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Synthesis and Characterization of New Organometallic Hybrid Material LCP-1 Based on MOF (Metal–Organic Framework) and Maghnite-H+, a Protons Exchanged Montmorillonite Clay, as Catalytic Support

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Abstract

In this work, a new 3D crystalline metal–organic framework formulated as [Zn2(BTC)4, (BTC: 1,2,4,5-Benzenetetracarboxylate)] and called LCP-1 (LCP: Laboratoire de Chimie des Polymères), with unsaturated coordinated Zn(II) sites as metal ion and pyromellitic acid (H4BTC: 1,2,4,5-Benzenetetracarboxylic acid) as organic ligand, has been successfully synthesized under solvothermal conditions. In-Situ polymerization of this material was also carried out using an amount of clay called Maghnite-H+, an acid-exchanged montmorillonite, as an eco-catalyst with the aim to respect the principles of green chemistry, to give a new hybrid composite material LCP-1/Mag-H+ with a better yield, a significantly reduced time and temperature reaction than those of LCP-1. LCP-1 and LCP-1/Mag-H+ have been structurally characterized and established by fourier transform infrared spectroscopy (FT-IR). The morphology of these compounds was studied by the X-ray diffraction (XRD) and revealed a highly crystalline and ordered structure for both LCP-1 and LCP-1/Mag-H+. FT-IR and XRD spectra showed also that the stability and structural integrity of LCP-1 and LCP-1/Mag-H+ was maintained even after being evacuated from the DMF solvent molecules. The thermal stability identified by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) showed that Maghnite-H+, as inorganic support, has also improved the thermal stability of LCP-1 compound.

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Acknowledgements

The authors would like to especially thank A. Addou (Laboratory of Polymer Chemistry, University of Oran1 Amed Benbella, Algeria) for FT-IR, XRD and TGA analysis.

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  1. Laboratory of Polymer Chemistry, Department of Chemistry, Faculty of Exact and Applied Sciences, University of Oran1 Ahmed BenBella, BP 1524 El M’Naouar, 31000, Oran, Algeria

    Souad Bennabi & Mohammed Belbachir

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  1. Souad Bennabi
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  2. Mohammed Belbachir
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Correspondence to Souad Bennabi.

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Bennabi, S., Belbachir, M. Synthesis and Characterization of New Organometallic Hybrid Material LCP-1 Based on MOF (Metal–Organic Framework) and Maghnite-H+, a Protons Exchanged Montmorillonite Clay, as Catalytic Support. J Inorg Organomet Polym 27, 1787–1799 (2017). https://doi.org/10.1007/s10904-017-0643-4

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  • DOI: https://doi.org/10.1007/s10904-017-0643-4

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