Skip to main content
SpringerLink
Log in

Synthesis, Crystal Structure, Vibrational Spectra, Optical Properties and Thermal Analysis of a New Chlorocadmate Templated by 1-(2-Ammoniumethyl) Piperazinium

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

Chemical preparation, X-ray single crystal diffraction, thermal analysis, electrochemical measurements, IR, Raman and UV spectroscopic investigations of a novel organic–inorganic hybrid material, (C6H18N3)Cd2Cl7(H2O)·2H2O, are described. The 1-(2-ammoniumethyl) piperazinium aquapentachlorocadmate(II) hexacholorocadmate(II) dihydrate crystallizes in the triclinic system with P−1 space group. Its unit cell dimensions are a = 9.174(3) Å, b = 9.709(3) Å, c = 12.956(4) Å, α = 96.77(3)°, β = 72,10(2)°, γ = 113.99(4)° with V = 1003,2(5) Å3, and Z = 2. The structure provides a new interesting example of infinite inorganic layers of [Cd2Cl7(H2O)] 3n−n following the b crystallographic direction. The CdCl6 2− and CdCl5(H2O)− anions are interconnected by O–H···Cl, N–H···O and N–H···Cl hydrogen bonds. Thermal analysis reveals the hydrous character of the compound. IR and Raman spectra are reported and discussed on the basis of group theoretical analysis. The optical study was also investigated by UV–Vis absorption spectra. Cyclic voltammetry was studied to evaluate the spectral and structural changes accompanying electron transfer.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme. 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. H.F. Qian, Y. Liu, T. Tao, K.H. Gu, G. Yin, W. Huang, Inorg. Chim. Acta 405, 1 (2013)

