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Synthesis and Structure Characterizations of Coordination Polymers Based on Silver(I) and Nitrogen Donors

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Abstract

Yellow crystals of the coordination polymers (CP) [Ag(qox)NO3], 1 [Ag(pyzca)], 2 were obtained by the reaction of AgNO3, quinoxaline (qox) or pyrazinecarboxylic acid (pyzcaH), respectively. The crystal structure of 1 displays 1D-extended chain of [Ag(qox)]n with NO3 coordinated to every Ag atom. The 1D-chains of 1 are interconnected by strong hydrogen bonds, π–π stacking and short contacts developing two dimensional sheets containing channels. Furthermore, the overall packing arrangement of 1 results 3D topology with corrugated network. The Ag atom in 2 acquires tetrahedral geometry while each pyzca ligand provides three donor sites connected to three Ag atoms. The structure of CP 2 displays 1D-extended helical chain of [Ag(pyzca)]n. The 3D-packing of the CP 2 creates nanometer pores. The luminescence properties of 1 and 2 were discussed.

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References

  1. L.E. Kreno, K. Leong, O.K. Farha, M. Allendorf, R.P. Van Duyne, J.T. Hupp, Chem. Rev. 112, 1105–1125 (2012)

    Article  CAS  Google Scholar 

  2. D. Maspoch, D. Ruiz-Molina, J. Veciana, Chem. Soc. Rev. 360, 770–818 (2007)

    Article  Google Scholar 

  3. W. Lin, Z. Wang, L. Ma, J. Am. Chem. Soc. 121, 11249–11250 (1999)

    Article  CAS  Google Scholar 

  4. U. Mueller, M. Schubert, F. Teich, H. Puetter, K. Schierle-Arndt, J. Pastre, J. Mater. Chem. 16, 626–636 (2006)

    Article  CAS  Google Scholar 

  5. J.L.C. Rowsell, E.C. Spencer, J. Eckert, J.A.K. Howard, O.M. Yaghi, Science 309, 1350–1354 (2005)

    Article  CAS  Google Scholar 

  6. D. Bradshaw, J.B. Claridge, E.J. Cussen, T.J. Prior, M.J. Rosseinsky, Acc. Chem. Res. 38, 27–282 (2005)

    Article  Google Scholar 

  7. M.D. Allendorf, C.A. Bauer, R.K. Bhakta, R.J.T. Houk, Chem. Soc. Rev. 38, 1330–1352 (2009)

    Article  CAS  Google Scholar 

  8. C.-Y. Su, C.-L. Chen, J.-Y. Zhang, B.-S. Kang, Silver(I) coordination polymers, in Design and Construction of Coordination Polymers, ed. by M.-C. Hong, L. Chen (Wiley, Hoboken, 2009)

