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Preparation of Pd Nanoparticles with Tetrahedral, Spherical, Plate, and Feather Shapes by Capping with 1-Pentyl Isocyanide

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Abstract

In this study, we synthesized n-alkyl-isocyanide-protected palladium colloidal nanoparticles with different shapes. The 1-pentyl-isocyanide-protected Pd nanoparticles prepared by the reduction of the Pd complex with ethylene glycol had various geometric shapes. Transmission electron micrographs showed that tetrahedral particles were predominant, although some spherical, plate-, and feather-shaped particles were also observed. The enriched nanotetrahedra were isolated as a black powder by reprecipitation with methanol–chloroform and the particle size was controlled by the reaction conditions.

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References

  1. G. Schmid, Chem. Rev. 92, 1709 (1992)

    Article  CAS  Google Scholar 

  2. G. Schmid, Nanoparticles: From Theory to Application (Wiely-XCH, Weinheim, Germany, 2004)

    Google Scholar 

  3. M.C. Daniel, D. Astruc, Chem. Rev. 104, 293 (2004)

    Article  CAS  Google Scholar 

  4. N.R. Shiji, V.V. Guliants, Appl. Catal. A 356, 1 (2009)

    Article  Google Scholar 

  5. K. Liu, C.-L. Ho, S. Aouba, Y.-Q. Zhao, Z.-H. Lu, S. Petrov, N. Coombs, P. Dube, H.E. Ruda, W.-Y. Wong, I. Manners, Angew. Chem. Int. Ed. 47, 1255 (2008)

    Article  CAS  Google Scholar 

  6. Q. Dong, G. Li, C.-L. Ho, M. Faisal, C.-W. Leung, P.W.-T. Pong, K. Liu, B.-Z. Tang, I. Manners, W.-Y. Wong, Adv. Mater. 24, 1034 (2012)

