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Synthesis, Characterization and Crystal Structure of Zn(II) and Cd(II) One- and Two-Dimensional Coordination Polymers Derived from Pyridine Based Schiff Base ligand

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Abstract

Four coordination polymers with the formulas [Zn(L)(NO3)]n (1), {[Zn(L)(NO2)]·CH3OH}n (2), [Cd(L)(NO2)]n (3) and [Cd(L)(NO3)]n (4) {HL=2-benzolypyridine-isonicotinoylhydrazone (HBPIH)} have been synthesized and characterized by elemental analyses, FT-IR spectroscopy, 1H and 13C NMR and single crystal X-ray data diffraction. The L ligand acts as a negatively charged tetradentae N3O-donor in 1–3 and pentadentate ligand in 4. The Schiff base ligand coordinates to a metal center as N2O-donor and coordinates to adjacent metal center via its Para-Nitrogen of pyridlyl group in 1–3 leading to formation of one-dimensional, 1D, coordination polymer. The oxygen atom of the ligand L also coordinates to the third metal center as a bridging atom in 4 and forms a two-dimensional, 2D, coordination polymer. Metal centers are six coordinated with distorted octahedral geometry in 1–3 and seven coordinated with pentagonal bipyramid geometry in 4. The nitrate and nitrite groups act as asymmetric bidentate ligands in all complexes.

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Acknowledgments

We are grateful to the University of Tabriz for the generous financial support of this research. Single crystal X-ray diffraction experiments were performed at Villanova University and Cardinal Stefan Wyszynski University in Warsaw and Universidad de Oviedo. We thank them all for their helpful collaboration.

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Authors and Affiliations

  1. Department of Inorganic Chemistry, Faculty of Chemistry, University of Tabriz, 51666-16471, Tabriz, Iran

    Ali Akbar Khandar, Farhad Akbari Afkhami & Seyed Abolfazl Hosseini-Yazdi

  2. Faculty of Mathematics and Natural Sciences, Cardinal Stefan Wyszynski University in Warsaw, Wóycickiego 1/3, 001-938, Warsaw, Poland

    Janusz Lipkowski

  3. Department of Chemistry, Villanova University, 800 Lancaster Ave., Villanova, PA, 19085, USA

    William. G. Dougherty & W. Scott Kassel

  4. Departamento de Química Física y Analítica, Facultad de Química, Universidad de Oviedo–CINN, C/Julián Clavería, 8, 33006, Oviedo, Asturias, Spain

    Héctor Rodríguez Prieto & Santiago García-Granda

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  1. Ali Akbar Khandar
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Correspondence to Ali Akbar Khandar.

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Khandar, A.A., Afkhami, F.A., Hosseini-Yazdi, S.A. et al. Synthesis, Characterization and Crystal Structure of Zn(II) and Cd(II) One- and Two-Dimensional Coordination Polymers Derived from Pyridine Based Schiff Base ligand. J Inorg Organomet Polym 25, 860–868 (2015). https://doi.org/10.1007/s10904-015-0175-8

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