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Synthesis and Characterization of Copper(II)–Cysteine/SiO2–Al2O3 as an Efficient and Reusable Heterogeneous Catalyst for the Oxidation of Aromatic Alcohols

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Abstract

In the present study, heterogeneous copper(II)–cysteine/SiO2–Al2O3 catalyst was successfully prepared by a simple adsorption method. The physical and chemical properties of Cu(II)–cysteine/SiO2–Al2O3 were investigated by X-ray diffraction, thermal gravimetric analyzer, FT–IR spectroscopy, Brunauer–Emmett–Teller, UV–Vis spectroscopy, scanning electron microscopy and atomic absorption spectrometer. The obtained composite was effectively employed as catalyst for selective oxidation of various aromatic alcohols to corresponding aldehydes in high yields using hydrogen peroxide as an oxidant under mild condition. The catalyst can be recycled over five times without significant loss of activity.

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Authors and Affiliations

  1. Department of Chemistry, Shahreza Branch, Islamic Azad University, Shahreza, 31186145, Esfahān, Iran

    Farzad Zamani

  2. Central Laboratory Complex, Sheikh-Bahai Department, Isfahan Science and Technology Town, Isfahan University of Technology, 8415683111, Esfahān, Iran

    Elham Izadi

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  1. Farzad Zamani
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  2. Elham Izadi
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Correspondence to Farzad Zamani.

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Zamani, F., Izadi, E. Synthesis and Characterization of Copper(II)–Cysteine/SiO2–Al2O3 as an Efficient and Reusable Heterogeneous Catalyst for the Oxidation of Aromatic Alcohols. J Inorg Organomet Polym 23, 1501–1510 (2013). https://doi.org/10.1007/s10904-013-9956-0

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  • DOI: https://doi.org/10.1007/s10904-013-9956-0

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