    Article  CAS  Google Scholar 

  7. Q. Dong, G. Li, C.-L. Ho, C.-W. Leung, P.W.-T. Pong, I. Manners, W.-Y. Wong, Adv. Funct. Mater. 24, 857 (2014)

    Article  CAS  Google Scholar 

  8. T. Teranishi, R. Kurita, M. Miyake, J. Inorg. Organomet. Polym. 10, 145 (2000)

    Article  CAS  Google Scholar 

  9. H.P. Choo, K.Y. Liew, W.A.K. Mahmood, H. Liu, J. Mater. Chem. 11, 2906 (2001)

    Article  CAS  Google Scholar 

  10. R. Narayanan, M.A. El-Sayed, Nano Lett. 4, 1343 (2004)

    Article  CAS  Google Scholar 

  11. R. Narayanan, M.A. El-Sayed, J. Am. Chem. Soc. 126, 7194 (2004)

    Article  CAS  Google Scholar 

  12. C. Burda, X. Chen, R. Narayanan, M.A. El-Sayed, Chem. Rev. 105, 1025 (2005)

    Article  CAS  Google Scholar 

  13. H. Choo, B. He, K.Y. Liew, H. Liu, J. Li, J. Mol. Catal. A 244, 217 (2006)

    Article  CAS  Google Scholar 

  14. F.Y. Norimatsu, Y. Mizokoshi, K. Mori, T. Mizugaki, K. Ebitani, K. Kaneda, Chem. Lett. 35, 276 (2006)

    Article  CAS  Google Scholar 

  15. A.R. Tao, S. Habas, P. Yang, Small 4, 310 (2008)

    Article  CAS  Google Scholar 

  16. B.J. Wiley, Y. Sun, Y. Xia, Acc. Chem. Res. 40, 1067 (2007)

    Article  CAS  Google Scholar 

  17. Y. Xiong, H. Cai, B.J. Wiley, J. Wang, M.J. Kim, Y. Xia, J. Am. Chem. Soc. 129, 3665 (2007)

    Article  CAS  Google Scholar 

  18. Y. Xia, Y. Xiong, B. Lim, S.E. Skrabalak, Angew. Chem. Int. Ed. 48, 60 (2009)

    Article  CAS  Google Scholar 

  19. B. Kowalczyk, I. Lagzi, B.A. Grzybowski, Curr. Opin. Colloid Interface Sci. 16, 135 (2011)

    Article  CAS  Google Scholar 

  20. M. Crespo-Quesada, J.-M. Andanson, A. Yarulin, B. Lim, Y. Xia, L. Kiwi-Minsker, Langmuir 27, 7909 (2011)

    Article  CAS  Google Scholar 

  21. N.V. Long, T. Hayakawa, T. Matsubara, N.D. Chien, M. Ohtaki, M. Nogami, J. Exp. Nanosci. 7, 426 (2012)

    Article  Google Scholar 

  22. X. Huang, S. Tang, H. Zhang, Z. Zhou, N. Zheng, J. Am. Chem. Soc. 131, 13916 (2009)

    Article  CAS  Google Scholar 

  23. S. Horinouchi, Y. Yamanoi, T. Yonezawa, T. Mouri, H. Nishihara, Langmuir 22, 1880 (2006)

    Article  CAS  Google Scholar 

  24. Y. Yamamoto, M. Miyachi, Y. Yamanoi, A. Minoda, S. Maekawa, S. Oshima, Y. Kobori, H. Nishihara, J. Nanopart. Res. 13, 6333 (2011)

    Article  CAS  Google Scholar 

  25. Y. Yamanoi, Y. Yamamoto, M. Miyachi, M. Shimada, A. Minoda, S. Oshima, Y. Kobori, H. Nishihara, Langmuir 29, 8768 (2013)

    Article  CAS  Google Scholar 

  26. Y. Yamamoto, M. Miyachi, Y. Yamanoi, A. Minoda, S. Maekawa, S. Oshima, Y. Kobori, H. Nishihara, J. Inorg. Organomet. Polym Mater. 24, 208 (2014)

    Article  CAS  Google Scholar 

  27. F. Fievet, J.P. Lagier, B. Blin, B. Beaudoin, M. Figlarz, Solid State Ion. 31–32, 198 (1989)

    Article  Google Scholar 

  28. Y. Xiong, J. Chen, B. Wiley, Y. Xia, J. Am. Chem. Soc. 127, 7332 (2005)

    Article  CAS  Google Scholar 

  29. Y. Xiong, J.M. McLellan, J. Chen, Y. Yin, Z.Y. Li, Y. Xia, J. Am. Chem. Soc. 127, 17118 (2005)

    Article  CAS  Google Scholar 

  30. J.F. Moulder, W.F. Stickle, P.E. Sobol, K.D. Bomben, Handbook of X-ray Photoelectron Spectroscopy (Perkin-Elmer Corporation, Eden Prairie, 1992)

    Google Scholar 

  31. P. Villars, Pearson’s Handbook: Crystallographic Data for Intermetallic Phases, 2nd edn. (ASM International, Materials Park, 1997)

    Google Scholar 

  32. K.H. Park, K. Jang, H.J. Kim, S.U. Son, Angew. Chem. Int. Ed. 46, 1152 (2007)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The work was financially supported by Grant-in-Aids for Scientific Research on Innovative Areas “Coordination Programming: Science of Super-molecular Structure and Creation of Chemical Elements” (area 2107, No. 21108002), and “Molecular Architectonics: Orchestration of Single Molecules for Novel Functions” (area 2509, Nos. 26110505 and 26110506) from the Ministry of Education, Culture, Sports, Science, and Technology, Japan. This work was also supported in part by the Kurata Grant awarded by the Kurata Memorial Hitachi Science and Technology Foundation.

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Authors and Affiliations

  1. Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan

    Mariko Miyachi, Yuki Yamamoto, Yoshinori Yamanoi & Hiroshi Nishihara

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  1. Mariko Miyachi
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  2. Yuki Yamamoto
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  3. Yoshinori Yamanoi
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  4. Hiroshi Nishihara
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Correspondence to Yoshinori Yamanoi or Hiroshi Nishihara.

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Miyachi, M., Yamamoto, Y., Yamanoi, Y. et al. Preparation of Pd Nanoparticles with Tetrahedral, Spherical, Plate, and Feather Shapes by Capping with 1-Pentyl Isocyanide. J Inorg Organomet Polym 25, 140–144 (2015). https://doi.org/10.1007/s10904-014-0121-1

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  • DOI: https://doi.org/10.1007/s10904-014-0121-1

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