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Syntheses and Characterization of New Nano-porous Soft Copper(II) Metal–organic Framework and Nano-porous Two-dimensional Manganese(II) and Zinc(II) Coordination Polymers with 4,4′-Bipyridine and 2-Sulfobenzoic Acid

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Abstract

Three new Cu(II), Mn(II), and Zn(II) coordination polymers with 4,4′-bipyridine (4,4′-bipy) and 2-sulfobenzoic acid (2-H2sb) ligands, [M(4,4′-bipy)(2-sb)(H2O)]n, have been synthesized and characterized by IR spectroscopy and elemental analyses. The structures were determined by single-crystal X-ray crystallography. The structural studies show that the metal atoms have six-coordinate geometry with a distorted octahedral environment constructed with 4,4′-bipy and 2-sb2− linkers stacked over each other to generate a two-dimension motif. Self-assembly of these compounds in the solid state is likely caused by coordination and hydrogen-bonds. While polymers containing Zn(II) and Mn(II) have analogous structures, the Cu(II)-containing nano-porous soft metal–organic framework presents a different structure.

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References

  1. A. Morsali, M.Y. Masoomi, Coord. Chem. Rev. 253, 1882 (2009)

    Article  CAS  Google Scholar 

  2. K. Akhbari, A. Morsali, Coord. Chem. Rev. 254, 1977 (2010)

    Article  CAS  Google Scholar 

  3. H. Li, M. Eddaoudi, M. O’Keeffe, O.M. Yaghi, Nature. 402, 276 (1999)

    Article  CAS  Google Scholar 

  4. T. Loiseau, C. Serre, C. Huguenard, G. Fink, F. Taulelle, M. Henry, T. Bataille, G. Férey, Chem. Eur. J. 10, 1373 (2004)

    Article  CAS  Google Scholar 

  5. S.S.-Y. Chiu, S.M.-F. Lo, J.P.H. Charmant, A.G. Orpen, I.D. Williams, Science. 283, 1148 (1999)

    Article  Google Scholar 

  6. A.K. Cheetham, C.N.R. Rao, Science. 318, 58 (2007)

    Article  CAS  Google Scholar 

  7. B. Moulton, M.J. Zaworotko, Chem. Rev. 101, 1629 (2001)

    Article  CAS  Google Scholar 

  8. L. Vayssieres, Adv. Mater. 15, 464 (2003)

    Article  CAS  Google Scholar 

  9. M. Bochmann, Coord. Chem. Rev. 253, 2000 (2009)

    Article  CAS  Google Scholar 

  10. V. Stavila, R.L. Davidovich, A. Gulea, K.H. Whitmire, Coord. Chem. Rev. 250, 2782 (2009)

    Article  Google Scholar 

  11. R.L. Davidovich, V. Stavila, K.H. Whitmire, Coord. Chem. Rev. 254, 2193 (2010)

    Article  CAS  Google Scholar 

  12. H.K. Chae, D.Y. Siberio-Perez, J. Kim, Y. Go, M. Eddaoudi, A.J. Matzger, M. O’Keeffe, O.M. Yaghi, Nature 427, 523 (2004)

    Article  CAS  Google Scholar 

  13. N.L. Toh, M. Nagarathinam, J.J. Vittal, Angew. Chem. Int. Ed. 44, 2237 (2005)

    Article  CAS  Google Scholar 

  14. S. Kitagawa, R. Kitaura, S. Noro, Angew. Chem. Int. Ed. 43, 2334 (2004)

    Article  CAS  Google Scholar 

  15. R.L. Davidovich, V. Stavila, D.V. Marinin, E.I. Voit, K.H. Whitmire, Coord. Chem. Rev. 253, 1316 (2009)

    Article  CAS  Google Scholar 

  16. F. Marandi, F. Amoopour, I. Pantenburg, G. Meyer, J. Mol. Struct. 973, 124 (2010)

    Article  CAS  Google Scholar 

  17. J.D. Woodward, R. Backov, K.A. Abboud, H. Ohnuki, M.W. Meisel, D.R. Talham, Polyhedron. 22, 2821 (2003)

    Article  CAS  Google Scholar 

  18. V. Tudor, V. Kravtsov, M. Julve, F. Lloret, Y.A. Simonov, J. Lipkowski, V. Buculei, M. Andruh, Polyhedron. 20, 3033 (2001)

    Article  CAS  Google Scholar 

  19. C. Biswas, S. Chattopadhyay, M.G.B. Drew, A. Ghosh, Polyhedron. 26, 4411 (2007)

    Article  CAS  Google Scholar 

  20. N. Lah, I. Leban, Inorg. Chem. Commun. 9, 42 (2006)

    Article  CAS  Google Scholar 

  21. H.-P. Xiaoa, X.-H. Li, A. Morsali, J.-G. Wanga, W.-B. Zhang, Z. Anorg. Allg. Chem. 633, 1107 (2007)

    Article  Google Scholar 

  22. A. Morsali, H. Hossieni Monfared, A. Morsali, J. Mol. Struct. 938, 10 (2009)

    Article  CAS  Google Scholar 

  23. A. Morsali, H. Hossieni Monfared, A. Morsali, Inorg. Chim. Acta. 362, 3427 (2009)

    Article  CAS  Google Scholar 

  24. F. Bigdeli, A. Morsali, Mater. Lett. 64, 4 (2010)

    Article  CAS  Google Scholar 

  25. F. Bigdeli, A. Morsali, P. Retailleau, Polyhedron. 29, 801 (2010)

    Article  CAS  Google Scholar 

  26. K. Nakamoto, Infrared and Raman spectra of inorganic and coordination compounds, 5th edn. (Wiley, New York, 1997)

    Google Scholar 

Download references

Acknowledgments

The authors acknowledge financial support by the Nation Natural Science Foundation of China (grant no. 20871095) and Zhejiang Provincial Natural Science Foundation (No. X063638) and by Islamic Azad University, East Tehran Branch, Qiamdasht.

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Authors and Affiliations

  1. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, China

    Ai-Yin Wang, Jie Wang, Jia-Guo Wang & Hong-Ping Xiao

  2. Department of Chemistry, Islamic Azad University, East Tehran Branch, Qiamdasht, Tehran, Iran

    Shokufeh Aghabeygi

  3. Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14155-4838, Tehran, Iran

    Ali Mosali

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  1. Ai-Yin Wang
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  2. Jie Wang
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  3. Shokufeh Aghabeygi
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  4. Jia-Guo Wang
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  5. Hong-Ping Xiao
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  6. Ali Mosali
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Correspondence to Ai-Yin Wang or Ali Mosali.

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Wang, AY., Wang, J., Aghabeygi, S. et al. Syntheses and Characterization of New Nano-porous Soft Copper(II) Metal–organic Framework and Nano-porous Two-dimensional Manganese(II) and Zinc(II) Coordination Polymers with 4,4′-Bipyridine and 2-Sulfobenzoic Acid. J Inorg Organomet Polym 21, 700–705 (2011). https://doi.org/10.1007/s10904-011-9487-5

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