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Fe3O4@Tween20@Ag Magnetically Recyclable Nanocatalyst for Various Hydrogenation Reactions

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Abstract

In this paper, for the first time, we describe a facile method for synthesis of Ag-deposited Tween-20 coated Fe3O4 magnetic nanoparticles, which have a magnetic core and active silver nanoparticles an outer shell using polyvinylpyrrolidone as the reductant of AgNO3 in ethanol. The synthesized magnetic nanocatalyst was characterized by X-ray diffraction, Fourier trasform infrared spectra, Transmisson and scanning electron microscopy, and vibration sample magnetometer have been used for different hydrogenation reactions containing 2-nitroaniline, 3-nitroaniline, 4-nitroaniline, 4-nitrophenol by monitoring UV–Vis spectrophotometry. The obtained product showed a narrow size distribution and good catalytic activity towards various hyrogenation reactions. This magnetic catalyst could also be easily separated by magnetic separation and reused many times.

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Acknowledgments

This work was supported by Fatih University under BAP Grant No: P50021301-Y (3146).

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Authors and Affiliations

  1. Department of Chemistry, Fatih University, B.Çekmece, 34500, Istanbul, Turkey

    U. Kurtan & A. Baykal

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  1. U. Kurtan
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  2. A. Baykal
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Correspondence to U. Kurtan.

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Kurtan, U., Baykal, A. Fe3O4@Tween20@Ag Magnetically Recyclable Nanocatalyst for Various Hydrogenation Reactions. J Inorg Organomet Polym 25, 657–663 (2015). https://doi.org/10.1007/s10904-014-0138-5

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  • DOI: https://doi.org/10.1007/s10904-014-0138-5

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