    Article  CAS  Google Scholar 

  2. Y.F. Wei, T. Wang, M. Pi, W. Song, C.M. Jin, J. Mol. Struct. 1027, 150 (2012)

    Article  CAS  Google Scholar 

  3. F.Q. Wang, D.F. Weng, X.J. Zheng, J.J. Zhang, H. Ma, L.P. Jin, Inorg. Chim. Acta 360, 2029 (2007)

    Article  CAS  Google Scholar 

  4. C.Y. Zheng, H. Li, Inorg. Chem. Commun. 34, 30 (2013)

    Article  CAS  Google Scholar 

  5. K.S. Tapan, S. Chakraborty, A.K. Mukherjee, M.G.B. Drew, R. Bhattacharyya, Polyhedron 27, 2233 (2008)

    Article  Google Scholar 

  6. S.P. Yáñez, O. Castillo, J. Cepeda, J.P.G. Terán, A. Luque, P. Román, Inorg. Chim. Acta 365, 211 (2011)

    Article  Google Scholar 

  7. T.H. Ma, J.H. Yu, L. Ye, J.Q. Xu, T.G. Wang, C.H. Lü, J. Mol. Struct. 654, 47 (2003)

    Article  CAS  Google Scholar 

  8. A. Ray, P.C. Mandal, A.D. Jana, W.S. Sheldrick, S. Mondal, M. Mukherjee, M. Ali, Polyhedron 27, 3112 (2008)

    Article  CAS  Google Scholar 

  9. G.J. Perpétuo, J. Janczak, J. Mol. Struct. 1041, 127 (2013)

    Article  Google Scholar 

  10. C.L. Bourdeau, N.B. Chanh, R. Duplessix, B. Gallois, J. Phys. Chem. Solids 54, 349 (1993)

    Article  Google Scholar 

  11. R. Puget, M. Jannin, C. de Brauer, R. Perret, Acta Cryst. C47, 1803 (1991)

    CAS  Google Scholar 

  12. W. Amamou, H. Feki, N. Chniba-Boudjada, F. Zouari, J. Mol. Struct. 1059, 169 (2014)

    Article  CAS  Google Scholar 

  13. A.B. Corradi, M.R. Cramarossa, G.C. Pellacani, L.P. Battaglia, J. Giusti, Gazz. Chim. Ital. 124, 481 (1994)

    CAS  Google Scholar 

  14. R. Xu, Acta Cryst. E65, m951 (2009)

    Google Scholar 

  15. M. Glaoui, M. Zeller, E. Jeanneau, C. BenNasra, Acta Cryst. E66, m895 (2010)

    Google Scholar 

  16. M. Charfi, A. Jouini, J. Solid State Chem. 127, 9 (1996)

    Article  CAS  Google Scholar 

  17. F. Issaoui, I. Baccar, E. Dhahri, O. El Sadek, F. Zouari, E.K. Hlil, J. Supercond. Nov. Magn. 25, 1563 (2012)

    Article  CAS  Google Scholar 

  18. M.R. Reisi, M.S. Salga, H. Khaledib, H.M. Alib, Acta Cryst. E67, o2400 (2011)

    Google Scholar 

  19. K. Harms, S. Wocadlo, XCAD4 (University of Marburg, Germany, 1995)

  20. G.M. Sheldrick, Acta Cryst. A64, 112 (2008)

    Article  Google Scholar 

  21. W.H. Baur, Acta Cryst. B13, 1195 (1974)

    Article  Google Scholar 

  22. L. Venkataramani, B.M. Craven, Acta Cryst. B47, 968 (1991)

    Article  Google Scholar 

  23. J. Tyrselova, L. Kuchta, F. Pavelcik, Acta Cryst. C52, 17 (1996)

    CAS  Google Scholar 

  24. C.B. Aakeröy, G.S. Bhara, M. Nieuwenhuyzen, Acta Cryst. C52, 1471 (1996)

    Google Scholar 

  25. V. Zima, K.H. Lii, J. Solid State Chem. 139, 326 (1998)

    Article  CAS  Google Scholar 

  26. M. Vanier, F. Brisse, Acta Cryst. B38, 3060 (1982)

    Article  CAS  Google Scholar 

  27. J.P. Sangin, F. Brisse, Acta Cryst. C40, 2091 (1984)

    CAS  Google Scholar 

  28. T. Guerfel, M. Bdiri, A. Jouini, J. Chem. Cryst. 29, 1205 (1999)

    Article  CAS  Google Scholar 

  29. T. Steiner, Angew. Chem. Int. Ed. 41, 48 (2002)

    Article  CAS  Google Scholar 

  30. L. Baouab, A. Jouini, J. Solid State Chem. 141, 343 (1998)

    Article  CAS  Google Scholar 

  31. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part A: Theory and Applications in Inorganic Chemistry , 6th edn. (Wiley, Hoboken, 2009)

    Google Scholar 

  32. S.M. Haile, P.M. Calkins, D. Boysen, J. Solid State Chem. 139, 373 (1998)

    Article  CAS  Google Scholar 

  33. A. Chtioui, T. Guerfel, L. Benhamada, A. Jouini, Solid State Sci. 3, 859 (2001)

    Article  CAS  Google Scholar 

  34. I. Němec, I. Císařová, Z. Mička, J. Solid State Chem. 140, 71 (1998)

    Article  Google Scholar 

  35. S.K. Lee, H.S. Choi, Bull. Korean Chem. Soc. 22, 463 (2001)

    CAS  Google Scholar 

  36. P. Deveci, B. Taner, Z. Klllç, A.O. Solak, U. Arslan, E. Özcan, Polyhedron 30, 1726 (2011)

    Article  CAS  Google Scholar 

  37. E.L. Torres, M.A. Mendiola, Polyhedron 24, 1435 (2005)

    Article  Google Scholar 

  38. X. Feng, Z.-F. Li, S.-F. Xue, Z. Tao, Q.-J. Zhu, Y.-Q. Zhang, J.-X. Liu, Inorg. Chem. 49, 7638 (2010)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Chimie du Solide, Faculté des Sciences de Monastir, Université de Monastir, 5000, Monastir, Tunisia

    Melek Hajji, Amel Gharbi & Taha Guerfel

Authors
  1. Melek Hajji
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Amel Gharbi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Taha Guerfel
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Taha Guerfel.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOC 39 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Hajji, M., Gharbi, A. & Guerfel, T. Synthesis, Crystal Structure, Vibrational Spectra, Optical Properties and Thermal Analysis of a New Chlorocadmate Templated by 1-(2-Ammoniumethyl) Piperazinium. J Inorg Organomet Polym 24, 766–775 (2014). https://doi.org/10.1007/s10904-014-0034-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-014-0034-z

Keywords

Search

Navigation