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2D and 1D Coordination Polymers of Ag(I) Ions with 2,6-Naphthalenedicarboxylate and N–Donor Coligands

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Abstract

Two new Ag(I) coordination polymers [Ag2(mepyz)](2,6-ndc)] n (1) and [Ag4(4,4′-bipy)]4(2,6-ndc)2·8(H2O) (2) (where 2,6-ndcH2 = 2,6-napthalene dicarboxylic acid, mepyz = 2-methyl pyrazine and 4,4′-bipy = 4,4′-bipyridine) have been synthesized and characterized by single crystal X-ray diffraction analysis. Complex 1 displays a 2D rectangular grid architecture comprising short Ag···Ag interactions, while 2 is a 1D coordination polymer: both enlarge their dimensionality to 3D via weak interactions. Luminescence study performed on complexes as well on ligands shows metal perturbed intraligand CT transition.

Graphical Abstract

Two new luminescent coordination polymers of Ag(I) have been synthesized. The X-ray structural determination analysis revealed 2D and 1D coordination polymers that enlarge dimensionality to 3D via weak supramolecular interactions.

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Acknowledgments

The work carried out in this paper is financially supported by CSIR, New Delhi, India [No. 01(2536)/11/EMR-II]. S.K.J is thankful to UGC for providing research fellowship.

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Authors and Affiliations

  1. Department of Chemistry and Chemical Technology, Vidyasagar University, Midnapore, 721 102, West Bengal, India

    Madhusudan Bera, Swapan Kumar Jana, Debdoot Hazari, Abhinandan Rana, Durga Sankar Chowdhuri & Sudipta Dalai

  2. Department of Chemistry, Durham University, Durham, DH1 3LE, UK

    Horst Puschmann

  3. Dipartimento di Scienze Chimiche e Farmaceutiche, University of Trieste, 34127, Trieste, Italy

    Ennio Zangrando

Authors
  1. Madhusudan Bera
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  2. Swapan Kumar Jana
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  8. Sudipta Dalai
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Correspondence to Sudipta Dalai.

Appendix

CCDC 885243 and 885244 contain the supplementary crystallographic data for compounds 1 and 2, respectively. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.

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Supplementary material 1 (DOC 186 kb)

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Bera, M., Jana, S.K., Hazari, D. et al. 2D and 1D Coordination Polymers of Ag(I) Ions with 2,6-Naphthalenedicarboxylate and N–Donor Coligands. J Inorg Organomet Polym 23, 325–332 (2013). https://doi.org/10.1007/s10904-012-9780-y

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