Abstract
Two cadmium(II) coordination polymers, [Cd(L)(nda)(H2O)·0.75H2O] n (1) and [Cd(L)(tbta)(H2O)] n (2) (L = 1,3-bis-(2-methylbenzimidazol-1-ylmethyl)benzene, H2nda = 2,6-naphthalenedicarboxylic acid, H2tbta = tetrabromoterephthalic acid), were synthesized under hydrothermal conditions and characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction and powder X-ray diffraction analysis. Both complexes exhibit 2D (6,3) honeycomb-like structures. Complex 1 is further extended into a twofold interpenetrating 3D 4,4-connected mog supramolecular architecture with point symbol of {4.64.8}2{42.62.82} via classical O–H···O hydrogen bonding interactions, while 2 displays a 3D supramolecular framework through π–π stacking interactions. The fluorescence properties and thermal stability of the two complexes were investigated.
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Acknowledgments
The project was supported by the National Natural Science Foundation of China (51474086) and the Hercules Foundation (project AUGE/11/029“3D-SPACE: 3D Structural Platform Aiming for Chemical Excellence”) for funding.
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Yang, R., Xiao, W.C., Van Hecke, K. et al. Two 3D Supramolecular Cadmium(II) Coordination Polymers Derived from Semi-rigid Bis(2-methylbenzimidazole) and Different Dicarboxylate Ligands. J Inorg Organomet Polym 25, 772–779 (2015). https://doi.org/10.1007/s10904-014-0157-2
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DOI: https://doi.org/10.1007/s10904-014-0157-2