Binding of Cobaltocenium-Containing Polyelectrolytes with Anionic Probes

Abstract

Cationic cobaltocenium-containing polyelectrolytes have a unique ability to form ionic complex with various anionic species. We carried out two sets of model study to compare the relative binding strength of a cobaltocenium-containing polyelectrolyte. First, the nature and relative strength of intermolecular interaction between cobaltocenium-containing polyelectrolytes and different anionic probes were investigated by spectroscopic methods. A dye-displacement method was used to monitor absorbance and fluorescence emissions. Second, the binding strength of this cobaltocenium-containing polyelectrolyte was compared with a classical quaternary ammonium polymer. Formation of polyelectrolyte complex between the cobaltocenium-containing polyelectrolyte and a common anionic polyelectrolyte at various concentrations was examined by optical absorption and light scattering.

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Acknowledgements

The support from National Institutes of Health (R01AI120987) is acknowledged.

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Correspondence to Chuanbing Tang.

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Pageni, P., Kabir, M.P., Yang, P. et al. Binding of Cobaltocenium-Containing Polyelectrolytes with Anionic Probes. J Inorg Organomet Polym 27, 1100–1109 (2017). https://doi.org/10.1007/s10904-017-0561-5

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Keywords

  • Metallopolymers
  • Polyelectrolytes
  • Cobaltocenium
  • Ion-binding
  • Polyelectrolyte complex