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Synthesis, Characterization, and Magnetic Properties of Two Transition Metal Coordination Polymers Based on 2,5-Furandicarboxylic Acid and N-Donor Ligands

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Abstract

Two new transition metal-based coordination polymers, [Cu(fdc)(dmbpy)(H2O)]n (1) {[Ni2(fdc)2(bipy)2(H2O)4]·(H2O)2}n (2) (fdca = 2,5-furandicarboxylic acid, dmbpy = 3,3′-dimethyl-4,4′-bipyridine, bipy = 4,4′-bipyridine) have been synthesized under the same reaction conditions (H2O, pH 7–8, and 130 °C) and were structurally characterized. 1 is a ladder chain, whereas 2 shows a 2D (4,4) network. Both 1 and 2 are further connected into 3D structures through hydrogen bonds. Furthermore, the magnetic properties of 1 and 2 are also investigated.

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References

  1. S. Qiao, H. Wei, T. Wang, W. Huang, C. Gu, R. Yang, X. Li, New J. Chem. 40, 3172 (2016)

    Article  CAS  Google Scholar 

  2. J. Li, H.R. Fu, J. Zhang, L.S. Zheng, J. Tao, Inorg. Chem. 54, 3093 (2015)

    Article  CAS  Google Scholar 

  3. L.N. Duan, Q.Q. Dang, C.Y. Han, X.M. Zhang, Dalton Trans. 44, 1800 (2015)

    Article  CAS  Google Scholar 

  4. M. Yoon, R. Srirambalaji, K. Kim, Chem. Rev. 112, 1196 (2012)

    Article  CAS  Google Scholar 

  5. C.L. Chang, X.Y. Qi, J.W. Zhang, Y.M. Qiu, X.J. Li, X. Wang, Y. Bai, J.L. Sun, H.W. Liu, Chem. Commun. 51, 3566 (2015)

    Article  CAS  Google Scholar 

  6. H.Y. Li, Y.L. Wei, X.Y. Dong, S.Q. Zang, T.C.W. Mak, Chem. Mater. 27, 1327 (2015)

    Article  CAS  Google Scholar 

  7. D.Y. Ma, Z. Li, J.X. Xiao, R. Deng, P.F. Lin, R.Q. Chen, Y.Q. Liang, H.F. Guo, B. Liu, J.Q. Liu, Inorg. Chem. 54, 6719 (2015)

    Article  CAS  Google Scholar 

  8. X. Zhang, W. Wang, Z. Hu, G. Wang, K. Uvdal, Coord. Chem. Rev. 284, 206 (2015)

    Article  CAS  Google Scholar 

  9. S. Sanda, S. Parshamoni, S. Biswas, S. Konar, Chem. Commun. 51, 6576 (2015)

    Article  CAS  Google Scholar 

  10. G. Zhang, G. Yang, Q. Chen, J.S. Ma, Cryst. Growth Des. 5, 661 (2005)

    Article  CAS  Google Scholar 

  11. Y.Q. Lan, S.L. Li, J.S. Qin, D.Y. Du, X.L. Wang, Z.M. Su, Q. Fu, Inorg. Chem. 47, 10600 (2008)

    Article  CAS  Google Scholar 

  12. F. Bu, Q. Lin, Q. Zhai, L. Wang, T. Wu, S.T. Zheng, X. Bu, P. Feng, Angew. Chem. Int. Ed. 51, 8538 (2012)

    Article  CAS  Google Scholar 

  13. F.P. Huang, J.L. Tian, G.J. Chen, D.D. Li, W. Gu, X. Liu, S.P. Yan, D.Z. Liao, P. Cheng, Cryst. Eng. Comm. 12, 1269 (2010)

    Article  CAS  Google Scholar 

  14. K. Biradha, M. Sarkar, L. Rajput, Chem. Commun. 40, 4169 (2006)

    Article  Google Scholar 

  15. H. Guo, J. Lei, L. Qin, Y. Liang, J. Yan, W. Lin, W. Ding, H. Sakiyama, J. Liu, D. Ma, J. Inorg. Organomet. Polym. 26, 413 (2016)

