Skip to main content
SpringerLink
Log in

Hydrothermal Preparation, Crystal Structures, Spectroscopic and Thermal Analyses of Cadmium(II) and Cobalt(II) Coordination Polymers With Pyridine-2,3-dicarboxylic Acid

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

Two novel 1D coordination polymers, [M(μ-2,3-pydc)(H2O)3]n (M = Cd for 1 and Co for 2) (2,3-pydcH2 = pyridine-2,3-dicarboxylic acid) have been hydrothermally synthesized. Both complexes were characterized by elemental analysis and by IR and UV–Vis spectroscopy. Their molecular and crystal structures were determined by X-ray crystal structure analysis and their thermal stability by TGA-DTA methods. Compound 1 crystallizes in the orthorhombic Pca2 space group, while compound 2 crystallizes in the triclinic P−1 space group. Polymeric chains of 1 and 2 are composed of M(II) ions bridged by pyridine-2,3-dicarboxylate ions (2,3-pydc) in N,O,O′ fashion. Distorted octahedral coordination geometry around the metal ions is completed by three water molecules. A wide range of hydrogen bonding (of the O–H···O type) is also present in the crystal structures. These interactions lead to formation of a 3D structure for 1 and 2D network for 2.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. X. Lin, C. Yun-Xia, Z. Ji-Min, Chinese J. Struct. Chem. 25, 1250 (2006)

    Google Scholar 

  2. Y.H. Wen, J.K. Cheng, Y.L. Feng, J. Zhang, Z.J. Li, Y.G. Yao, Inorg. Chim. Acta 358, 3347 (2005)

    Article  CAS  Google Scholar 

  3. H.D. Yin, F.H. Li, C.H. Wang, Inorg. Chim. Acta 360, 2797 (2007)

    Article  CAS  Google Scholar 

  4. H. Yin, S.X. Liu, Polyhedron 26, 3103 (2007)

    Article  CAS  Google Scholar 

  5. A. Thirumurugan, S. Natarajan, Eur. J. Inorg. Chem. 762 (2004)

  6. J.C. Yao, W. Huang, B. Li, S. Gou, Y. Xu, Inorg. Chem. Commun. 5, 711 (2002)

    Article  CAS  Google Scholar 

  7. X. M. Zhang, M. L. Tong, M. L. Gong, X. M. Chen, Eur. J. Inorg. Chem. 138 (2003)

  8. H. Li, C.E. Davis, F.L. Croy, D.G. Kelley, O.M. Yaghi, J. Am. Chem. Soc. 120, 2186 (1998)

    Article  CAS  Google Scholar 

  9. M. Tabatabaee, M. Ghassemzadeh, F. Rezaie, H.R. Khavasi, M.M. Amini, Acta Cryst. E62, m2784 (2006)

    CAS  Google Scholar 

  10. M. Tabatabaee, M.A. Sharif, F. Vakili, S. Saheli, J. Rare Earths 27, 356 (2009)

    Article  Google Scholar 

  11. M. Tabatabaee, H. Aghabozorg, J. Attar Gharamaleki, M.A. Sharif, Acta Cryst. E65, m473 (2009)

    CAS  Google Scholar 

  12. M. Tabatabaee, R. Mohamadinasab, K. Ghaini, H.R. Khavasi, Bull. Chem. Soc. Ethiop. 24, 401 (2010)

    CAS  Google Scholar 

  13. M. Tabatabaee, Acta Cryst. E66, m647 (2010)

    CAS  Google Scholar 

  14. H. Aghabozorg, F. Manteghi, S. Sheshmani, J. Iran. Chem. Soc. 5, 184 (2008)

    CAS  Google Scholar 

  15. E. Norkus, I. Stalnioniené, Chemija (Vilnius) 13, 194 (2002)

    CAS  Google Scholar 

  16. K.A. Abboud, C. Xu, R.S. Drago, Acta Cryst. C54, 1270 (1998)

    CAS  Google Scholar 

  17. Y. Kanay, Analyst 115, 809 (1990)

    Article  Google Scholar 

  18. F. Semerci, O.Z. Yeşilel, E. Şahin, J. Inorg. Organomet. Polym. 20, 334 (2010)

    Article  CAS  Google Scholar 

  19. Oxford Diffraction. CrysAlis CCD and CrysAlis RED, Versions 171.32.29 (Oxford Diffraction Ltd, Abingdon, Oxfordshire, England, 2008)

  20. G.M. Sheldrick, Acta Crystallogr. A64, 112 (2008)

    CAS  Google Scholar 

  21. A.L. Spek, J. Appl. Crystallogr. 36, 7 (2003)

    Article  CAS  Google Scholar 

  22. L.J. Farrugia, J. Appl. Crystallogr. 30, 565 (1997)

    Article  CAS  Google Scholar 

  23. C.F. Macrae, I.J. Bruno, J.A. Chisholm, P.R. Edgington, P. McCabe, E. Pidcock, L. Rodriguez-Monge, R. Taylor, J. van de Streek, P.A. Wood, J. Appl. Crystallogr. 41, 466 (2008)

