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Synthesis and Solid-State Pyrolysis Behavior of POSS Containing Organometallic Polymer with Dicobalt Hexacarbonyl in the Side Chain

Journal of Inorganic and Organometallic Polymers and Materials volume 25, pages 98–106 (2015)Cite this article

Abstract

POSS containing organometallic polymer (P2-Co) with dicobalt hexacarbonyl in the side chain was synthesized for solid-state pyrolysis to produce magnetic nanoparticles. For comparison, its analogue (P1-Co) without POSS groups was also prepared. After pyrolysis, the nanospheres obtained from P2-Co with POSS groups, had a Co@C–SiOx structure with small and uniform size (~15 nm), and its diameter almost remained unchanged when the pyrolysis temperature increased, showing excellent sinter-resistant properties. However, the nanoparticles obtained from P1-Co sintered seriously at high temperature, and its size was enlarged from 45 to 160 nm, when the pyrolysis temperature increased from 700 to 850 °C. Meanwhile, the obtained nanoparticles all showed good magnetic properties, with the saturation magnetization in the range of 24.0–58.5 emu g−1, making them promising candidates for the actual applications.

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Acknowledgments

We are grateful to the National Fundamental Key Research Program (2011CB932702) and the National Natural Science Foundation of China (No. 21325416) for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Hubei Key Lab on Organic and Polymeric Opto-Electronic Materials, Wuhan University, Wuhan, 430072, China

    Zhijun Ruan, Wenhui Rong, Qianqian Li & Zhen Li

Authors
  1. Zhijun Ruan
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  2. Wenhui Rong
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  3. Qianqian Li
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  4. Zhen Li
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Corresponding author

Correspondence to Zhen Li.

Additional information

Zhijun Ruan and Wenhui Rong contributed equally to this work.

This paper is dedicated to Prof. Ben Zhong Tang for his outstanding contribution to the field of metal-containing polymers.

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Ruan, Z., Rong, W., Li, Q. et al. Synthesis and Solid-State Pyrolysis Behavior of POSS Containing Organometallic Polymer with Dicobalt Hexacarbonyl in the Side Chain. J Inorg Organomet Polym 25, 98–106 (2015). https://doi.org/10.1007/s10904-014-0092-2

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  • DOI: https://doi.org/10.1007/s10904-014-0092-2

Keywords

  • Organometallic polymer
  • Polyhedral oligosilsesquioxanes
  • Solid-state pyrolysis
  • Magnetism
  • Sinter-resistant properties