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Inorganic Molybdenum Octahedral Nanosized Cluster Units, Versatile Functional Building Block for Nanoarchitectonics

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Abstract

Recently, Nanoarchitectonics has been introduced as a new concept that refers to a technology system for arranging nanoscale structural units in a required architecture. Multifunctional properties are achieved by a combination of several materials in a well-defined architecture. In the frame of this concept, composite nanoarchitectures represent a new class of nanostructured entities that integrate various dissimilar nanoscale building blocks including clusters, particles, wires and films. The heterogeneous composite nanostructured materials are composed by definition of multi-(nano)components, each tailored to address different requirements. As one of the nanocomponents, nanometer sized metal clusters (<2 nm), which consist of less than a few dozens of metal atoms, could be defined as a link between atom and nanoparticle. In this paper, we will focus on our results on new nano-composites involving Mo6 atom nanosized cluster units for optical, nanobiotechnology, energy and environmental applications.

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Acknowledgments

We are grateful to T. Aubert, C. Neaime, N. Nerambourg, J.F. Dechezelles, M. A. Shestopalov, A. Y. Ledneva, O.A. Efremova and F. Dorson who made a part of their PhD or post-doc work on this research topic. The authors thank Dr. P. Gredin from University of Paris 6-France, Dr. G. Patriarche at Laboratoire de Photonique et de Nanostructures (LPN-CNRS), Prof. G. Férey and Dr C. Serre from Institut Lavoisier Versailles, Prof. S. L. Jain from Chemical Sciences Division, CSIR-Indian Institute of Petroleum Mohkampur, Prof. K. Kimoto and Prof. Y. Bando from NIMS and MANA-NIMS, Prof. G. Saito and Dr Y. Yoshida from Faculty of Agriculture, Meijo University, Shiogamaguchi for very fruitful collaborations. These works have been supported by YCIS-NIMS, UR1, CNRS, Region Bretagne and ANR (CLUSTOP-11-BS08-013-01; CLUSTOMESOGEN-13-BS07-0003-01).

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Cordier, S., Grasset, F., Molard, Y. et al. Inorganic Molybdenum Octahedral Nanosized Cluster Units, Versatile Functional Building Block for Nanoarchitectonics. J Inorg Organomet Polym 25, 189–204 (2015). https://doi.org/10.1007/s10904-014-0112-2

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