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Anatase-Titania Templated by Nanofibrillated Cellulose and Photocatalytic Degradation for Methyl Orange

  • He Xiao
  • Junrong Li
  • Beihai He
Article

Abstract

In this work, novel titania (TiO2) nanoparticles were designed as a high performance photocatalyst. It was obtained by a simple method of dispersing nanofibrillated cellulose (NFC) onto the surface of titanium tetrachloride (TiCl4), inducing crystallization and removing NFC templates. Under UV light irradiation, The TiO2 nanoparticles displayed excellent photocatalytic activity for the decomposition of methyl orange solution. It was found that TiO2 after calcination had a more efficiency than that before calcination. The optimum calcination temperature for the removal of NFC templates was 300 °C. Methyl orange solution had been remarkably degraded by TiO2 nanoparticles when the mass ratio of TiCl4 and NFC was 12:1. These results indicate that the TiO2 nanopartilces can be easily applied in the field of wastewater treatment.

Keywords

Nanofibrillated cellulose Template TiO2 Photocatalyst 

Notes

Acknowledgements

This work was supported by State Key Laboratory of Pulp and Paper Engineering (201617), Fujian Science and Technology of Education Department Fund (JAT160151), Fujian Innovation and Entrepreneurship Training Program (201610389083).

References

  1. 1.
    Y.Y. Kim, C. Neudeck, D. Walsh, Biopolymer templating as synthetic route to functional metal oxide nanoparticles and porous sponges. Polym. Chem. 1(3), 272–275 (2010)CrossRefGoogle Scholar
  2. 2.
    B. Boury, S. Plumejeau, Metal oxides and polysaccharides: an efficient hybrid association for materials chemistry. Green Chem. 17(1), 72–88 (2015)CrossRefGoogle Scholar
  3. 3.
    A. Ivanova, D. Fattakhova-Rohlfing, B.E. Kayaalp et al., Tailoring the morphology of mesoporous titania thin films through biotemplating with nanocrystalline cellulose. J. Am. Chem. Soc. 136(16), 5930–5937 (2014)CrossRefPubMedGoogle Scholar
  4. 4.
    J.H. Kim, J.H. Kim, E.S. Choi et al., Colloidal silica nanoparticle-assisted structural control of cellulose nanofiber paper separators for lithium-ion batteries. J. Power Sources 242, 533–540 (2013)CrossRefGoogle Scholar
  5. 5.
    F.Y. Fu, L.Y. Li, L.J. Liu et al., Construction of cellulose based ZnO nanocomposite films with antibacterial properties through one-step coagulation. ACS Appl. Mater. Interfaces 7(4), 2597–2606 (2015)CrossRefPubMedGoogle Scholar
  6. 6.
    M.A. Mohamed, W. Salleh, J. Jaafar et al., Incorporation of N-doped TiO2 nanorods in regenerated cellulose thin films fabricated from recycled newspaper as a green portable photocatalyst. Carbohydr. Polym. 133, 429–437 (2015)CrossRefPubMedGoogle Scholar
  7. 7.
    X.Y. Chen, D.H. Kuo, D.F. Lu et al., Synthesis and photocatalytic activity of mesoporous TiO2 nanoparticle using biological renewable resource of un-modified lignin as a template. Microporous Mesoporous Mater. 223, 145–151 (2016)CrossRefGoogle Scholar
  8. 8.
    J. Liu, W.Y. Li, Y.G. Liu et al., Titanium(IV) hydrate based on chitosan template for defluoridation from aqueous solution. Appl. Surf. Sci. 293, 46–54 (2014)CrossRefGoogle Scholar
  9. 9.
    M.C. Kimling, R.A. Caruso, Sol–gel synthesis of hierarchically porous TiO2 beads using calcium alginate beads as sacrificial templates. J. Mater. Chem. 22(9), 4073–4082 (2012)CrossRefGoogle Scholar
  10. 10.
    A. Henry, S. Plumejeau, L. Heux et al., Conversion of nanocellulose aerogel into TiO2 and TiO2@C nano-thorns by direct anhydrous mineralization with TiCl4. Evaluation of electrochemical properties in Li batteries. ACS Appl. Mater. Interfaces 7(27), 14584–14592 (2015)CrossRefPubMedGoogle Scholar
  11. 11.
    B. Boury, R.G. Nair, S.K. Samdarshi et al., Non-hydrolytic synthesis of hierarchical TiO2 nanostructures using natural cellulosic materials as both oxygen donors and templates. New J. Chem. 36(11), 2196–2200 (2012)CrossRefGoogle Scholar
  12. 12.
    H. Ceylan, C. Ozgit-Akgun, T.S. Erkal et al., Size-controlled conformal nanofabrication of biotemplated three-dimensional TiO2 and ZnO nanonetworks. Sci. Rep. 3, 1–7 (2013)Google Scholar
  13. 13.
    D.H. Yu, X.D. Yu, C.H. Wang et al., Synthesis of natural cellulose-templated TiO2/Ag nanosponge composites and photocatalytic properties. ACS Appl. Mater. Interfaces 4(5), 2781–2787 (2012)CrossRefPubMedGoogle Scholar
  14. 14.
    Z.D. Li, C.H. Yao, F. Wang et al., Cellulose nanofiber-templated three-dimension TiO2 hierarchical nanowire network for photoelectrochemical photoanode. Nanotechnology 25(50), 1–10 (2014)Google Scholar
  15. 15.
    Y. Lu, Q.F. Sun, T.C. Liu et al., Fabrication, characterization and photocatalytic properties of millimeter-long TiO2 fiber with nanostructures using cellulose fiber as a template. J. Alloys Compd. 577, 569–574 (2013)CrossRefGoogle Scholar
  16. 16.
    N. Olaru, G. Galin, L. Olaru, Zinc oxide nanocrystals grown on cellulose acetate butyrate nanofiber mats and their potential photocatalytic activity for dye degradation. Indus. Eng. Chem. Res. 53(46), 17968–17975 (2014)CrossRefGoogle Scholar
  17. 17.
    B. Tryba, A.W. Morawski, M. Inagaki, A new route for preparation of TiO2-mounted activated carbon. Appl. Catal. B 46(1), 203–208 (2003)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2017

Authors and Affiliations

  1. 1.College of Materials EngineeringFujian Agriculture and Forestry UniversityFuzhouChina
  2. 2.State Key Laboratory of Pulp and Paper EngineeringSouth China University of TechnologyGuangzhouChina

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