robin, K.M. Fromm, Coord. Chem. Rev. 250, 2127 (2006)CrossRefGoogle Scholar
  14. 14.
    S.-L. Zheng, M.-L. Tong, X.-M. Chen, Coord. Chem. Rev. 246, 185 (2003)CrossRefGoogle Scholar
  15. 15.
    P. Afanasiev, J. Solid State Chem. 239, 69 (2016)CrossRefGoogle Scholar
  16. 16.
    M.T. Harvey, Further Studies on Phenolic Hexamethylenetetramine Compounds (Biblio Bazaar, Charleston, 2009)Google Scholar
  17. 17.
    S. Hazra, B. Sarkar, S. Naiya, M.G.B. Drew, A. Ghosh, Inorg. Chim. Acta 402, 12 (2013)CrossRefGoogle Scholar
  18. 18.
    K. Ezzayani, A. Ben Khelifa, E. Saint-Aman, F. Loiseau, H. Nasri, J. Mol. Struct. 1137, 412 (2017)CrossRefGoogle Scholar
  19. 19.
    J. Pickardt, Acta Cryst. B37(9), 1753 (1981)CrossRefGoogle Scholar
  20. 20.
    J. Pickardt, Z. Naturforsch, B Chem. Sci. 36(10), 1225 (1981)Google Scholar
  21. 21.
    S.E.H. Etaiw, M.M. El-bendary, Appl. Catal. B 126, 326 (2012)CrossRefGoogle Scholar
  22. 22.
    S.E.H. Etaiw, D.I. Saleh, Spectrochim. Acta Part A 117, 54 (2014)CrossRefGoogle Scholar
  23. 23.
    R.G. El-sharkawy, A.S. Badr, S.E.H. El-din, Etaiw, Spectrochim. Acta Part A 79, 1969 (2011)CrossRefGoogle Scholar
  24. 24.
    A. Goshadrou, A. Moheb, Desalination 269, 170 (2011)CrossRefGoogle Scholar
  25. 25.
    A. Khataee, S. Saadi, B. Vahid, S.W. Joo, B. Min, Ultrason. Sonochem. 29, 27 (2016)CrossRefGoogle Scholar
  26. 26.
    Y.P. Zhang, S.H. Lee, K.R. Reddy, A.I. Gopalan, K.P. Lee, J. Appl. Polym. Sci. 104, 2743 (2007)CrossRefGoogle Scholar
  27. 27.
    K.R. Reddy, M. Hassan, V.G. Gomes, Appl. Catal. A: Gen. 489, 1 (2015)CrossRefGoogle Scholar
  28. 28.
    M. Hassan, E. Haque, K.R. Reddy, A.I. Minett, J. Chen, V.G. Gomes, Nanoscale 6, 11988 (2014)CrossRefGoogle Scholar
  29. 29.
    K.R. Reddy, V.G. Gomes, M. Hassan, Mater. Res. Express 1, 015012‏ (2014)CrossRefGoogle Scholar
  30. 30.
    K.R. Reddy, K.P. Lee, A.I. Gopalan, Colloid Surf. A 320, 49 (2008)CrossRefGoogle Scholar
  31. 31.
    F.B. Stocker, T.P. Staeva, C.M. Rienstra, D. Britton, Inorg. Chem. 38(5), 984 (1999)CrossRefGoogle Scholar
  32. 32.
    G.M. Sheldrick, “SHELXL-97.” Program for crystal-structure refinement (University of Gottingen, Germany, 1997)Google Scholar
  33. 33.
    A. Altomare, G. Cascarano, C. Giacovazzo, A. Guagliardi, M.C. Burla, G. Polidori, M. Camalli, J. Appl. Cryst. 27, 435 (1994)Google Scholar
  34. 34.
    Y. Bai, W.-L. Shang, D.-B. Dang, J.-D. Sun, H. Gao, Spectrochim. Acta A 72, 407 (2009)CrossRefGoogle Scholar
  35. 35.
    J.K. Clegg, S.S. Iremonger, M.J. Hayter, P.D. Southon, R.B. Macquart, M.B. Duriska, P. Jensen, P. Turner, K.A. Jolliffe, C.J. Kepert, G.V. Meehan, L.F. Lindoy, Angew. Chem. Int. Ed. 49(6), 1075 (2010)CrossRefGoogle Scholar
  36. 36.
