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Fe3O4@Hpipe-4@Cu Nanocatalyst for Hydrogenation of Nitro-Aromatics and Azo Dyes

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Abstract

In this study, a facile method is described for the Cu deposited Piperidine-4-carboxylic acid (Hpipe-4) coated magnetite (Fe3O4) nanoparticles. For which, Fe3O4 was used as magnetic core, Hpipe-4 as linker and active copper nanoparticles as the catalyst. For the reduction of Cu2+ to Cu0 was accomplished by NaBH4. The phase and morphology of the as-prepared product is characterized by means of X-ray powder diffractometry, energy dispersive spectrometry, Scanning electron microscopy. Magnetic and catalytic properties of the product were followed by vibrating sample magnetometer and UV–Vis spectrophometer respectively. Experiments showed that the as-prepared Fe3O4@Hpipe-4@Cu nanocatalyst owned strong catalytic activity for the reduction of some aromatic nitro-compounds and organic azo dyes and also emphasizes the effect of copper nanoparticles on the degradation of rate of hazardous compounds by NaBH4. Fe3O4@Hpipe-4@Cu nanocatalyst show great promise for the treatment of industrial dye pollutants hence environmental protection.

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References

  1. A. Manikandan, R. Sridhar, S. Arul Antony, S. Ramakrishna, J. Mol. Struct. 1076, 188–200 (2014)

    Article  CAS  Google Scholar 

  2. C.O. Hendren, X. Mesnard, J. Droge, M.R. Wiesner, Environ. Sci. Technol. 45, 2562–2569 (2011)

    Article  CAS  Google Scholar 

  3. R. Sharma, C. Sharma, Tetrahedron Lett. 51, 4415–4418 (2010)

    Article  CAS  Google Scholar 

  4. K. Chinnaraj, A. Manikandan, P. Ramu, S. Arul Antony, P. Neeraja, J. Supercond. Nov. Magn. 28, 179–190 (2015)

    Article  CAS  Google Scholar 

  5. N. Tripathy, R. Ahmad, J.E. Song, H.A. Ko, Y.B. Hahn, G. Khang, Mater. Lett. 136, 171–174 (2014)

    Article  CAS  Google Scholar 

  6. I.A. Salem, Transition Met. Chem. 25, 599–604 (2000)

    Article  CAS  Google Scholar 

  7. J. Fu, G.Z. Kyzas, Chin. J. Catal. 35, 1–7 (2014)

    Article  Google Scholar 

  8. N. Baliarsingh, K.M. Parida, G.C. Pradhan, Ind. Eng. Chem. Res. 53, 3834–3841 (2014)

    Article  CAS  Google Scholar 

  9. K.T. Chung, S.E. Stevens, Environ. Toxicol. Chem. 12, 2121–2132 (1993)

    CAS  Google Scholar 

  10. M.S. Lucas, J.A. Peres, Dyes Pigm. 71, 236–244 (2006)

    Article  CAS  Google Scholar 

  11. B. Ho, T.M. Zabriskie, Bioorg. Med. Chem. Lett. 8, 739 (1998)

    Article  CAS  Google Scholar 

  12. K. Lv, J. Wu, J. Wang, M. Liu, Z. Wei, J. Cao, Y. Sun, H. Guo, Bioorg. Med. Chem. Lett. 23, 1754–1759 (2013)

    Article  CAS  Google Scholar 

  13. S.T. Harini, H.V. Kumar, J. Rangaswamy, N. Naik, Bioorg. Med. Chem. Lett. 22, 7588–7592 (2012)

    Article  CAS  Google Scholar 

  14. G. Liu, C.H. Marrinan, S.A. Taylor, S. Black, A.D. Basso, P. Kirschmeier, W. Robert Bishop, M. Liu, B.J. Long, Anticancer Drugs 18, 923–931 (2007)

    Article  CAS  Google Scholar 

  15. X. Chen, P. Zhan, C. Pannecouque, J. Balzarini, E. De Clercq, X. Liu, Eur. J. Med. Chem. 51, 60–66 (2012)

    Article  Google Scholar 

  16. B.P. Bandgar, S.A. Patil, R.N. Gacche, B.L. Korbad, B.S. Hote, S.N. Kinkar, S.S. Jalde, Bioorg. Med. Chem. Lett. 20, 730–733 (2010)

