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Synthesis, Crystal Structure and Antitumor Activity of Ca(II) Coordination Polymer Based on 1,5-Naphthalenedisulfonate

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Abstract

A novel Ca(II) coordination polymer, [CaL(H2O)2] n (L = 1,5-naphthalenedisulfonate), was synthesized by reaction of calcium perchlorate with 1,5-naphthalenedisulfonic acid sodium in CH3CH2OH/H2O. It was characterized by elemental analysis, IR, 1HNMR and thermal analysis. X-ray crystallographic reveals that the Ca(II) coordination polymer belongs to triclinic system, with space group P-1. The geometry of the Ca(II) ion is a distorted CaO6 octahedron coordination environment, arising from its coordination by two water molecules, and four oxygen atoms from two l ligands. The Ca(II) ions are linked through the O atoms of 1,5-naphthalenedisulfonate ligands to form 1D chain structure. And then a 2D layered structure is constructed by hydrogen bonds and π–π stacking. The antitumor activity of 1,5-naphthalenedisulfonic acid sodium ligand and its Ca(II) coordination polymer against human hepatoma smmc-7721 cell line and human lung adenocarcinoma A549 cell line have been investigated.

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Acknowledgments

The authors would like to thank the National Natural Science Foundation of China (Nos. 21171132 and 20671073), the Promotive Research Fund for Excellent Young and Middle-aged Scientisits of Shandong Province (2010BSA07004) and Science Foundation of Weifang University.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Weifang University, Weifang, 261061, China

    Xi-Shi Tai

  2. Department of Chemistry, Qinghai Normal University, Xining, 810008, China

    Wen-Hua Zhao

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  1. Xi-Shi Tai
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  2. Wen-Hua Zhao
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Correspondence to Xi-Shi Tai.

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Tai, XS., Zhao, WH. Synthesis, Crystal Structure and Antitumor Activity of Ca(II) Coordination Polymer Based on 1,5-Naphthalenedisulfonate. J Inorg Organomet Polym 23, 1354–1357 (2013). https://doi.org/10.1007/s10904-013-9936-4

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  • DOI: https://doi.org/10.1007/s10904-013-9936-4

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