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1D Coordination Polymer from Tetraaza Macrocyclic Nickel(II) Complex and 1,2,3,4-Cyclobutanetetracarboxylic Acid

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Abstract

The self assembly of [Ni(L)]Cl2·2H2O (L = 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,01.18,07.12]docosane) and 1,2,3,4-cyclobutanetetracarboxylic acid (H4cbtc) acid generates a 1D coordination and 2D hydrogen-bonded polymer [Ni(L)(H2cbtc)2·3H2O] n (1). Complex 1 is characterized by X-ray crystallography, spectroscopy and magnetic susceptibility. Each nickel(II) ion has a distorted octahedral coordination environment with the four secondary amines of the macrocycle in which two carboxylate anions of the H2cbtc2− ligand have assembled around each nickel center. The compound crystallizes in the triclinic system P-1 with a = 9.715(3) Å, b = 12.891(5) Å, c = 13.903(6) Å, α = 72.64(2)°, β = 75.70(3)°, γ = 73.27(3)°, V = 1566.6(10) Å3, Z = 2. The electronic spectrum of 1 indicates a high-spin octahedral environment. The magnetic behavior of 1 reveals a weak intramolecular antiferromagnetic interaction with J = −1.23(1) cm−1.

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  1. Department of Chemistry Education, Kongju National University, Kongju, 314-701, Korea

    Ki-Young Choi & In-Taek Lim

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  1. Ki-Young Choi
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Correspondence to Ki-Young Choi.

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Choi, KY., Lim, IT. 1D Coordination Polymer from Tetraaza Macrocyclic Nickel(II) Complex and 1,2,3,4-Cyclobutanetetracarboxylic Acid. J Inorg Organomet Polym 22, 1194–1199 (2012). https://doi.org/10.1007/s10904-012-9693-9

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