    Article  CAS  Google Scholar 

  17. E. Hollink, S.E. Tichy, E.E. Simanek, Ind. Eng. Chem. Res. 44, 1634–1639 (2005)

    Article  CAS  Google Scholar 

  18. S.P. Frances, N. Van Dung, N.W. Beebe, M. Debboun, J. Med. Entomol. 39, 541–544 (2002)

    Article  CAS  Google Scholar 

  19. V.D. Vitnik, Z.J. Vitnik, Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 138, 1–12 (2015)

    Article  CAS  Google Scholar 

  20. S.I. Mostafa, Transition Met. Chem. 32, 769–777 (2007)

    Article  CAS  Google Scholar 

  21. K. Takahama, T. Miyata, Y. Okano, M. Kataoka, T. Hitoshi, Y. Kase, Eur. J. Pharmacol. 81, 327–335 (1982)

    Article  CAS  Google Scholar 

  22. M.F. Wilson, A.E. Bell, Phytochemistry 17, 403–411 (1978)

    Article  CAS  Google Scholar 

  23. C.M. Adams, E.A. Bernays, Entomol. Exp. Appl. 23, 101–108 (1978)

    Article  CAS  Google Scholar 

  24. E. Karaoglu, A. Baykal, M. Şenel, H. Sözeri, M.S. Toprak, Mater. Res. Bull. 47, 2480–2486 (2012)

    Article  CAS  Google Scholar 

  25. H. Erdemi, A. Baykal, E. Karaoğlu, M.S. Toprak, Mater. Res. Bull. 47, 2193–2199 (2012)

    Article  CAS  Google Scholar 

  26. E. Karaoglu, A. Baykal, H. Deligöz, M. Şenel, H. Sözeri, M.S. Toprak, J. Alloy. Compd. 509, 8460–8468 (2011)

    Article  CAS  Google Scholar 

  27. A. Manikandan, L. John Kennedy, J. Arul Mary, A. Dinesh, J. Judith Vijaya, J. Ind. Eng. Chem. 20, 2077–2085 (2014)

    Article  CAS  Google Scholar 

  28. M. Tang, S. Zhang, X. Li, X. Pang, H. Qiu, Mater. Chem. Phys. 148, 639–647 (2014)

    Article  CAS  Google Scholar 

  29. H. Kavas, Z. Durmus, A. Baykal, A. Aslan, A. Bozkurt, M.S. Toprak, J. Noncrystalline Solids 356, 484–489 (2010)

    Article  CAS  Google Scholar 

  30. B. Unal, M.S. Toprak, Z. Durmus, H. Sözeri, A. Baykal, J. Nanopart. Res. 12, 3039–3048 (2010)

    Article  CAS  Google Scholar 

  31. Z. Durmus, H. Kavas, A. Baykal, H. Sozeri, L. Alpsoy, S.Ü. Çelik, M.S. Toprak, J. Alloy. Compd. 509, 2555–2561 (2011)

    Article  CAS  Google Scholar 

  32. A.A.A. El-Deen, A.E.M.E.E. Askalany, R. Halaoui, B.J.J. Claude, I.S. Butler, S.I. Mostafa, J. Mol. Struc. 1036, 161–167 (2013)

    Article  Google Scholar 

  33. S.I. Mostafa, Transition Met. Chem. 32, 769–777 (2007)

    Article  CAS  Google Scholar 

  34. Y. Inomata, Y. Arai, T. Yamakoshi, F. Scott Howell, Inorg. Biochem. 98, 2149–2154 (2004)

    Article  CAS  Google Scholar 

  35. P.I. Girginova, F.A. Almeida Paz, H.I.S. Nogueira, N.J.O. Silva, V.S. Amaral, J. Klinowski, T. Trindade, Polyhedron 24, 563–571 (2005)

    Article  CAS  Google Scholar 

  36. E. Murugan, J.N. Jebaranjitham, J. Mol. Cat. A: Chem. 365, 128–135 (2012)

    Article  CAS  Google Scholar 

  37. Y. Inomata, M. Ando, F.S. Howell, J. Mol. Struc. 616, 201–212 (2002)

    Article  CAS  Google Scholar 

  38. U. Kurtan, A. Baykal, Mater. Res. Bull. 60, 79–87 (2014)

    Article  CAS  Google Scholar 

  39. Y. Junejo, A. Baykal, T. J. Chem. 38, 765–774 (2014)

    Article  CAS  Google Scholar 

  40. Y. Junejo, Sirajuddin, A. Baykal, M. Safdar, A. Balouch, Appl. Surf. Sci. 290, 499–503 (2014)

    Article  CAS  Google Scholar 

  41. E. Karaoğlu, U. Özel, C. Caner, A. Baykal, M.M. Summak, H. Sözeri, Mater. Res. Bull. 47, 4316–4321 (2012)

    Article  Google Scholar 

  42. N. Pradhan, A. Pal, T. Pal, Langmuir 17, 1800–1809 (2001)

    Article  CAS  Google Scholar 

  43. J.M. Herrmann, Water treatment by heterogeneous photocatalysis, in Environmental Catalysis, Catalytic Science Series, vol. Vol. 1, ed. by F. Jansen, R.A. van Santen (Imperial College Press, London, 1999), pp. 171–194. Chapter 9

    Google Scholar 

  44. W. Lua, R. Ninga, X. Qin, Y. Zhang, G. Chang, S. Liu, Y. Luo, X. Sun, J. Hazard. Mater. 197, 320–326 (2011)

    Article  Google Scholar 

  45. Q. Zhou, G. Qian, Y. Li, G. Zhao, Y. Chao, J. Zheng, Thin Solid Films 516, 953–956 (2008)

    Article  CAS  Google Scholar 

  46. V.K. Vidhu, Daizy Philip, Micron 56, 54–62 (2014)

    Article  CAS  Google Scholar 

  47. J. Feng, L. Su, Y. Ma, C. Ren, Q. Guo, X. Chena, Chem. Eng. J. 13, 16–24 (2013)

    Article  Google Scholar 

  48. N. Pradhan, A. Pal, T. Pal, Colloids Surf. A 196, 247–257 (2002)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by Fatih University under BAP Grant No: P50021301-Y (3146).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Arts and Sciences, Fatih University, B.Çekmece, 34500, Istanbul, Turkey

    U. Kurtan, E. Onuş, Md. Amir & A. Baykal

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  1. U. Kurtan
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  2. E. Onuş
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  3. Md. Amir
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  4. A. Baykal
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Correspondence to U. Kurtan.

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Kurtan, U., Onuş, E., Amir, M. et al. Fe3O4@Hpipe-4@Cu Nanocatalyst for Hydrogenation of Nitro-Aromatics and Azo Dyes. J Inorg Organomet Polym 25, 1120–1128 (2015). https://doi.org/10.1007/s10904-015-0218-1

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  • DOI: https://doi.org/10.1007/s10904-015-0218-1

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