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Design, Synthesis and Optical Properties of Tetrahedrally Silicon-Cored Phenyl-Linked Pyrazole Ligands

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Abstract

A novel series of tetrahedrally silicon-centered pyrazole derivatives, including bis(4-(pyrazol-1-yl)phenyl)dimethylsilane (1), bis(3-(pyrazol-1-yl)phenyl)dimethylsilane (2) and tri(4-(pyrazole-1-yl)phenyl)methylsilane (3) have been designed, synthesized and determined by FT-IR, 1H NMR, 13C NMR, 29Si NMR and mass spectroscopy. These compounds are stable in moisture and have high thermal stability. The optical properties reveal that these compounds show a fluorescent emission in the blue-violet region, which could be potentially applied as blue emitters for OLEDs and utilized to construct functional MOFs with luminescent properties.

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Acknowledgments

This work was supported by the Scientific and Technological Project of Shandong Province (2008GG30003009) and Doctor Foundation of Shandong Province (BS2009CL0153).

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Authors and Affiliations

  1. School of Materials Science and Engineering, University of Jinan, Jinan, 250022, People’s Republic of China

    Qing-Yu Ma

  2. Key Laboratory of Special Functional Aggregated Materials of Ministry of Education; School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, People’s Republic of China

    Deng-Xu Wang

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  1. Qing-Yu Ma
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  2. Deng-Xu Wang
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Correspondence to Deng-Xu Wang.

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Ma, QY., Wang, DX. Design, Synthesis and Optical Properties of Tetrahedrally Silicon-Cored Phenyl-Linked Pyrazole Ligands. J Inorg Organomet Polym 21, 797–801 (2011). https://doi.org/10.1007/s10904-011-9553-z

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  • DOI: https://doi.org/10.1007/s10904-011-9553-z

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