    Google Scholar 

  9. S.E.H. Etaiw, M.M. El-bendary, J. Inorg. Organomet. Polym. 23, 510–518 (2013)

    Article  CAS  Google Scholar 

  10. S.E.H. Etaiw, A.S. Sultan, M.M. El-bendary, J. Organomet. Chem. 696, 1668–1676 (2011)

    Article  CAS  Google Scholar 

  11. S.E.H. Etaiw, A.S. Badr El-din, M.M. El-bendary, Z. Anorg. Allg. Chem. 639, 810–816 (2013)

    Article  CAS  Google Scholar 

  12. S.E.H. Etaiw, M.M. El-bendary, Spectrochim. Acta A 110, 304–310 (2013)

    Article  CAS  Google Scholar 

  13. S.E.H. Etaiw, A.S. Fouda, S.N. Abdou, M.M. El-bendary, Corros. Sci. 53, 3057–3665 (2011)

    Article  Google Scholar 

  14. S.E.H. Etaiw, M.M. El-bendary, App. Catal. B 126, 326–333 (2012)

    Article  CAS  Google Scholar 

  15. S. Kitagawa, R. Matsuda, Coord. Chem. Rev. 251, 2490–2509 (2007)

    Article  CAS  Google Scholar 

  16. Y.B. Dong, X. Zhao, B. Tang, H.Y. Wang, R.Q. Huang, M.D. Smith, H.C. Zur Loye, Chem. Commun., 220–221 (2004)

  17. Y.B. Dong, X. Zhao, R.Q. Huang, Inorg. Chem. 43, 5603–5612 (2004)

    Article  CAS  Google Scholar 

  18. M. Pascu, F. Tuna, E. Kolodziejczyk, G.I. Pascu, G. Clarkson, M.J. Hannon, Dalton Trans., 1546–1555 (2004)

  19. D.Y. Wu, W. Huang, C.Y. Duan, Q.J. Meng, Inorg. Chem. Commun. 10, 1009–1013 (2007)

    Article  CAS  Google Scholar 

  20. Y.B. Dong, H.Q. Zhang, J.P. Ma, R.Q. Huang, Cryst. Growth Des. 5, 1857–1866 (2005)

    Article  CAS  Google Scholar 

  21. Y. Bai, C.Y. Duan, P. Cai, D.B. Dang, Q.J. Meng, Dalton Trans., 2678–2680 (2005)

  22. Q.Z. Sun, M.L. Wei, Y. Bai, C. He, Q.J. Meng, C.Y. Duan, Dalton Trans., 4089–4094 (2007)

  23. C.M.R. Juan, B. Lee, Coord. Chem. Rev. 183, 43–80 (1999)

    Article  Google Scholar 

  24. T.N. Guru Row, Coord. Chem. Rev. 183, 81–100 (1999)

    Article  Google Scholar 

  25. I. Unamuno, J.M. Gutie´rrez-Zorrilla, A. Luque, P. Román, L. Lezama, R. Calvo, T. Rojo, Inorg. Chem. 37, 6452–6460 (1998)

    Article  CAS  Google Scholar 

  26. M.W. Hosseini, Acc. Chem. Res. 38, 313–323 (2005)

    Article  CAS  Google Scholar 

  27. K. Chainok, S.M. Neville, C.M. Forsyth, W.J. Gee, K.S. Murray, S.R. Batten, CrystEngComm 14, 3717–3726 (2012)

    Article  CAS  Google Scholar 

  28. P.J. Steel, C.M. Fitchett, Coord. Chem. Rev. 252, 990–1006 (2008)

    Article  CAS  Google Scholar 

  29. Q. Chu, D.C. Swenson, L.R. MacGillivray, Angew. Chem. 117, 3635–3638 (2005)

    Article  Google Scholar 

  30. R. Santra, K. Biradha, Cryst. Growth Des. 10, 3315–3320 (2010)

    Article  CAS  Google Scholar 

  31. O.-S. Jung, Y.J. Kim, Y.-A. Lee, S.W. Kang, S.N. Choi, Cryst. Growth Des. 4, 23–24 (2004)

    Article  CAS  Google Scholar 

  32. P.-P. Zhang, J. Peng, H.-J. Pang, J.-Q. Sha, M. Zhu, D.-D. Wang, M.-G. Liu, Z.-M. Su, Cryst. Growth Des. 11, 2736–2742 (2011)

    Article  CAS  Google Scholar 

  33. P.-S. Cheng, S. Marivel, S.-Q. Zang, G.-G. Gao, T.C. Mak, Cryst. Growth Des. 12, 4519–4529 (2012)

    Article  CAS  Google Scholar 

  34. R.-W. Huang, Y. Zhu, S.-Q. Zang, M.-L. Zhang, Inorg. Chem. Commun. 33, 38–42 (2013)

    Article  Google Scholar 

  35. D. Sun, G.-G. Luo, N. Zhang, Q.-J. Xu, C.-F. Yang, Z.-H. Wei, Y.-C. Jin, L.-R. Lin, R.-B. Huang, L.-S. Zheng, Inorg. Chem. Commun. 13, 290–293 (2010)

