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Synthesis of Lead(II) Minoxidil Coordination Polymer: A New Precursor for Lead(II) Oxide and Lead(II) Hydroxyl Bromide

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Abstract

A new lead(II) coordination polymer, [PbBr2(C9H15N5O)]n (1), where C9H15N5O is (2,4-diamino-6-piperidine-1-yl) pyrimidine N-oxide (minoxidil) is synthesized and characterized. Polymer 1 is synthesized in methanol by sonochemical and hydrothermal methods from lead(II) acetate, KBr and the minoxidil ligand. The crystal structure of [PbBr2(C9H15N5O)]n indicates a syndiotactic coordination polymer. The Pb(II) atom lies on a mirror plane; the mirror plane is perpendicular to the pyrimidine ring bisecting the piperidine ring. N–H···O intramolecular and C–H···Br, N–H···N strong intermolecular interactions were observed. Micro-rods of PbO and nano-plates of PbOHBr were prepared by thermal decomposition of the nano-structured [PbBr2(C9H15N5O)]n as a precursor. Characterization of the products was carried out using X-ray crystallography, elemental analysis, FTIR spectroscopy, scanning electron microscopy, energy dispersive X-ray analysis and thermal analysis. The sonochemical method resulted in a significant reduction of reaction time, reaction temperature and particle sizes of the products.

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Acknowledgment

The authors would like to express gratitude for support by nanotechnology initiative council (Project Number 89118) and for financial assistance by Iranian Research Organization for Science and Technology. The authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskisehir, Turkey, for the use of X-ray diffractometer.

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Authors and Affiliations

  1. Department of Chemical Technologies, Iranian Research Organization for Science and Technology, P.O. Box 15815-3538, Tehran, Iran

    Maryam Ranjbar & S. Heydar Mahmoudi Najafi

  2. Department of Physics, Faculty of Education, Dicle University, Diyarbakr, Turkey

    Ömer Çelik

  3. Department of Chemistry, Islamic Azad University, Shahr-e Rey Branch, Tehran, Iran

    Shabnam Sheshmani & Neda Akbari Mobarakeh

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  1. Maryam Ranjbar
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  2. Ömer Çelik
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  3. S. Heydar Mahmoudi Najafi
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  4. Shabnam Sheshmani
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  5. Neda Akbari Mobarakeh
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Correspondence to Maryam Ranjbar.

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Ranjbar, M., Çelik, Ö., Mahmoudi Najafi, S.H. et al. Synthesis of Lead(II) Minoxidil Coordination Polymer: A New Precursor for Lead(II) Oxide and Lead(II) Hydroxyl Bromide. J Inorg Organomet Polym 22, 837–844 (2012). https://doi.org/10.1007/s10904-011-9648-6

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  • DOI: https://doi.org/10.1007/s10904-011-9648-6

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