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Rapid Synthesis of Cobalt Metal Organic Framework

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Abstract

Metal-organic framework (MOF) has been shown to potential applications due to the high porous hybrid structure. Cobalt MOF was synthesized rapidly by ultrasound energy with about 3,000 m2/g surface area by BET method. Furthermore, this component is crystalline with significant thermal stability, on account of X-ray diffraction and thermal analysis, respectively. Based on high roughness, crystallinity, and unreported type of FTIR spectrum, a new structure of Co-MOF structure was proposed.

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References

  1. H.C. Zhou, J.R. Long, O.M. Yaghi, Introduction to metal-organic frameworks. Chem. Rev. 112, 673–674 (2012)

    Article  CAS  Google Scholar 

  2. A.U. Czaja, N. Trukhan, U. Muller, Industrial applications of metal-organic frameworks. Chem. Soc. Rev. 38, 1284–1293 (2009)

    Article  CAS  Google Scholar 

  3. N. Stock, S. Biswas, Synthesis of MOFs: routes to various MOF topologies, morphologies, and composites. Chem. Rev. 112, 933–969 (2011)

    Article  Google Scholar 

  4. H.K. Chae, D.Y. Siberio-Pérez, J. Kim, Y. Go, M. Eddaoudi, A.J. Matzger, M. O’Keeffe, O.M. Yaghi, A route to high surface area, porosity and inclusion of large molecules in crystals. Nature 427, 523–527 (2004)

    Article  CAS  Google Scholar 

  5. D.J. Tranchemontagne, Z. Ni, M. O’Keeffe, O.M. Yaghi, Reticular chemistry of metal-organic polyhedra. Angew. Chem. Int. Ed. 47, 5136–5147 (2008)

    Article  CAS  Google Scholar 

  6. J.-R. Li, J. Sculley, H.-C. Zhou, Metal-organic frameworks for separations. Chem. Rev. 112, 869–932 (2011)

    Article  Google Scholar 

  7. J. Lee, O.K. Farha, J. Roberts, K.A. Scheidt, S.T. Nguyen, J.T. Hupp, Metal-organic framework materials as catalysts. Chem. Soc. Rev. 38, 1450–1459 (2009)

    Article  CAS  Google Scholar 

  8. H.-Y. Cho, D. Yang, J. Kim, S.-Y. Jeong, W.-S. Ahn, CO2 adsorption and catalytic application of Co-MOF-74 synthesized by microwave heating. Catal. Today 185, 35–40 (2012)

    Article  CAS  Google Scholar 

  9. K. Sumida, D.L. Rogow, J.A. Mason, T.M. McDonald, E.D. Bloch, Z.R. Herm, T.-H. Bae, J.R. Long, Carbon dioxide capture in metal-organic frameworks. Chem. Rev. 112, 724–781 (2011)

    Article  Google Scholar 

  10. W. Zhou, H. Wu, T. Yildirim, Enhanced H2 adsorption in isostructural metal-organic frameworks with open metal sites: strong dependence of the binding strength on metal ions. J. Am. Chem. Soc. 130, 15268–15269 (2008)

    Article  CAS  Google Scholar 

  11. N.L. Rosi, J. Kim, M. Eddaoudi, B. Chen, M. O’Keeffe, O.M. Yaghi, Rod packings and metal-organic frameworks constructed from rod-shaped secondary building units. J. Am. Chem. Soc. 127, 1504–1518 (2005)

    Article  CAS  Google Scholar 

  12. Y. Zhao, J. Zhang, B. Han, J. Song, J. Li, Q. Wang, Metal-organic framework nanospheres with well-ordered mesopores synthesized in an ionic liquid/co2/surfactant system. Angew. Chem. Int. Ed. 50, 636–639 (2011)

    Article  CAS  Google Scholar 

  13. Y.-S. Bae, K.L. Mulfort, H. Frost, P. Ryan, S. Punnathanam, L.J. Broadbelt, J.T. Hupp, R.Q. Snurr, Separation of CO2 from CH4 using mixed-ligand metal-organic frameworks. Langmuir 24, 8592–8598 (2008)