    Article  CAS  Google Scholar 

  36. V.T. Yilmaz, E. Senel, E. Guney, C. Kazak, Inorg. Chem. Commun. 11, 1330–1333 (2008)

    Article  CAS  Google Scholar 

  37. E. Soyer, F. Yilmaz, V.T. Yilmaz, O. Buyukgungor, W.T. Harrison, J. Inorg. Organomet. Polym Mater. 20, 320–325 (2010)

    Article  CAS  Google Scholar 

  38. L. Brammer, M.D. Burgard, M.D. Eddleston, C.S. Rodger, N.P. Rath, H. Adams, CrystEngComm 4, 239–248 (2002)

    Article  CAS  Google Scholar 

  39. M.A.M. Abu-Youssef, V. Langer, L. Öhrstrom, Dalton Trans., 2542–2550 (2006)

  40. H.-Y. Liu, H. Wu, J.-F. Ma, J. Yang, Y.-Y. Liu, Dalton Trans., 7957–7968 (2009)

  41. H.-Y. Liu, H. Wu, J.-F. Ma, S.-Y. Song, J. Yang, Y.-Y. Liu, Z.-M. Su, Inorg. Chem. 46, 7299–7311 (2007)

    Article  CAS  Google Scholar 

  42. S. Qin, S. Lu, Y. Ke, J. Li, X. Wu, W. Du, Solid State Sci. 6, 753–755 (2004)

    Article  CAS  Google Scholar 

  43. Z.-H. Wang, D.-F. Wang, T. Zhang, R.-B. Huang, L.-S. Zheng, J. Mol. Struct. 1064, 27–31 (2014)

    Article  CAS  Google Scholar 

  44. M. Park, J. Jang, S.Y. Moon, O.-S. Jung, J. Mol. Struct. 1062, 89–95 (2014)

    Article  CAS  Google Scholar 

  45. S.E.H. Etaiw, D.M. Abd El-Aziz, A.S. Badr El-din, Polyhedron 28, 873–882 (2009)

    Article  CAS  Google Scholar 

  46. S.E.H. Etaiw, M.M. El-bendary, J. Coord. Chem. 63, 1038–1051 (2010)

    Article  CAS  Google Scholar 

  47. S.E.H. Etaiw, A.S. Sultan, A.S. Badr El-din, Eur. J. Med. Chem. 46, 5370–5378 (2011)

    Article  CAS  Google Scholar 

  48. S.E.H. Etaiw, A.S. Badr El-din, J. Inorg. Organomet. Polym. 21, 1–8 (2011)

    Article  CAS  Google Scholar 

  49. H.H. Jaffe, M. Orchin, Theory and Applications of Ultraviolet Spectroscopy, 5th edn. (Wiley, New York, 1970)

    Google Scholar 

  50. S.E.H. Etaiw, A.S. Badr El-din, J. Inorg. Organomet. Polym. 21, 110–117 (2011)

    Article  CAS  Google Scholar 

  51. S.E.H. Etaiw, S.N. Abdou, J. Inorg. Organomet. Polym. 23, 1296–1304 (2013)

    Article  CAS  Google Scholar 

  52. F.-F. Li, J.-F. Ma, S.Y. Song, J. Yang, Y.-Y. Liu, Z.-M. Su, Inorg. Chem. 44, 9374–9383 (2005)

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Tanta University, Tanta, Egypt

    Safaa El-din H. Etaiw, Mohamed M. El-bendary & Manal Maher

  2. Department of Chemistry, Faculty of Science, El-Mansoura University, El-Mansoura, 35516, Egypt

    Abd El-Aziz S. Fouda

Authors
  1. Safaa El-din H. Etaiw
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  2. Mohamed M. El-bendary
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  3. Abd El-Aziz S. Fouda
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  4. Manal Maher
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Correspondence to Safaa El-din H. Etaiw.

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Etaiw, S.Ed.H., El-bendary, M.M., Fouda, A.EA.S. et al. Synthesis and Structure Characterizations of Coordination Polymers Based on Silver(I) and Nitrogen Donors. J Inorg Organomet Polym 25, 702–711 (2015). https://doi.org/10.1007/s10904-014-0148-3

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