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Syntheses, Crystal Structure, and Luminescence Properties of Three Metal–Organic Compounds Bearing Diverse Dimensionalities Based on Mixed N- and O-Donor Organic Ligands

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Abstract

Three new MOFs, namely [Ni(pip)(H2O)2] (1), [Ba(pip)(H2O)] (2), [Zn(pip)] (3), based on 6-(3-pyridyl)isophthalic acid (H2pip) were obtained and characterized by single-crystal X-ray diffraction, elemental analyses, PXRD, IR and TGA. By adjusting the reaction solvent, temperature and selecting different metal centers, compounds 1 and 2 possess 1D and 2D network, respectively, compound 3 show a 3D network containing a paddlewheel secondary building unit [SBU, Zn2(COO)4] with the Schläfli symbol (4·62)2(42·610·83). The structural differences among compounds 1–3 exhibit the backbone of such mixed N- and O-donor atoms organic ligands can be used to construct diverse dimensional MOFs by adjusting the reaction environment. Furthermore, the luminescence properties of compounds 2 and 3 were investigated, and both of them exhibit intense fluorescent emissions in the solid state at room temperature.

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Acknowledgments

This work was financially supported by the National Native Science Foundation of China (21371028).

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Authors and Affiliations

  1. School of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Jinan, 250353, People’s Republic of China

    Yongzheng Zhang, Xiuling Zhang & Zaiwu Yuan

  2. Key Laboratory of Coordination Chemistry, Functional Materials in Universities of Shandong (De Zhou University), De Zhou, 253023, People’s Republic of China

    Xiuling Zhang, Baoyong Zhu & Yu’e Qiu

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  1. Yongzheng Zhang
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  2. Xiuling Zhang
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  3. Baoyong Zhu
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  4. Yu’e Qiu
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  5. Zaiwu Yuan
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Correspondence to Xiuling Zhang or Zaiwu Yuan.

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Zhang, Y., Zhang, X., Zhu, B. et al. Syntheses, Crystal Structure, and Luminescence Properties of Three Metal–Organic Compounds Bearing Diverse Dimensionalities Based on Mixed N- and O-Donor Organic Ligands. J Inorg Organomet Polym 25, 635–644 (2015). https://doi.org/10.1007/s10904-014-0129-6

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  • DOI: https://doi.org/10.1007/s10904-014-0129-6

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