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Sonochemical Synthesis and Characterization of the First Flower-Like Cadmium(II) Coordination Compound: New Precursor to Produce Pure Phase Nano-Sized Cadmium(II) Oxide

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Abstract

For the first time the flower-like cadmium(II) coordination compound, [Cd(2,2’-bpy)(ftfa)2]n (1), (2,2’-bpy = 2,2’-bipyridine; ftfa = furoyltrifluoroacetonate) is synthesized sonochemically. The new nano-structure was characterized by scanning electron microscopy, X-ray powder diffraction, elemental analyses and IR spectroscopy. Single crystalline material is obtained using a heat gradient applied to a solution of the reagents. The thermal stability of compound is studied by thermogravimetric and differential thermal analyses. After calcinations of nano-sized 1 at 400 °C, pure phase nano-sized Cd(II) oxide was produced. The average size of the nanoparticles is estimated by the Scherrer equation (diameter ≈ 25 nm). The morphology and size of the prepared Cd(II)O samples are examined by SEM.

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Acknowledgment

This work is funded by the World Class University Grant KRF R32-2008-000-20082-0 of the National Research Foundation of Korea.

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Authors and Affiliations

  1. School of Mechanical Engineering, WCU Nano Research Center, Yeungnam University, Gyongsan, 712-749, South Korea

    Younes Hanifehpour, Babak Mirtamizdoust & Sang Woo Joo

  2. Department of Inorganic Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran

    Younes Hanifehpour & Babak Mirtamizdoust

Authors
  1. Younes Hanifehpour
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  2. Babak Mirtamizdoust
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  3. Sang Woo Joo
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Correspondence to Sang Woo Joo.

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Hanifehpour, Y., Mirtamizdoust, B. & Joo, S.W. Sonochemical Synthesis and Characterization of the First Flower-Like Cadmium(II) Coordination Compound: New Precursor to Produce Pure Phase Nano-Sized Cadmium(II) Oxide. J Inorg Organomet Polym 22, 549–553 (2012). https://doi.org/10.1007/s10904-012-9654-3

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  • DOI: https://doi.org/10.1007/s10904-012-9654-3

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