    Article  CAS  Google Scholar 

  16. F.N. Shi, D. Ananias, T.H. Yang, J. Rocha, J. Solid State Chem. 204, 321 (2013)

    Article  CAS  Google Scholar 

  17. M. Rose, D. Weber, B.V. Lotsch, R.K. Kremer, R. Goddard, R. Palkovits, Microporous Mesoporous Mater. 181, 217 (2013)

    Article  CAS  Google Scholar 

  18. R. Sen, D. Mal, P. Brandao, R.A.S. Ferreira, Z. Lin, Cryst. Growth Des. 13, 5272 (2013)

    Article  CAS  Google Scholar 

  19. Y.F. Li, Y. Gao, X.L. Qin, Y. Xu, W.Y. Gao, L. Zhang, Inorg. Chem. Commun. 25, 86 (2012)

    Article  Google Scholar 

  20. Bruker, APEXII software, Version 6.3.1, Bruker AXS Inc., Madison, (2004)

  21. G.M. Sheldrick, Acta Cryst. A64, 112 (2008)

    Article  Google Scholar 

  22. J. Qin, C.X. Qian, N. Zhou, R.M. Zhu, Y.Z. Li, J.L. Zuo, X. You, Eur. J. Inorg. Chem. 2, 234 (2012)

    Article  Google Scholar 

  23. E.C. Yang, B. Ding, Z.Y. Liu, Y.L. Yang, X.J. Zhao, Cryst. Growth Des. 12, 1185 (2012)

    Article  CAS  Google Scholar 

  24. S. Das, S. Maloth, S. Pal, Eur. J. Inorg. Chem. 27, 4270 (2011)

    Article  Google Scholar 

  25. D. Venegas-Yazigi, E. Spodine, M. Saldias, A. Vega, V. Paredes-Garcia, R. Calvo, R.C. Santana, Inorg. Chem. 54, 3805 (2015)

    Article  CAS  Google Scholar 

  26. B.K. Tripuramallu, S. Mukherjee, S.K. Das, Cryst. Growth Des. 12, 5579 (2012)

    Article  CAS  Google Scholar 

  27. Z. Shi, S. Feng, L. Zhang, G. Yang, J. Hua, Chem. Mater. 12, 2930 (2000)

    Article  CAS  Google Scholar 

  28. R. Boca, Coord. Chem. Rev. 248, 757 (2004)

    Article  CAS  Google Scholar 

  29. R.L. Carlin, C.J. O’Connor, S.N. Bhatia, J. Am. Chem. Soc. 98, 3523 (1976)

    Article  CAS  Google Scholar 

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Acknowledgments

This work was supported by the Special Funds of Guangdong College Students’ scientific and Technological Innovation Cultivation (pdjh2016b0547), the Distinguished Young Talents in Higher Education of Guangdong Province (2014KQNCX222), the Natural Science Foundation of Guangdong Province (2015A030310407), the characteristics of innovative projects in Colleges and universities in Guangdong Province (2015KTSCX156), the Training Plan of Guangdong Province Outstanding Young Teachers in Higher Education Institutions (YQ2015168), the Natural Science Foundation of Zhaoqing University (201532) and JSPS KAKENHI (15K05445).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing, 526061, People’s Republic of China

    Deyun Ma, Peng Hu, Liang Qin, Jingjing Yan, Weijie Lin, Wanqiu Ding, Husheng Lu & Dongting Lin

  2. College of Life Science, Zhaoqing University, Zhaoqing, 526061, People’s Republic of China

    Fenglan Liang

  3. Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, Kojirakawa, Yamagata, 990-8560, Japan

    Hiroshi Sakiyama

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  1. Deyun Ma
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  2. Peng Hu
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  3. Liang Qin
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Correspondence to Liang Qin or Fenglan Liang.

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Ma, D., Hu, P., Qin, L. et al. Synthesis, Characterization, and Magnetic Properties of Two Transition Metal Coordination Polymers Based on 2,5-Furandicarboxylic Acid and N-Donor Ligands. J Inorg Organomet Polym 26, 1053–1060 (2016). https://doi.org/10.1007/s10904-016-0429-0

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  • DOI: https://doi.org/10.1007/s10904-016-0429-0

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