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Two New Cobalt Supramolecular Complexes Assembled From Triazole Derivatives

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Abstract

Two new complexes [Co3(Htrz)6(H2O)6](NO3)6·2H2O (1) and [Co3(Hdatrz)6(H2O)6](ClO4)6·4H2O (2) (Htrz = 1 H-1,2,4-triazole, Hdatrz = 3,5-diamino-1H-1,2,4-triazole) were synthesized at room temperature and characterized by elemental analysis, IR and TG-DTG and DSC. X-ray diffraction analyses. The two complexes consisted of similar linear trinuclear Co(II) units displaying 3D supramolecular architectures linked by a number of hydrogen bonding interactions. Thermal stability of the main frame of complex 2 is higher than 200 °C.

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Acknowledgements

The authors thank the financial support from the Welch Foundation (Grant No. BC-0022). We thank Dr. J. D. Korp for conducting the single crystal X-ray analyses of Complex 1. This work made use of MRSEC/TCSUH Shared Experimental Facilities supported by the National Science Foundation and the Texas Center for Superconductivity at the University of Houston. We’re very grateful for the financial support from the National Natural Science Foundation of China (Grant No. 21673181).

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Authors and Affiliations

  1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi’an, 710127, Shaanxi, People’s Republic of China

    Qi Yang

  2. Department of Chemistry, University of Houston-Clear Lake, 2700 Bay Area Blvd., Houston, TX, 77058, USA

    Qi Yang & Jack Y. Lu

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  1. Qi Yang
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  2. Jack Y. Lu
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Correspondence to Jack Y. Lu.

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Yang, Q., Lu, J.Y. Two New Cobalt Supramolecular Complexes Assembled From Triazole Derivatives. J Inorg Organomet Polym 27, 1122–1127 (2017). https://doi.org/10.1007/s10904-017-0560-6

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