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Coordination Polymers: Preparation, Physicochemical Characterization, Thermal and Biological Evaluation of Thiosemicarbazide Polychelates

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Abstract

Coordination polymers were prepared by the condensation reaction of salicylaldehyde and thiosemicarbazide with formaldehyde, transition metal acetates Mn(II), Co(II), Ni(II), Cu(II) and Zn(II). Structural and spectral properties have been studied by elemental, spectral (FT-IR, 1H NMR, and UV–Vis), and thermogravimetric analysis. The geometry of the chelated coordination polymers was confirmed by magnetic susceptibility measurements and UV–Visible spectroscopy. Antimicrobial screening was done against microbes such as Escherichia coli, Pseudomonas aeruginosa, Bacillus subtilis, Staphylococcus aureus, Staphylococcus typhi, Candida albicans, Microsporum canis, Aspergillus niger. In vitro antimicrobial activity was determined by the Agar Well Diffusion method and result show that all the coordination polymers exhibited better antimicrobial activity than their parent polymeric Schiff base. Coordination polymers were found to be more stable than their corresponding ligand as deduced by on thermogravimetric analysis. Because of antimicrobial and thermal behavior, these coordination polymers have broad range of applications as thermally resistant as well as antimicrobial-biocidal and antifouling coating materials.

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Acknowledgments

One of the authors (Raza Rasool) is thankful to University Grants Commission (New Delhi) for financial support in the form of the Basic Scientific Research Fellowship. The authors express their sincere thanks to ‘‘The Third World Academy of Sciences, Italy’’ for UV–Visible spectrophotometer EZ-201 (Perkin-Elmer) through research Grant Scheme No. 00-047 RG/CHE/AS.

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Authors and Affiliations

  1. Materials Research Laboratory, Department of Chemistry, Jamia Millia Islamia, New Delhi, 110025, India

    Raza Rasool, Sumaiya Hasnain & Nahid Nishat

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  1. Raza Rasool
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  2. Sumaiya Hasnain
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  3. Nahid Nishat
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Correspondence to Sumaiya Hasnain.

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Rasool, R., Hasnain, S. & Nishat, N. Coordination Polymers: Preparation, Physicochemical Characterization, Thermal and Biological Evaluation of Thiosemicarbazide Polychelates. J Inorg Organomet Polym 25, 763–771 (2015). https://doi.org/10.1007/s10904-014-0156-3

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