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Tail of the Organic Ligand Templated Metal-Organic Framework

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Abstract

A new compound, namely [Zn2(L1)2(H2O)]n (1, H2L1 = 5–(benzyloxy)isophthalic acid), was hydrothermally synthesized and characterized by elemental analysis, FT-IR spectra and powder X-ray diffraction. Single crystal x-ray diffraction reveals that 1 features a three-dimensional framework with the tails (phenyl groups) of the organic ligands (L1) effectively filling in the hexagonal channels and playing a template role. Compound 1 exhibits an intense violet photoluminescence in the solid state at room temperature.

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Acknowledgments

This work was supported by 973 Program of China (2011CBA00505), the Chinese Academy of Sciences (KJCX2-YW-H30, KGCX2-YW-222 and KJCX2-YW-M10) and the Science Foundation of the Fujian Province (2009HZ0005-1 and 2006L2005).

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Authors and Affiliations

  1. Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, Fujian, People’s Republic of China

    Xin Zhang, Jin-Xia Yang & Yuan-Gen Yao

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  1. Xin Zhang
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  2. Jin-Xia Yang
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  3. Yuan-Gen Yao
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Correspondence to Yuan-Gen Yao.

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Zhang, X., Yang, JX. & Yao, YG. Tail of the Organic Ligand Templated Metal-Organic Framework. J Inorg Organomet Polym 22, 1189–1193 (2012). https://doi.org/10.1007/s10904-012-9690-z

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