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Synthesis and Characterization of Sporopollenin-Supported Schiff Bases and Ruthenium(III) Sorption Studies

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Abstract

Two Schiff base derivatives, (2-pycolylimino)benzen-1,4-diol and (2-pyridylimino)benzen-1,4-diol) were immobilized onto sporopollenin (Lycopodium clavatum) surfaces. The compounds were fully characterized by an infrared spectroscopy, elemental analysis, scanning electron microscopy, and X-ray diffraction techniques. The sorption capacities of the immobilized surfaces toward Ru(III) ions were investigated by batch sorption experiments. For the sorption experiment, the Ru(III) concentration, initial pH, and the temperature effects were studied. The isotherm data of Ru(III) ions were correlated reasonably well as a Freundlich sorption isotherm. The thermodynamic studies showed that the Ru(III) sorption onto immobilized sporopollenin derivatives is a non-spontaneous, endothermic and physical reaction.

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Acknowledgments

We thank the Selcuk University Research Foundation and Necmettin Erbakan University Research Foundation for the financial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Selcuk University, 42075, Konya, Turkey

    Mustafa Sahin & Ilkay Hilal Gubbuk

  2. Department of Science Education, Faculty of Education, Necmettin Erbakan University, 42090, Konya, Turkey

    Nuriye Kocak

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  1. Mustafa Sahin
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  2. Ilkay Hilal Gubbuk
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  3. Nuriye Kocak
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Correspondence to Mustafa Sahin.

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Sahin, M., Gubbuk, I.H. & Kocak, N. Synthesis and Characterization of Sporopollenin-Supported Schiff Bases and Ruthenium(III) Sorption Studies. J Inorg Organomet Polym 22, 1279–1286 (2012). https://doi.org/10.1007/s10904-012-9739-z

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  • DOI: https://doi.org/10.1007/s10904-012-9739-z

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