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Two Supramolecular Microporous Metal–Organic Frameworks Templated by Keggin Polyoxometalates

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Abstract

Two new Keggin polyoxometalates (POM)-templated supramolecular metal–organic frameworks (MOF) with micropores, Cu3(L)6[H3(PMo12O40)2]·6H2O (1) and Cu3(L)6[H5(SiW12O40)2]·6H2O (2) (L = 1,2-bis(imidazol-1-ylmethyl)ethane), have been prepared under hydrothermal conditions and characterized by single-crystal X-ray diffraction, elemental analyses, IR spectra and cyclic voltammetry. These two isostructural compounds are constructed by two distinct moieties, a Keggin polyanion and a linear [Cu(L)2]+ subunit. The [Cu(L)2]+ subunits further form a microporous MOF through supramolecular interactions. The Keggin polyanions act as templates inducing the micropores. The electrochemical and electrocatalytic behavior of compounds 1 and 2 bulk-modified carbon paste electrodes (1-, 2-CPE) was studied.

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References

  1. B.S. Bassil, M. Ibrahim, R. Al-Oveini, M. Asano, Z. Wang, J. Tol, N.S. Dalal, K.Y. Choi, R.N. Biboum, B. Keita, L. Nadjo, U. Kortz, Angew. Chem. Int. Ed. 50, 5961 (2011)

    Article  CAS  Google Scholar 

  2. F.J. Ma, S.X. Liu, C.Y. Sun, D.D. Liang, G.J. Ren, F. Wei, Y.G. Chen, Z.M. Su, J. Am. Chem. Soc. 133, 4178 (2011)

    Article  CAS  Google Scholar 

  3. J. Zhang, J. Hao, Y.G. Wei, F.P. Xiao, P.C. Yin, L.S. Wang, J. Am. Chem. Soc. 132, 14 (2010)

    Article  CAS  Google Scholar 

  4. Y.L. Zhong, W. Ng, J.X. Yang, K.P. Loh, J. Am. Chem. Soc. 131, 18293 (2009)

    Article  CAS  Google Scholar 

  5. C. Streb, R. Tsunashima, D.A. MacLaren, T. McGlone, T. Akutagawa, T. Nakamura, A. Scandurra, B. Pignataro, N. Gadegaard, L. Cronin, Angew. Chem. Int. Ed. 48, 6490 (2009)

