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Cyano-Bridged Heteropolynuclear Ni(II), Cu(II) and Cd(II) Complexes, [M(deten)2Ni(μ-CN)2(CN)2] n

  • Güneş Süheyla Kürkçüoğlu
  • Tuncer Hökelek
  • Mehran Aksel
  • Okan Zafer Yeşilel
  • Hakan Dal
Article

Abstract

Three new complexes [M(deten)2Ni(μ-CN)2(CN)2] n (M = Ni, Cu and Cd, deten = N,N-diethylethylenediamine) have been synthesized and characterized by chemical, thermal analysis, FT-IR and Raman spectroscopies. The crystal structure of the Cd complex has been determined by X-ray single crystal diffraction. Structural study reveals that the Ni2+ and Cd2+ ions are located on inversion centers, and adopt slightly distorted square-planar and octahedral geometries, respectively. In the crystal structure, the intermolecular N–H⋯N hydrogen bonds link the polymeric chains into a two dimensional network. Vibrational spectral data indicate the presence of two ν(C≡N) for complexes can be assigned to the terminal and bridging cyanides. The decomposition reaction take places in the temperature range 30–1000 °C in the static air atmosphere.

Keywords

Heterometallic complexes Cyano-bridged complexes Tetracyanonickelate(II) complexes N,N-Diethylethylenediamine complexes 

Notes

Acknowledgment

This work was supported by the Research Fund of Eskişehir Osmangazi University. Project number: 201019024.