    M.A.S. Goher, M.R. Saber, R.G. Mohamed, A.K. Hafez, F.A. Mautner, J. Coord. Chem. 62(2), 234 (2009)CrossRefGoogle Scholar
  37. 37.
    M. Xue, G. Zhu, H. Ding, L. Wu, X. Zhao, Z. Jin, S. Qiu, Cryst. Growth Des. 9(3), 1481 (2009)CrossRefGoogle Scholar
  38. 38.
    J.-J. Wang, Z. Chang, A.-S. Zhang, T.-L. Hu, X.-H. Bu, Inorg. Chim. Acta 363(7), 1377 (2010)CrossRefGoogle Scholar
  39. 39.
    S. Konar, S.C. Manna, E. Zangrando, T. Mallah, J. Ribas, N.R. Chaudhuri, Eur. J. Inorg. Chem. 21, 4202 (2004)CrossRefGoogle Scholar
  40. 40.
    S.R. Batten, B.F. Hoskins, R. Robson, Chem. Eur. J. 6(1), 156 (2000)CrossRefGoogle Scholar
  41. 41.
    M.J. Lim, C.A. Murray, T.A. Tronic, K.E. de Krafft, A.N. Ley, J.C. de Butts, R.D. Pike, H. Lu, H.H. Patterson, Inorg. Chem. 47(15), 6931 (2008)CrossRefGoogle Scholar
  42. 42.
    Y. Wang, T.-A. Okamura, W.-Y. Sun, N. Ueyamahttp, Cryst. Growth Des. 8(3), 802 (2008)CrossRefGoogle Scholar
  43. 43.
    S.H. Etaiw, S.N. Abdou, A.S. Badr El-din, J. Inorg. Organomet. Polym. 25, 1478 (2015)CrossRefGoogle Scholar
  44. 44.
    D.J. Chesnut, D. Plewak, J. Zubieta, J. Chem. Soc. Dalton Trans. 18, 2567 (2001)CrossRefGoogle Scholar
  45. 45.
    A.M.A. Ibrahim, E. Siebel, R.D. Fischer, Inorg. Chem. 37(14), 3521 (1998)CrossRefGoogle Scholar
  46. 46.
    T. Pretsch, J. Ostmann, C. Donner, M. Nahorska, J. Mroziński, H. Hartl, Inorg. Chim. Acta 358(8), 2558 (2005)CrossRefGoogle Scholar
  47. 47.
    S.E.H. Etaiw, A.S. Badr, S.N. El-din, Abdou, Trans. Met. Chem. 41(4), 413 (2016)CrossRefGoogle Scholar
  48. 48.
    H. Hanika-Heidl, S.E.H. Etaiw, R.D. Fischer, M.Sh. Ibrahim, A.S.B. El-din. J. Organomet. Chem. 684, 329 (2003)CrossRefGoogle Scholar
  49. 49.
    J.H. Yu, J.Q. Xu, Q.X. Yang, L.Y. Pan, T.G. Wang, C.H. Lu, T.H. Ma, J. Mol. Str. 658, 1 (2003)CrossRefGoogle Scholar
  50. 50.
    O. Steigelmann, P. Bissinger, H. Schmidbaur, Angew. Chem. Int. Ed. Engl. 29(12), 1399 (1990)CrossRefGoogle Scholar
  51. 51.
    A.F. Wells, Z. Kristallogr. 94, 447 (1936)Google Scholar
  52. 52.
    S. Hazra, S. Biswas, A.M. Kirillov, A. Ghosh, Polyhedron 79, 66 (2014)CrossRefGoogle Scholar
  53. 53.
    R.A. Penneman, L.H. Jones, J. Chem. Phys. 24(2), 293 (1956)CrossRefGoogle Scholar
  54. 54.
    S.J. Hibble, S.G. Eversfield, A.R. Cowley, A.M. Chippindale, Angew. Chem. Int. Ed. 43(5), 628 (2004)CrossRefGoogle Scholar
  55. 55.