    Article  CAS  Google Scholar 

  6. S.T. Zheng, J. Zhang, J.M. Clemente-Juan, D.Q. Yuan, G.Y. Yang, Angew. Chem. Int. Ed. 48, 7176 (2009)

    Article  CAS  Google Scholar 

  7. X.L. Wang, C. Qin, E.B. Wang, Z.M. Su, Y.G. Li, L. Xu, Angew. Chem. Int. Ed. 45, 7411 (2006)

    Article  CAS  Google Scholar 

  8. Y.Q. Lan, S.L. Li, X.L. Wang, K.Z. Shao, D.Y. Du, Z.M. Su, E.B. Wang, Chem. Eur. J. 14, 9999 (2008)

    Article  CAS  Google Scholar 

  9. A.X. Tian, J. Ying, J. Peng, J.Q. Sha, Z.G. Han, J.F. Ma, Z.M. Su, N.H. Hu, H.Q. Jia, Inorg. Chem. 47, 3274 (2008)

    Article  CAS  Google Scholar 

  10. S. Upreti, A. Ramanan, Cryst. Growth Des. 5, 1837 (2005)

    Article  CAS  Google Scholar 

  11. X.Y. Zhao, D.D. Liang, S.X. Liu, C.Y. Sun, R.G. Cao, C.Y. Gao, Y.H. Ren, Z.M. Su, Inorg. Chem. 47, 7133 (2008)

    Article  CAS  Google Scholar 

  12. Z.G. Han, Y.Z. Gao, X.L. Zhai, J. Peng, A.X. Tian, Y.L. Zhao, C.W. Hu, Cryst. Growth Des. 9, 1225 (2009)

    Article  CAS  Google Scholar 

  13. Z.G. Han, Y.L. Zhao, J. Peng, A.X. Tian, Q. Liu, J.F. Ma, E.B. Wang, N.H. Hu, CrystEngComm 7, 380 (2005)

    Article  CAS  Google Scholar 

  14. Z.G. Han, Y.Z. Gao, C.W. Hu, Cryst. Growth Des. 8, 1261 (2008)

    Article  CAS  Google Scholar 

  15. Y.M. Xie, Q.S. Zhang, Z.G. Zhao, X.Y. Wu, S.C. Chen, C.Z. Lu, Inorg. Chem. 47, 8086 (2008)

    Article  CAS  Google Scholar 

  16. E. Coronado, C.J. Gómez-García, Chem. Rev. 98, 273 (1998)

    Article  CAS  Google Scholar 

  17. J.Q. Sha, J. Peng, Y.Q. Lan, Z.M. Su, H.J. Pang, A.X. Tian, P.P. Zhang, M. Zhu, Inorg. Chem. 47, 5145 (2008)

    Article  CAS  Google Scholar 

  18. L. Lisnard, A. Dolbecq, P. Mialane, J. Marrot, E. Codjovi, F. Sécheresse, Dalton Trans. 34, 3913 (2005)

    Article  Google Scholar 

  19. P.P. Zhang, J. Peng, J.Q. Sha, A.X. Tian, H.J. Pang, Y. Chen, M. Zhu, CrystEngComm 11, 902 (2009)

    Article  CAS  Google Scholar 

  20. X.J. Li, X.Y. Wang, S. Gao, R. Cao, Inorg. Chem. 45, 1508 (2006)

    Article  CAS  Google Scholar 

  21. X.J. Li, R. Cao, Z.G. Guo, Y.F. Li, X.D. Zhu, Polyhedron 26, 3911 (2007)

    Article  CAS  Google Scholar 

  22. L.P. Wu, Y. Yamagiwa, T. Kuroda-Sowa, T. Kamikawa, M. Munakata, Inorg. Chim. Acta 256, 155 (1997)

    Article  CAS  Google Scholar 

  23. J.G. Ding, H.Y. Ge, Y.M. Zhang, B.L. Li, Y. Zhang, J. Mol. Struct. 782, 143 (2006)

    Article  CAS  Google Scholar 

  24. X. Zhu, J.W. Zhao, B.L. Li, Y. Song, Y.M. Zhang, Y. Zhang, Inorg. Chem. 49, 1266 (2010)

    Article  CAS  Google Scholar 

  25. G.M. Sheldrick, Acta Crystallogr. A 64, 112 (2008)

    Article  Google Scholar 

  26. K. Pavani, A. Ramanan, Eur. J. Inorg. Chem. 40, 3080 (2005)

    Article  Google Scholar 

  27. P.Q. Zheng, Y.P. Ren, L.S. Long, R.B. Huang, L.S. Zheng, Inorg. Chem. 44, 1190 (2005)

    Article  CAS  Google Scholar 

  28. A.X. Tian, J. Ying, J. Peng, J.Q. Sha, H.J. Pang, P.P. Zhang, Y. Chen, M. Zhu, Z.M. Su, Inorg. Chem. 48, 100 (2009)

    Article  CAS  Google Scholar 

  29. C.M. Liu, D.Q. Zhang, D.B. Zhu, Cryst. Growth Des. 6, 524 (2006)

    Article  CAS  Google Scholar 

  30. I.D. Brown, D. Altermatt, Acta Crystallogr. B 41, 244 (1985)

    Article  Google Scholar 

  31. Z.G. Han, Y.L. Zhao, J. Peng, Q. Liu, E.B. Wang, Electrochim. Acta 51, 218 (2005)

    Article  CAS  Google Scholar 

  32. A.X. Tian, J. Ying, J. Peng, J.Q. Sha, H.J. Pang, P.P. Zhang, Y. Chen, M. Zhu, Z.M. Su, Cryst. Growth Des. 8, 3717 (2008)

    Article  CAS  Google Scholar 

  33. M. Sadakane, E. Steckhan, Chem. Rev. 98, 219 (1998)

    Article  CAS  Google Scholar 

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Acknowledgments

We are thankful for financial support from the National Natural Science Foundation of China (No. 21101015 and 21171025), New Century Excellent Talents in University (NCET-09-0853) and Doctoral Initiation Project of Liaoning Province (No. 20111147).

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Authors and Affiliations

  1. Department of Chemistry, Bohai University, Jinzhou, 121000, People’s Republic of China

    Yujing Liu, Xiaoling Lin, Jun Ying & Aixiang Tian

  2. Liaoning Ocean and Fisheries Science Research Institute, DaLian, 116023, People’s Republic of China

    Guiying Liu

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  1. Yujing Liu
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  2. Xiaoling Lin
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  3. Guiying Liu
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  4. Jun Ying
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Correspondence to Aixiang Tian.

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Liu, Y., Lin, X., Liu, G. et al. Two Supramolecular Microporous Metal–Organic Frameworks Templated by Keggin Polyoxometalates. J Inorg Organomet Polym 22, 946–951 (2012). https://doi.org/10.1007/s10904-012-9701-0

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