References

  1. 1.
    K.R. Dunbar, R.A. Heintz, Prog. Inorg. Chem. 45, 283 (1997)CrossRefGoogle Scholar
  2. 2.
    T. Mallah, S. Thiebaut, M. Verdaguer, P. Veillet, Science 262, 1554 (1993)CrossRefGoogle Scholar
  3. 3.
    M. Verdaguer, A. Bleuzen, V. Marvaud, J. Vaissermann, M. Seuleiman, C. Desplanches, A. Scuiller, C. Train, R. Garde, G. Gelly, C. Lomenech, I. Rosenman, P. Veillet, C. Cartier, F. Villain, Coord. Chem. Rev. 190, 1023 (1999)CrossRefGoogle Scholar
  4. 4.
    M. Ohba, K. Okawa, Coord. Chem. Rev. 198, 313 (2000)CrossRefGoogle Scholar
  5. 5.
    J. Cernak, M. Orendac, I. Potocnak, J. Chomic, A. Orendacova, J. Skorsepa, A. Feher, Coord. Chem. Rev. 224, 51 (2002)CrossRefGoogle Scholar
  6. 6.
    Z.Z. Gu, O. Sato, T. Iyoda, K. Hashimoto, A. Fujishima, Chem. Mater. 9, 1092 (1997)CrossRefGoogle Scholar
  7. 7.
    J.S. Miller, A.J. Epstein (eds.), MRS Bull. 21, 25 (2000)Google Scholar
  8. 8.
    L. Yet, Angew. Chem. Int. Ed. Engl. 40, 875 (2001)CrossRefGoogle Scholar
  9. 9.
    A. Karadağ, I. Önal, A. Şenocak, I. Uçar, A. Bulut, O. Büyükgüngör, Polyhedron 27, 223 (2008)CrossRefGoogle Scholar
  10. 10.
    P.S. Mukherjee, T.K. Maji, T. Mallah, E. Zangrando, L. Randaccio, N.R. Chaudhuri, Inorg. Chim. Acta 315, 249 (2001)CrossRefGoogle Scholar
  11. 11.
    T. Iwamoto, in Inclusion Compounds, vol. 1, ed. by J.L. Atwood, J.E.D. Davies, D.D. Mac Nicol (Academic, London, 1984), pp. 29–57Google Scholar
  12. 12.
    T. Iwamoto, J. Incl. Phenom. 24, 61 (1996)CrossRefGoogle Scholar
  13. 13.
    T. Iwamoto, in Inclusion Compounds, Chap. 2, vol. 5, ed. by J.L. Atwood, J.E.D. Davies, D.D. Mac Nicol (Oxford University Press, Oxford, 1991), pp. 177–212Google Scholar
  14. 14.
    C. Janiak, H.P. Wu, P. Klüfers, P. Mayer, Acta Cryst. C55, 1966 (1999)Google Scholar
  15. 15.
    J. Cernák, J. Skoršepa, K.A. Abboud, M.W. Meisel, M. Orendáč, A. Orendáčová, A. Feher, Inorg. Chim. Acta 326(1), 3 (2001)CrossRefGoogle Scholar
  16. 16.
    M. Kajnaková, J. Cernák, V. Kavecanský, F. Gérard, T. Papageorgiou, M. Orendác, A. Orendácová, A. Feher, Solid State Sci. 8, 203 (2006)CrossRefGoogle Scholar
  17. 17.
    J. Cernák, J. Lipkowski, E. Cižmár, A. Orendácovác, M. Orendác, A. Feher, M.W. Meisel, Solid State Sci. 5, 579 (2003)CrossRefGoogle Scholar
  18. 18.
    A. Sopkova, J. Mol. Struct. 75, 81 (1981)CrossRefGoogle Scholar
  19. 19.
    J. Cernák, K.A. Abboud, Acta Cryst. C58, 167 (2002)Google Scholar
  20. 20.
    J. Paharova, J. Cernák, R. Boc, Z. Zak, Inorg. Chim. Acta 346, 25 (2003)CrossRefGoogle Scholar
  21. 21.
    G.S. Kürkçüoğlu, T. Hökelek, O.Z. Yeşilel, S. Aksay, Struct. Chem. 19, 493 (2008)CrossRefGoogle Scholar
  22. 22.
    G.S. Kürkçüoğlu, O.Z. Yeşilel, İ. Kavlak, O. Büyükgüngör, Z. Anorg. Allg. Chem. 635, 175 (2009)CrossRefGoogle Scholar
  23. 23.
    J. Cernák, J. Chomic, J. Therm. Anal. 32(2), 527 (1987)CrossRefGoogle Scholar
  24. 24.
    J. Chomic, J. Cernák, Thermochim. Acta 93, 93 (1985)CrossRefGoogle Scholar
  25. 25.
    J. Chomic, J. Skorsepa, J. Cernak, Thermochim. Acta 93, 113 (1985)CrossRefGoogle Scholar
  26. 26.
    J. Cernak, J. Chomic, D. Baloghova, M. Dunaj-Jurco, Acta Crystallogr. Sect. C44, 1902 (1988)Google Scholar
  27. 27.
    J. Cernak, J. Chomic, P. Domiano, O. Ori, G.D. Andreetti, Acta Crystallogr. C46, 2103 (1990)Google Scholar
  28. 28.
    G.J. Gainsford, N.F. Curtis, Aust. J. Chem. 37, 1799 (1984)CrossRefGoogle Scholar
  29. 29.
    J. Cernak, K.A. Abboud, Acta Crystallogr. C56, 783 (2000)Google Scholar
  30. 30.
    S.Z. Zhan, D. Guo, X.Y. Zhang, C.X. Du, Y. Zhu, Inorg. Chim. Acta 298, 57 (2000)CrossRefGoogle Scholar
  31. 31.
    M. Dunaj-Jurco, J. Garaj, J. Chomic, V. Haluska, F. Valach, Proceedings of the Sixth Conference on Coordination Chemistry (Smolenice-Bratislava, 1976), p. 45Google Scholar
  32. 32.
    H.Z. Kou, D.Z. Liao, Z.H. Jiang, S.P. Yan, Q.J. Wu, S. Gao, G.L. Wang, Inorg. Chem. Commun. 3, 151 (2000)CrossRefGoogle Scholar
  33. 33.
