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A Nano Nickel (II) Metal–Organic Coordination Compound for Nano Nickel (II) Oxide: Sonochemical Synthesis and Characterization

  • Younes Hanifehpour
  • Babak Mirtamizdoust
  • Ruiyao Wang
  • Saeed Anbarteh
  • Sang Woo Joo
Article
  • 161 Downloads

Abstract

A sonochemical method was used to synthesize a nickel (II) coordination complex, [Ni(phen)3](BF4)2·H2O}n (1) (phen = 1,10-phenamthroline), with particle sizes in the range of 40–120 nm. The new nanostructure was characterized by scanning electron microscopy (SEM), X-ray powder diffraction (PXRD), infrared, and elemental analyses. Compound 1 was structurally characterized by single-crystal X-ray diffraction, and the data show that the Ni(II) ions are coordinated by six N-donor atoms from three phen ligands. The charge was balanced by two tetrafluoroborate anions. The supramolecular features in these complexes are guided and controlled by weak directional intermolecular interactions. They are further extended into a three-dimensional (3-D) supramolecular structure by weak π–π directional intermolecular interactions. Cubic NiO nanoparticles with sizes of 5–40 nm were obtained by thermolysis of 1 at 180 °C.

Keywords

Nano complex Ni(II) 1,10-Phenamthroline Ultrasonic irradiation Nano nickel oxide Crystal structure 

Notes

Acknowledgements

The kind support for this investigation by the University of Qom is gratefully acknowledged. This work was funded by grant NRF-2015-002423 from the National Research Foundation of Korea.

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Copyright information

© Springer Science+Business Media New York 2017

Authors and Affiliations

  1. 1.School of Mechanical Engineering, WCU Nano Research CenterYeungnam UniversityGyeongsanSouth Korea
  2. 2.Department of Chemistry, Faculty of ScienceUniversity of QomQomIran
  3. 3.Department of ChemistryXi’an Jiaotong-Liverpool UniversitySuzhouPeople’s Republic of China

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