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A New Chiral Coordination Polymer with Large Cavities of [Cu3(NA)6(DMF)3]n: Synthesis, Structural and Magnetic Property

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Abstract

A new metal–organic architectures, [Cu3(NA)6(DMF)3]n (1), where NA stands for nicotinic acid, has been successfully synthesized and characterized by elemental analysis, IR, TG analysis and single crystal X-ray diffraction. Single-crystal X-ray diffraction reveals that the CuII centers adopt a distorted square pyramidal geometry, and nicotinic acid acts as a bidentate ligand connected with the adjacent two Cu atoms by the pyridyl and carboxylate groups to form a 3D framework structure. The framework exhibits open chiral channels with coordinated DMF molecules inside it. In addition, the magnetic properties have also been studied.

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References

  1. G.S. Papaefstathiou, T. Friščić, L.R. MacGillivray, J. Am. Chem. Soc. 127, 14160–14161 (2005)

    Article  CAS  Google Scholar 

  2. Y.Q. Sun, J. Zhang, Z.F. Ju, G.Y. Yang, Cryst. Growth Des. 5, 1939–1943 (2005)

    Article  CAS  Google Scholar 

  3. X.Q. Liang, X.H. Zhou, C. Chen, H.P. Xiao, Y.Z. Li, J.L. Zuo, X.Z. You, Cryst. Growth Des. 9, 1041–1053 (2009)

    Article  CAS  Google Scholar 

  4. D.P. Li, X.H. Zhou, X.Q. Liang, C.H. Li, C. Chen, J. Liu, X.Z. You, Cryst. Growth Des. 10, 2136–2145 (2010)

    Article  CAS  Google Scholar 

  5. A. Duong, M.A. Dubois, J.D. Wuest, Langmuir 26, 18089–18096 (2010)

    Article  CAS  Google Scholar 

  6. T. Matsumoto, T. Shiga, M. Noguchi, T. Onuki, G.N. Newton, N. Hoshino, M. Nakano, H. Oshio, Inorg. Chem. 49, 368–370 (2010)

    Article  CAS  Google Scholar 

  7. L.C. Song, M.Y. Tang, S.Z. Mei, J.H. Huang, Q.M. Hu, Organometallics 26, 1575–1577 (2007)

    Article  CAS  Google Scholar 

  8. F. Pointillart, A. Bourdolle, T. Cauchy, O. Maury, Y. Le Gal, S. Golhen, O. Cador, L. Ouahab, Inorg. Chem. 51, 978–984 (2012)

    Article  CAS  Google Scholar 

  9. M.E. Chapman, P. Ayyappan, B.M. Foxman, G.T. Yee, W. Lin, Cryst. Growth Des. 1, 159 (2001)

    Article  CAS  Google Scholar 

  10. J.Y. Lu, A.M. Babb, Inorg. Chem. Commun. 4, 716 (2001)

    Article  CAS  Google Scholar 

  11. J.H. Yu, J.Q. Xu, L. Ye, H. Ding, W.J. Jing, T.G. Wang, J.N. Xu, H.B. Jia, Z.C. Mu, G.D. Yang, Inorg. Chem. Commun. 5, 572 (2002)

    Article  CAS  Google Scholar 

  12. R. Song, K.M. Kim, Y.S. Sohn, Inorg. Chem. 42, 821 (2003)

    Article  CAS  Google Scholar 

  13. J.W. Cheng, S.T. Zheng, W. Liu, G.Y. Yang, CrystEngComm 10, 1047 (2008)

    Article  CAS  Google Scholar 

  14. K. Biradha, C. Seward, M.J. Zaworotko, Angew. Chem. 111, 584 (1999)

    Article  Google Scholar 

  15. D. Moon, J. Song, B.J. Kim, B.J. Suh, M.S. Lah, Inorg. Chem. 43, 8230–8232 (2004)

    Article  CAS  Google Scholar 

  16. A. Goswami, S. Bala, P. Pachfule, R. Mondal, Cryst. Growth Des. 13, 5487–5498 (2013)

    Article  CAS  Google Scholar 

  17. Y. Qi, F. Luo, S.R. Batten, Y.X. Che, J.M. Zheng, Cryst. Growth Des. 8, 2806 (2008)

    Article  CAS  Google Scholar 

  18. C.W. Yeh, M.C. Suen, H.L. Hu, J.D. Chen, J.C. Wang, Polyhedron 23, 1947 (2004)

    Article  CAS  Google Scholar 

  19. D. Dipankar, R. Subhadip, R.N.D. Purkayastha, P. Raghavaiah, M. Patrick, J. Mol. Struct. 1053, 127–133 (2013)

    Article  Google Scholar 

  20. C.T. Yang, M. Vetricheran, X. Yang, B. Moubaraki, K.S. Murry, J.J. Vittal, Dalton Trans. 33, 113–121 (2004)

    Article  Google Scholar 

Download references

Acknowledgments

The authors thank the financial support of PNSF of Hunan (13JJ6041; 2015 JJ2138).

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Authors and Affiliations

  1. Key Laboratory of Environmentally Friendly Chemistry and Applications of the Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan, 411105, Hunan, People’s Republic of China

    Zhi-juan Feng, Zhao-wei Yan, Tao-hai Li & Feng Li

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  1. Zhi-juan Feng
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  2. Zhao-wei Yan
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  3. Tao-hai Li
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  4. Feng Li
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Correspondence to Tao-hai Li.

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Feng, Zj., Yan, Zw., Li, Th. et al. A New Chiral Coordination Polymer with Large Cavities of [Cu3(NA)6(DMF)3]n: Synthesis, Structural and Magnetic Property. J Inorg Organomet Polym 25, 1006–1010 (2015). https://doi.org/10.1007/s10904-015-0198-1

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  • DOI: https://doi.org/10.1007/s10904-015-0198-1

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