    H.Z. Kou, S.F. Si, S. Gao, D.Z. Liao, Z.H. Jiang, S.P. Yan, Y.G. Fan, G.L. Wang, Eur. J. Inorg. Chem. 699 (2002)Google Scholar
  34. 34.
    T. Miyoshi, T. Iwamoto, Y. Sasaki, Inorg. Chim. Acta 7, 97 (1973)CrossRefGoogle Scholar
  35. 35.
    C. Janiak, H.P. Wu, P. Klüfers, P. Mayer, Acta Crystallogr. C55, 1966 (1999)Google Scholar
  36. 36.
    G.S. Kürkçüoğlu, O.Z. Yeşilel, I. Kavlak, O. Büyükgüngör, Struct. Chem. 19, 879 (2008)CrossRefGoogle Scholar
  37. 37.
    G.S. Kürkçüoğlu, O.Z. Yeşilel, I. Kavlak, O. Büyükgüngör, J. Mol. Struct. 920, 220 (2009)CrossRefGoogle Scholar
  38. 38.
    G.S. Kürkçüoğlu, O.Z. Yeşilel, I. Kavlak, S. Kurtaran, O. Büyükgüngör, J. Inorg. Organomet. Polym. 19, 314 (2009)CrossRefGoogle Scholar
  39. 39.
    G.S. Kürkçüoğlu, O.Z. Yeşilel, I. Kavlak, O. Büyükgüngör, J. Inorg. Organomet. Polym. 19, 539 (2009)CrossRefGoogle Scholar
  40. 40.
    G.S. Kürkçüoğlu, O.Z. Yeşilel, I. Çaylı, O. Büyükgüngör, Z. Kristallogr. 224, 493 (2009)CrossRefGoogle Scholar
  41. 41.
    G.S. Kürkçüoğlu, O.Z. Yeşilel, I. Çaylı, O. Büyükgüngör, J. Inorg. Organomet. Polym. (2011). doi: 10.1007/s10904-010-9454-6
  42. 42.
    Bruker, SADABS (Bruker AXS Inc., Madison, 2005)Google Scholar
  43. 43.
    G.M. Sheldrick, Acta Crystallogr. A64, 112 (2008)Google Scholar
  44. 44.
    L.J. Farrugia, J. Appl. Crystallogr. 30, 565 (1997)CrossRefGoogle Scholar
  45. 45.
    D.T. Cromer, J.T. Waber, Atomic Scattering Factors for X-Rays, Sec. 2.2. in International Tables for X-ray Crystallography, vol. IV (Kynoch Press, Birmingham, 1974), pp. 71–147Google Scholar
  46. 46.
    A. Frisch, A.B. Nielsen, A.J. Holder, M.J. Pittsburg, G.W. Frisch, H.B. Trucks et al., Gaussian 03W Revision D.01 Version 6.1 (Gaussian Inc., Pittsburgh, 2003)Google Scholar
  47. 47.
    S. Akyüz, A.B. Dempster, R.L. Morehouse, S. Suzuki, J. Mol. Struct. 17, 105 (1973)CrossRefGoogle Scholar
  48. 48.
    A.G. Sharpe, The Chemistry of Cyano Complexes of the Transition Metals (Academic, London, 1976)Google Scholar
  49. 49.
    K. Nakamoto, Infrared and Raman Spectra of Inorganic & Coordination Compounds, 5th edn. (Wiley, New York, 1997)Google Scholar
  50. 50.
    Y. Zhou, A.M. Arif, J.S. Miller, Chem. Commun. 1881 (1996)Google Scholar
  51. 51.
    R.L. McCullough, L.H. Jones, G.A. Crosby, Spectrochim. Acta 16, 929 (1960)CrossRefGoogle Scholar
  52. 52.
    S.Z. Zhan, X.Y. Chun, Q.J. Meng, Transition Met. Chem. 21, 181 (1996)CrossRefGoogle Scholar
  53. 53.
    S.Z. Zhan, C.J. Hu, C.W. Yuan, Q.J. Meng, J. Mol. Struct. 486, 3 (1999)Google Scholar
  54. 54.
    S.Z. Zhan, Q.J. Meng, Spectrosc. Lett. 29, 127 (1996)CrossRefGoogle Scholar
  55. 55.
    S.Z. Zhan, X.Y. Chen, A. Vij, D. Guo, Q.J. Meng, Inorg. Chim. Acta 292, 157 (1999)CrossRefGoogle Scholar
  56. 56.
    S.Z. Zhan, X.Y. Chun, Q.J. Meng, W. Xie, Synth. React. Inorg. Met.-Org. Chem. 26, 277 (1996)CrossRefGoogle Scholar
  57. 57.
    S. Alvarez, C. Lopez, M.J. Bermejo, Transition Met. Chem. 9, 123 (1984)CrossRefGoogle Scholar
  58. 58.
    D.F. Shriver, J. Am. Chem. Soc. 85, 1405 (1963)CrossRefGoogle Scholar
  59. 59.
    D.A. Dows, A. Haim, W.K. Wilmarth, J. Inorg. Nucl. Chem. 21, 33 (1961)CrossRefGoogle Scholar
  60. 60.
    C.A. Bignozzi, R. Argazzi, J.R. Schoonover, K.C. Gordon, R.B. Dyer, F. Scandola, Inorg. Chem. 31, 5260 (1992)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • Güneş Süheyla Kürkçüoğlu
    • 1
  • Tuncer Hökelek
    • 2
  • Mehran Aksel
    • 3
  • Okan Zafer Yeşilel
    • 4
  • Hakan Dal
    • 5
  1. 1.Department of Physics, Faculty of Arts and SciencesEskişehir Osmangazi UniversityEskişehirTurkey
  2. 2.Department of Physics, Faculty of EngineeringHacettepe UniversityAnkaraTurkey
  3. 3.Graduate School of ScienceEskişehir Osmangazi UniversityEskişehirTurkey
  4. 4.Department of Chemistry, Faculty of Arts and SciencesEskişehir Osmangazi UniversityEskişehirTurkey
  5. 5.Department of Chemistry, Faculty of SciencesAnadolu UniversityEskişehirTurkey

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