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Structure, Characterization and Photocatalytic Activity of a Series of Well-Established Covalent Heterojunction Coordination Polymers

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Abstract

Six novel coordination polymers {Co(HCOO)2(4,4′-bipy)} n (1), {[Ni(4,4′-bipy)(OH)2(H2O)2]·suc·2H2O} n (2), {Ni(HCOO)2(4,4′-bipy)} n (3), {Zn(HCOO)2(4,4′-bipy)} n (4), {Cu(HCOO)2(4,4′-bipy)} n (5) and {[Cu(ox)(2,2′-bipy)]·2H2O} n (6) (suc succinic acid, ox oxalic cid) based on pyridine derivatives and carboxylates as ligands were designed and synthesized. The coordination polymers were characterized by elemental analysis, IR and UV–Vis spectra, powder X-ray diffraction, the thermo gravimetric analyses and single-crystal diffraction analysis. The structure analysis showed that the central metal atoms in coordination polymers 1, 2, 3, 4 and 6 all were six-coordination modes, forming distorted octahedron geometries. Cu atom in the coordination polymer 5 was four-coordination mode, forming square planar coordination geometry. While in the coordination polymers 1, 3 and 4, two metal centers were connected by bridging coordination fashions of formic acid ligand, forming a three-dimensional network structure, and in the coordination polymer 6, the two metal centers were connected by bridging coordination fashions of oxalic acid ligand, forming one-dimensional chain. In addition, the photocatalytic activity of a series of covalent heterojunction coordination polymers was studied.

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Acknowledgments

This work was supported by the grants of the National Natural Science Foundation of China (Grant No. 21071071, 21371086). Guangxi Key Laboratory of Information Materials, Guilin University of ElectronicTechnology, P. R. China (Project No. 1210908-06-K) and Commonweal Research Foundation of Liaoning province in China (No. 2014003019) for financial assistance.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, China

    Xue Gao, Che Wang, Qing-lin Guan, Ji-Xiao Wang, Si-Yue Wei, Xiao-Xi Zhang, Xue-Ting Xu & Yong-heng Xing

  2. School of Life Science, Liaoning Normal University, Dalian, 116029, China

    Feng-Ying Bai

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  1. Xue Gao
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  2. Che Wang
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Correspondence to Che Wang or Yong-heng Xing.

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Gao, X., Wang, C., Bai, FY. et al. Structure, Characterization and Photocatalytic Activity of a Series of Well-Established Covalent Heterojunction Coordination Polymers. J Inorg Organomet Polym 25, 1088–1102 (2015). https://doi.org/10.1007/s10904-015-0215-4

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