    Article  CAS  Google Scholar 

  24. G.B. Deacon, R.J. Philips, Coord. Chem. Rev. 33, 227 (1980)

    Article  CAS  Google Scholar 

  25. B.-M. Kukovec, Z. Popović, B. Kozlevčar, Z. Jagličić, Polyhedron 27, 3631 (2008)

    Article  CAS  Google Scholar 

  26. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th edn. (Wiley Interscience, New York, 1986)

    Google Scholar 

  27. H. Aghabozorg, E. Sadr-khanlou, A. Shokrollahi, M. Ghaedi, M. Shamsipur, J. Iran. Chem. Soc. 6, 55 (2009)

    CAS  Google Scholar 

  28. Z. Aghajani, H. Aghabozorg, E. Sadr-khanlou, A. Shokrollahi, S. Derki, M. Shamsipur, J. Iran. Chem. Soc. 6, 373 (2009)

    CAS  Google Scholar 

  29. M. Indrani, R. Ramasubramanian, S. Kumaresan, S.K. Kang, M. Chen, M. Du, Polyhedron 27, 3593 (2008)

    Article  CAS  Google Scholar 

  30. M. Tabatabaee, H. Aghabozorg, R. Nasrolahzadeh, L. Roshan, N. Firoozi, Acta Cryst. E64, m1290 (2008)

    CAS  Google Scholar 

  31. M. Odoko, A. Kusano, N. Okabe, Acta Cryst. E58, m25 (2002)

    CAS  Google Scholar 

  32. A. Moghimi, S. Sheshmani, A. Shokrollahi, H. Aghabozorg, M. Shamsipur, G. Kickelbick, M.C. Aragoni, V. Lippolis, Z. Anorg. Allg. Chem. 630, 617 (2004)

    Article  CAS  Google Scholar 

  33. S. Sheshmani, H. Aghabozorg, F. Mohammad Panah, R. Alizadeh, G. Kickelbick, B. Nakhjavan, A. Moghimie, F. Ramezanipourb, H.R. Aghabozorg, Z. Anorg, Allg. Chem. 632, 469 (2006)

    Article  CAS  Google Scholar 

  34. B.-M. Kukovec, Z. Popović, J. Mol. Struct. 938, 174 (2009)

    Article  CAS  Google Scholar 

  35. B.-M. Kukovec, Z. Popović, G. Pavlović, M. Rajić Linarić, J. Mol. Struct. 882, 47 (2008)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This research was supported by the Ministry of Science, Education and Sports of the Republic of Croatia (Grant No. 119-1193079-1332) and Islamic Azad University, Yazd Branch, Iran.

Author information

Authors and Affiliations

  1. Department of Chemistry, Islamic Azad University, Yazd Branch, Yazd, Iran

    Masoumeh Tabatabaee & Vajieh Razavimahmoudabadi

  2. Laboratory of General and Inorganic Chemistry, Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, 10000, Zagreb, Croatia

    Boris-Marko Kukovec

  3. Chemistry & Chemical Engineering Research Center of Iran, P.O. Box 14335-189, Tehran, Iran

    Mitra Ghassemzadeh

  4. Fachbereich Chemie, Universität Marburg, Hans-Meerwein-Straße, 35032, Marburg, Germany

    Bernhard Neumüller

Authors
  1. Masoumeh Tabatabaee
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Vajieh Razavimahmoudabadi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Boris-Marko Kukovec
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Mitra Ghassemzadeh
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Bernhard Neumüller
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Masoumeh Tabatabaee.

Electronic supplementary material

Supplementary material: CCDC 805009 and 805010 contain the supplementary crystallographic data for 1 and 2. These data can be obtained free of charge viawww.ccdc.cam.ac.uk/conts/retrieving.html [or from the Cambridge Crystallographic Data Centre (CCDC), 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44(0)1223-336033; email: deposit@ccdc.cam.ac.uk]. Structure factor table is available from the authors.

Supplementary material 1 (TIFF 424 kb)

Supplementary material 2 (TIFF 458 kb)

Supplementary material 3 (TIFF 319 kb)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tabatabaee, M., Razavimahmoudabadi, V., Kukovec, BM. et al. Hydrothermal Preparation, Crystal Structures, Spectroscopic and Thermal Analyses of Cadmium(II) and Cobalt(II) Coordination Polymers With Pyridine-2,3-dicarboxylic Acid. J Inorg Organomet Polym 21, 450–457 (2011). https://doi.org/10.1007/s10904-011-9462-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-011-9462-1

Keywords

Search

Navigation