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An Efficient and Recyclable Silica Based Inorganic–Organic Hybrid Zinc Catalyst for Transesterification of β-Ketoesters

  • R. K. Sharma
  • Deepti Rawat
Article

Abstract

A new silica based inorganic–organic hybrid zinc catalyst was synthesized and its catalytic activity was investigated for transesterification of β-ketoesters. Polymer supported catalyst was characterized by various techniques such as surface area (BET), elemental and thermogravimetric analyses, FTIR, 13C CPMAS spectral studies and atomic absorption spectroscopy (AAS). The reaction proceeded smoothly in the presence of 0.04 mmol of catalyst in toluene at refluxing conditions. The catalyst revealed higher catalytic activity compared to homogeneous catalyst and was reused without appreciable loss in catalytic activity.

Keywords

Transesterification β-Ketoesters Recyclable Silica Inorganic–organic 

Notes

Acknowledgment

Authors gratefully acknowledge IISc Bangalore for carrying out solid state NMR analyses.

Supplementary material

10904_2011_9525_MOESM1_ESM.doc (29 kb)
Supplementary material 1 (DOC 29 kb)

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Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  1. 1.Department of Chemistry, Green Chemistry Network CentreUniversity of DelhiDelhiIndia

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