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Zirconia Sulphate Dispersed Polymer Composites for Electronic Applications

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Abstract

We prepared polymer composites by dispersion of crystalline inorganic zirconium sulphate (ZrSO4)2 with polymer polyvinyl alcohol (PVA) system. Variation in Semi-crystalline phase of composites confirmed by X-ray diffraction technique. Decrease in direct band gap (Eg) has been demonstrated by Ultraviolet–visible spectroscopy technique. Chemical modification of PVA moiety addressed by FTIR tool. Optical microscopy illustrates miscibility of organometallic with polymer system. Scanning electron microscopy demonstrates the functional network of organo metallic filler in the polymer system. Atomic force microscopy, lateral topographic (2D, 3D) micrographs locate the subatomic network of fillers. The thermogravimetry technique exhibit the moderate increase in the glass transition (Tg), degradation (Td) and melting (Tm) temperature. Dielectric constant (Ɛr) has been measured as a function of frequency. The dissipation factor in PVA/Zr(SO4)2 decreases due to the homogenous integration of crystalline zirconia with semi crystalline system of PVA. The shore ‘A’ durometer test confirms the softness of miscible blends.

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Acknowledgements

The authors would like to thank Naval Research Board, Defence Research and Development Organization (NRB-DRDO), New Delhi Project No. 259/Mat./11-12, for providing the instrumentation facility of electrical characterization. Authors also thanks to VIT University for providing the facilities of SEM under DST-FIST project and Center for Crystal Growth for optical microscopy techniques. The authors would like to acknowledge SAS, VIT University, Vellore, for providing the central facilities of XRD, UV-Vis-NIR, TGA and FTIR spectroscopy.

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  1. Polymer Nanocomposite Laboratory, Center for Crystal Growth, VIT University, Vellore, Tamilnadu, 632014, India

    Joseph Anandraj & Girish M. Joshi

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  1. Joseph Anandraj
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Correspondence to Girish M. Joshi.

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Anandraj, J., Joshi, G.M. Zirconia Sulphate Dispersed Polymer Composites for Electronic Applications. J Inorg Organomet Polym 27, 1835–1850 (2017). https://doi.org/10.1007/s10904-017-0649-y

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