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Solid-State Characterization of a Fused Salphen–Nickel Metallopolymer Prepared via Transmetalation in a Heterogeneous Reaction System

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Abstract

A nickel-containing metallopolymer with fully π-conjugated fused salphen ligands was prepared from the corresponding zinc-containing metallopolymer by means of transmetalation. As a model for the metallopolymer, an analogous fused tetrasalphen–nickel complex was also prepared. Solid-thin-film absorption microspectroscopy was used to confirm that the transmetalation reaction had occurred and to determine the degree of polymerization, which was estimated to be 8–15. Combined with theoretical normal-mode analysis, comparison of the FT-IR spectra of a series of model complexes with different nuclearities revealed two diagnostic peaks that could be used to validate the polynuclearity of the nickel-containing metallopolymer.

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Acknowledgments

T. Mutai gratefully acknowledges the financial support from the Japan Society for the Promotion of Science (Grants-in-Aid for Scientific Research C: 24550222). The authors are grateful to Dr. Y. Taninouchi and Prof. T. H. Okabe for measurement of XRF, and to Dr. G. Hayashi and Prof. A. Okamoto for measurement of MALDI–TOF-MS.

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Authors and Affiliations

  1. Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo, 153-8505, Japan

    Hirohiko Houjou, Keisuke Yagi, Isao Yoshikawa, Toshiki Mutai & Koji Araki

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  1. Hirohiko Houjou
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  2. Keisuke Yagi
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  3. Isao Yoshikawa
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  4. Toshiki Mutai
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Correspondence to Hirohiko Houjou.

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Houjou, H., Yagi, K., Yoshikawa, I. et al. Solid-State Characterization of a Fused Salphen–Nickel Metallopolymer Prepared via Transmetalation in a Heterogeneous Reaction System. J Inorg Organomet Polym 25, 906–911 (2015). https://doi.org/10.1007/s10904-015-0187-4

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  • DOI: https://doi.org/10.1007/s10904-015-0187-4

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