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Sonochemical Synthesis and Characterization of A Nano-Rod Lead(II) Supramolecular, Three Dimensional Coordination Compound: New Precursor to Produce Pure Phase Nano-Sized Lead(II) Oxide

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Abstract

Nanorods of a lead(II) supramolecular three-dimensional (3D) coordination compound, [Pb(tfpb)2]n (1) (Htfpb = 4,4,4-trifluoro-1-phenyl-1,3-butanedione), was prepared by the sonochemical method. The new nano-structure was characterized by scanning electron microscopy, X-ray powder diffraction, elemental analyses and IR spectroscopy. A single-crystal structure of the compound showed that the coordination number of Pb(II) is eight with six O-donor atoms from the tfpb ligand and two F-donors from anionic ligands. The 3D supramolecular structure of 1 is realized by weak directional C–F···F–C and π–π stacking interactions. After calcination of nano-sized 1 at 500 °C, pure phase nano-sized lead(II) oxide is produced.

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Acknowledgments

This work is funded by the World Class University Grant R32-2008-000-20082-0 and the Grant 2011-0014246 of the National Research Foundation of Korea.

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Authors and Affiliations

  1. WCU Nano Research Center, Yeungnam University, Gyongsan, 712-749, Korea

    Younes Hanifehpour, Babak Mirtamizdoust & Sang Woo Joo

  2. Department of Inorganic Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran

    Younes Hanifehpour & Babak Mirtamizdoust

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  1. Younes Hanifehpour
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  2. Babak Mirtamizdoust
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  3. Sang Woo Joo
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Correspondence to Sang Woo Joo.

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Hanifehpour, Y., Mirtamizdoust, B. & Joo, S.W. Sonochemical Synthesis and Characterization of A Nano-Rod Lead(II) Supramolecular, Three Dimensional Coordination Compound: New Precursor to Produce Pure Phase Nano-Sized Lead(II) Oxide. J Inorg Organomet Polym 22, 952–956 (2012). https://doi.org/10.1007/s10904-012-9678-8

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  • DOI: https://doi.org/10.1007/s10904-012-9678-8

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