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Structural Diversity of a Series of 2D Zn(II) Coordination Polymers Tuned by Different Dicarboxylic Acids Ligands

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Abstract

Three new coordination polymers, namely [Zn(tdc)(impy)]n (1), [Zn(4,4′-sdb)(impy)]n·1.5n(H2O) (2) [Zn(D-cam)(impy)]n (3) (H2tdc = 2,5-thiophenedicarboxylic acid, 4,4′-H2sdb = 4,4′-sulfonyldibenzoate, D-H2cam = D(+)-camphoric acid, impy = 2,6-bis(1-imdazoly)pyridine), have been synthesized under hydrothermal conditions. Structural analysis indicates that these three compounds all display 2D layer structures. Compound 1 presents a 3-connected hcb topology with the point symbol of {63}, compound 2 presents another 3-connected topological network with the point symbol of {82.10}, and compound 3 presents a 4-connected sql topology with the point symbol of {44.62}. Their thermal and luminescent properties are also investigated.

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Acknowledgments

This work was supported by Grants from the Sci-technical Support Project of Hebei Province (14227115D)

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Authors and Affiliations

  1. College of Sciences, Agricultural University of Hebei, Baoding, 071001, China

    Xiaohui Li, Pingping Zhou, Yanli Dong & Huimin Liu

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  1. Xiaohui Li
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  2. Pingping Zhou
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  3. Yanli Dong
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  4. Huimin Liu
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Correspondence to Huimin Liu.

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Li, X., Zhou, P., Dong, Y. et al. Structural Diversity of a Series of 2D Zn(II) Coordination Polymers Tuned by Different Dicarboxylic Acids Ligands. J Inorg Organomet Polym 25, 650–656 (2015). https://doi.org/10.1007/s10904-014-0134-9

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