    Article  CAS  Google Scholar 

  14. Z.R. Herm, J.A. Swisher, B. Smit, R. Krishna, J.R. Long, Metal-organic frameworks as adsorbents for hydrogen purification and precombustion carbon dioxide capture. J. Am. Chem. Soc. 133, 5664–5667 (2011)

    Article  CAS  Google Scholar 

  15. Y. Sun, Y.-H. Kim, S. Zhang, Effect of spin state on the dihydrogen binding strength to transition metal centers in metal-organic frameworks. J. Am. Chem. Soc. 129, 12606–12607 (2007)

    Article  CAS  Google Scholar 

  16. M.M.P. Silva, L.J. Carvalho, M. Lanznaster, J.A.L.C. Resende, Aqua(4,4′-bipyridine-[kappa]N)bis(1,4-dioxo-1,4-dihydronaphthalen-2-olato-[kappa]2O1, O2)zinc 4,4′-bipyridine monosolvate dihydrate. Acta Crystallogr. Sect. E 67, m1489–m1490 (2011)

    Article  CAS  Google Scholar 

  17. G. Valle-Bourrouet, V.M. Ugalde-Saldívar, M. Gómez, L.A. Ortiz-Frade, I. González, C. Frontana, Magnetic interactions as a stabilizing factor of semiquinone species of lawsone by metal complexation. Electrochim. Acta 55, 9042–9050 (2010)

    Article  CAS  Google Scholar 

  18. M. Mozurkewich, The dissociation constant of ammonium nitrate and its dependence on temperature, relative humidity and particle size. Atmos. Env. Part A. Gen. Top. 27, 261–270 (1993)

    Article  Google Scholar 

  19. A. Ghafarinazari, M. Mozafari, Simulation of structural features on mechanochemical synthesis of Al2O3–TiB2 nanocomposite by optimized artificial neural network. Adv. Powder Technol. 23, 220–227 (2012)

    Google Scholar 

  20. P. Sarawade, H. Tan, V. Polshettiwar, Shape-and morphology-controlled sustainable synthesis of CuCo, and in metal organic frameworks with high CO2 capture capacity. ACS Sustain. Chem. Eng. 1, 66–74 (2012)

    Google Scholar 

  21. E. Haque, S.H. Jhung, Synthesis of isostructural metal-organic frameworks, CPO-27 s, with ultrasound, microwave, and conventional heating: effect of synthesis methods and metal ions. Chem. Eng. J. 173, 866–872 (2011)

    Article  CAS  Google Scholar 

  22. N.A. Khan, E. Haque, S.H. Jhung, Rapid syntheses of a metal-organic framework material Cu3 (BTC) 2 (H2O) 3 under microwave: a quantitative analysis of accelerated syntheses. Phys. Chem. Chem. Phys. 12, 2625–2631 (2010)

    Article  CAS  Google Scholar 

  23. Z. Zhao, X. Li, Z. Li, Adsorption equilibrium and kinetics of p-xylene on chromium-based metal organic framework MIL-101. Chem. Eng. J. 173, 150–157 (2011)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Nano Chemistry, Graduate University of Advanced Technology, 7631133131, Kerman, Iran

    Ghasem Sargazi & Daryoush Afzali

  2. Department of Biotechnology, University of Verona, I-37134, Strada Le Grazie 15, Verona, Italy

    Ali Ghafainazari

  3. Department of Chemistry, University of Sistan and Baluchestan, Zahedan, Iran

    Hamideh Saravani

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  1. Ghasem Sargazi
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  2. Daryoush Afzali
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  3. Ali Ghafainazari
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  4. Hamideh Saravani
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Correspondence to Ali Ghafainazari.

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Sargazi, G., Afzali, D., Ghafainazari, A. et al. Rapid Synthesis of Cobalt Metal Organic Framework. J Inorg Organomet Polym 24, 786–790 (2014). https://doi.org/10.1007/s10904-014-0042-z

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  • DOI: https://doi.org/10.1007/s10904-014-0042-z

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