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Thermal and Fluorescence Properties of New Nanostructured Hg(ll) -2,2′-Bipyridine Derivative Complexes

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Abstract

Two new nano-structured Hg(II) supramolecular complexes, [Hg(5,5′-di-t-but-bpy)(μ-Br)Br]2[Hg(5,5′-di-t-but-bpy)Br2](1) and [Hg(5,5′-di-t-but-bpy)I2] (2) were synthesized by the sonochemical method. The structures of 1 and 2 were characterized by elemental analysis, IR, 1H-NMR, and 13C-NMR spectroscopy and single crystal X-ray diffraction. Their thermal stabilities were studied by thermogravimetric and differential thermal analyses. Solid-state luminescent spectra of 1 and 2 indicate a fluorescent broad emission band between 304 and 404 nm with excitation at 284 nm. These nanostructured coordination polymers were characterized by scanning electron microscopy, elemental analysis, and IR spectroscopy.

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Acknowledgments

Support of this investigation by Payam Noor University is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Payame Noor University, P.O. Box 19395-3697, Tehran, Iran

    Jafar Abedini

  2. Department of Chemistry, Faculty of Sciences, Islamic Azad University, Shahr-e-Rey Branch, Tehran, Iran

    Mojtaba Hosseinifard, Vahid Amani & Khadijeh Kalateh

  3. Department of Chemistry, Faculty of Sciences, TarbiatModares University, P.O. Box 14155-4838, Tehran, Iran

    Lida Hashemi & Ali Morsali

Authors
  1. Jafar Abedini
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  2. Mojtaba Hosseinifard
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  3. Lida Hashemi
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  4. Vahid Amani
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  5. Khadijeh Kalateh
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  6. Ali Morsali
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Correspondence to Jafar Abedini or Ali Morsali.

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Abedini, J., Hosseinifard, M., Hashemi, L. et al. Thermal and Fluorescence Properties of New Nanostructured Hg(ll) -2,2′-Bipyridine Derivative Complexes. J Inorg Organomet Polym 22, 1221–1227 (2012). https://doi.org/10.1007/s10904-012-9707-7

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