    G.A. Bowmaker, K.C. Lim, B.W. Skelton, A.H. White, Z. Naturforsch. 59b, 1264 (2004)Google Scholar
  56. 56.
    M.H. Begemann, C.S. Gudeman, J. Pfaff, R.J. Saykally, Phys. Rev. Lett. 51(7), 554 (1983)CrossRefGoogle Scholar
  57. 57.
    M.H. Begemann, R.J. Saykally, J. Chem. Phys. 82(8), 3570 (1985)CrossRefGoogle Scholar
  58. 58.
    J. Tang, T. Oka, J. Mol. Spec. 196(1), 120 (1999)CrossRefGoogle Scholar
  59. 59.
    M. Okumura, L.I. Yeh, J.D. Myers, Y.T. Lee, J. Phys. Chem. 94(9), 3416 (1990)CrossRefGoogle Scholar
  60. 60.
    D. Fãrcasiu, P. Lukinskas, D. Hâncu, J. Mol. Model. 6(2), 171 (2000)CrossRefGoogle Scholar
  61. 61.
    S.E.H. Etaiw, S.N. Abdou, Inorg. Organomet. Polym. 20(4), 622 (2010)CrossRefGoogle Scholar
  62. 62.
    C.A. Bayse, T.P. Brewster, R.D. Pike, Inorg. Chem. 48(1), 174 (2009)CrossRefGoogle Scholar
  63. 63.
    D. Coelho, A. Sampaio, C.J.S.M. Silva, H.P. Felgueiras, M.T.P. Amorim, A. Zille, ACS Appl. Mater. Interfaces 9(38), 33107 (2017)CrossRefGoogle Scholar
  64. 64.
    K.R. Reddy, K.O.T. Nakata, T. Murakami, D.A. Tryk, A. Fujishima, J. Nanosci. Nanotechnol. 11(4), 3692 (2011)CrossRefGoogle Scholar
  65. 65.
    K.R. Reddy, K.V. Karthik, S.B. Benaka Prasad, S.K. Soni, H.M. Jeong, A.V. Raghu, Polyhedron 120, 169 (2016)CrossRefGoogle Scholar
  66. 66.
    S.E.H. Etaiw, A.S. Elsherbiny, A.S. Badr El-din. Chin. J. Chem 29, 1401 (2011)CrossRefGoogle Scholar
  67. 67.
    A. Theodoridis, J. Maigut, R. Puchta, E.V. Kudrik, R. van Eldik, Inorg. Chem. 47(8), 2994 (2008)CrossRefGoogle Scholar
  68. 68.
    Z. Yu, S.C. Chuang, J. Phys. Chem. C 111(37), 13813 (2007)CrossRefGoogle Scholar
  69. 69.
    J. Yu, Q. Xiang, M. Zhou, Appl. Catal. B 90, 595 (2009)CrossRefGoogle Scholar
  70. 70.
    M. Sahni, B.R. Locke, Ind. Eng. Chem. Res. 45, 5819 (2006)CrossRefGoogle Scholar
  71. 71.
    J.L. Lefferts, K.C. Molly, M.B. Hossain, D. Vander Helen, J.J. Zucker-man, J. Organomet. Chem. 240, 349 (1982)CrossRefGoogle Scholar
  72. 72.
    P. Avalle, R.K. Harris, H. Hanika-Hiedle, R.D. Fischer, Solid State Sci. 6, 1069 (2004)CrossRefGoogle Scholar
  73. 73.
    C. Noubactep, G. Meinrath, P. Dietrich, M. Sauter, B. Merkel, Environ. Chem. 2, 71 (2005)CrossRefGoogle Scholar
  74. 74.
    D.H. Bremner, R. Molina, F. Mart nez, J.A. Melero, Y. Segura, Appl. Cat. B 90, 380 (2009)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2017

Authors and Affiliations

  • Safaa Eldin H. Etaiw
    • 1
  • Dina M. Abd El-Aziz
    • 1
  • Safaa N. Abdou
    • 2
  1. 1.Chemistry Department, Faculty of ScienceTanta UniversityTantaEgypt
  2. 2.Chemistry Department, Faculty of Education (Khourma)Taif UniversityTaifSaudi Arabia

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