Skip to main content
SpringerLink
Log in

Synthesis, Structure, and Luminescent Properties of Two 3D Pillared-Layer Networks with InS Topology

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

Two coordination polymers, [M(cbdc)(bipy)0.5(H2O)]n [M = Zn (1), Cd (2)]. (H2cbdc = 1,1-cyclobutane dicarboxylic acid, bipy = 4,4′-bipyridine), have been synthesized by using Zn(II)/Cd(II) acetate with cbdc and bipy ligands under hydrothermal conditions. Their structures have been characterized by elemental analysis, IR spectroscopy, single-crystal X-ray crystallography and powder X-ray diffraction analysis. Complexes 1 and 2 are isostructural and show a 3D pillared-layer network with (3,4)-connected InS topology. The luminescent properties of the complexes and the free ligand have been investigated.

Graphical Abstract

Two novel coordination polymers based on the flexible alicyclic dicarboxylic acid ligand 1,1-cyclobutane dicarboxylic acid (H2cbdc) ligand have been synthesized under hydrothermal conditions. Complexes 1 and 2 are isostructural and show a 3D pillared-layer network with (3,4)-connected InS topology. The luminescent properties of the complexes and the free ligand have been investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. S.-T. Zheng, J.T. Bu, Y. Li, T. Wu, F. Zuo, P. Feng, X. Bu, J. Am. Chem. Soc. 132, 17062 (2010)

    Article  CAS  Google Scholar 

  2. O.M. Yaghi, M. O’Keeffe, N.W. Ockwig, H.K. Chae, M. Eddaoudi, J. Kim, Nature 423, 705 (2003)

    Article  CAS  Google Scholar 

  3. H. Zhang, Y. Lu, Z.M. Zhang, H. Fu, Y.G. Li, D. Volkmer, D. Denysenko, E.B. Wang, Chem. Commun. 48, 7295 (2012)

    Article  CAS  Google Scholar 

  4. R.-J. Li, M. Li, X.-P. Zhou, D. Li, M. O’Keeffe, Chem. Commun. 50, 4047 (2014)

    Article  CAS  Google Scholar 

  5. L. Ma, C. Abney, W. Lin, Chem. Soc. Rev. 38, 1248 (2009)

    Article  CAS  Google Scholar 

  6. S.-L. Li, Q. Xu, Energy Environ. Sci. 6, 1656 (2013)

    Article  CAS  Google Scholar 

  7. L.E. Kreno, K. Leong, O.K. Farha, M. Allendorf, R.P.V. Duyne, J.T. Hupp, Chem. Rev. 112, 1105 (2012)

    Article  CAS  Google Scholar 

  8. P. Horcajada, T. Chalati, C. Serre, B. Gillet, C. Sebrie, T. Baati, J.F. Eubank, D. Heurtaux, P. Clayette, C. Kreuz, J.-S. Chang, Y.K. Hwang, V. Marsaud, P.-N. Bories, L. Cynober, S. Gil, G. Férey, P. Couvreur, R. Gref, Nat. Mater. 9, 172 (2010)

    Article  CAS  Google Scholar 

  9. Y. Ma, Y. Dai, X. Li, Q. Sun, B. Huang, Carbon 73, 382 (2014)

    Article  CAS  Google Scholar 

  10. Y. Ma, Y. Dai, W. Wei, L. Yu, B. Huang, J. Phys. Chem. A 117, 5171 (2013)

    Article  CAS  Google Scholar 

  11. P. A. Gale, M. E. Light and R. Quesada, Chem. Commun (47), 5864 (2005)

  12. X.-L. Zhao, W.-Y. Sun, CrystEngComm 16, 3247 (2014)

    Article  CAS  Google Scholar 

  13. Y.-Y. Liu, J.-F. Ma, J. Yang, J.-C. Ma, Z.-M. Su, CrystEngComm 10, 894 (2008)

    Article  CAS  Google Scholar 

  14. X. Zhao, G. Zhu, Q. Fang, Y. Wang, F. Sun, S. Qiu, Cryst. Growth Des. 9, 737 (2009)

    Article  CAS  Google Scholar 

  15. J. Luo, F. Jiang, R. Wang, M. Hong, Inorg. Chem. Commun. 7, 638 (2004)

    Article  CAS  Google Scholar 

  16. J. Wang, Y.-H. Zhang and M.-L. Tong, Chem. Commun. 3166 (2006)

  17. T. Rau, M. Shoukry, R. van Eldik, Inorg. Chem. 36, 1454 (1997)

    Article  CAS  Google Scholar 

  18. I. Bratsos, E. Zangrando, B. Serli, N. Katsarosa, and E. Alessio, Dalton Trans. 3881 (2005)

  19. SAINT, Software Reference Manual (Bruker AXS, Madison, 1998)

  20. G.M. Sheldrick, SADABS, Siemens Area Detector Absorption Corrected Software (University of Göttingen, Germany, 1996)

    Google Scholar 

  21. G.M. Sheldrick, SHELXTL NT Version 5.1. Program for Solution and Refinement of Crystal Structures (University of Göttingen, Germany, 1997)

    Google Scholar 

  22. Y.-H. Xu, Y.-Q. Lan, S.-X. Wu, K.-Z. Shao, Z.-M. Su, Y. Lia, CrystEngComm 11, 1711 (2009)

    Article  CAS  Google Scholar 

  23. R. Baldomá, M. Monfort, J. Ribas, X. Solans, M.A. Maestro, Inorg. Chem. 45, 8144 (2006)

    Article  Google Scholar 

  24. G. K. H. Shimizu, G. D. Enright, C. I. Ratcliffe, J. A. Ripmeester, Chem. Commun. 461 (1999)

  25. D.-R. Xiao, E.-B. Wang, H.-Y. An, Y.-G. Li, Z.-M. Su, C.-Y. Sun, Chem. Eur. J. 12, 6528 (2006)

    Article  CAS  Google Scholar 

  26. J.E. McGarrah, Y.J. Kim, M. Hissler, R. Eisenberg, Inorg. Chem. 40, 4510 (2001)

    Article  CAS  Google Scholar 

  27. J.-Y. Wu, P.-T. Yuan, C.-C. Hsiao, CrystEngComm 16, 3128 (2014)

    Article  CAS  Google Scholar 

  28. L.-H. Cao, H.-Y. Li, S.-Q. Zang, H.-W. Hou, T.C.W. Mak, Cryst. Growth Des. 12, 4299 (2012)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (21373178), the Nature Scientific Foundation of the Shaanxi Province of China (2012JM2015), and the National Undergraduate Training Programs of Innovation and Entrepreneurship (201210719010).

Author information

Authors and Affiliations

  1. Department of Chemistry and Chemical Engineering, Yan′an University, Yan′an, 716000, Shaanxi, People’s Republic of China

    Mei-Li Zhang, Ji-Jiang Wang & Xiao-Li Chen

Authors
  1. Mei-Li Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ji-Jiang Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Xiao-Li Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Mei-Li Zhang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhang, ML., Wang, JJ. & Chen, XL. Synthesis, Structure, and Luminescent Properties of Two 3D Pillared-Layer Networks with InS Topology. J Inorg Organomet Polym 24, 879–883 (2014). https://doi.org/10.1007/s10904-014-0058-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-014-0058-4

Keywords

Search

Navigation